Article
Biochemistry & Molecular Biology
Polona Umek, Michael Duerrschnabel, Leopoldo Molina-Luna, Sreco Skapin, Romana Cerc Korosec, Carla Bittencourt
Summary: CeO2-TiO2 is an important mixed oxide with catalytic properties in heterogeneous photocatalysis. This study presents a method to obtain 1D TiO2 nanostructures decorated with CeO2 nanoparticles. The phase composition and morphology changes were monitored during calcination, and the temperature required for phase conversion was influenced by the cerium oxidation state. Analysis showed the presence of both +4 and +3 oxidation states in all calcined samples.
Article
Materials Science, Multidisciplinary
Hussein O. Badr, Francisco Lagunas, Daniel E. Autrey, Jacob Cope, Takayuki Kono, Takeshi Torita, Robert F. Klie, Yong-Jie Hu, Michel W. Barsoum
Summary: We synthesized 1D TiO2-based nanofilaments by reacting Ti-containing precursors with quaternary ammonium hydroxides at near-ambient conditions. The structure was previously believed to be anatase-based, but we now conclude that it is actually a 1D titania lepidocrocite-based structure. The NFs grow along [100] and tend to self-assemble/stack in two directions. The band gap is not affected by the nature of the cations surrounding the NFs.
Article
Chemistry, Physical
Martin Wittmann, Astrid Ali, Thomas Gemming, Fernando Stavale, Juliane Simmchen
Summary: Colloidal active matter is highly sensitive to external conditions, with the nanoscopic material properties of the motor bodies playing a significant role in their catalytic activity. By asymmetrizing colloidal titania spheres with different nanoscale cobalt oxide species, the influence of subtle differences in chemical composition and interfacing between the different material compounds on catalytic activity was demonstrated.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Physical
Xuhui Wei, Haifeng Liu, Shugong Gao, Kun Jia, Zhijian Wang, Jiazang Chen
Summary: Photocatalytic fixed bed reactors have the advantages of straightforward separation and simplified installation and operation. This study demonstrates that by modulating the electronic process and mass transport, photocatalytic fixed bed reactors can achieve a superior reaction rate compared to slurry suspension. The research also shows that mass transport occurring on a decisecond time scale does not significantly slow down the reaction.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Miguel Recio-Poo, Angel Morales-Garcia, Francesc Illas, Stefan T. T. Bromley
Summary: In this study, the interrelation between crystallinity, surface hydroxylation, and electronic structure in titania nanoparticles (NPs) was investigated using density functional theory-based calculations. The results showed that the local coordination environments of the atoms in annealed non-crystalline NPs became similar to those in faceted crystalline anatase NPs with increasing hydroxylation. Highly hydroxylated annealed NPs also exhibited similar electronic energy gaps and band edge orbital characters to crystalline anatase NPs. These findings suggest that the anatase crystal structure may not be essential for TiO2 NP applications, and crystal-like NPs could exist in other nanomaterials.
Article
Materials Science, Multidisciplinary
Trinh Thi Loan, Vu Hoang Huong, Nguyen Thi Huyen, Lai Van Quyet, Ngac An Bang, Nguyen Ngoc Long
Summary: This study investigates the effect of Fe doping on the phase transformation and optical properties of TiO2 nanoparticles, showing that Fe3+ doping leads to the transformation into rutile phase and a decrease in band gap energy of TiO2.
Article
Chemistry, Multidisciplinary
Pritha Biswas, Tamara D. Koledin, Skylar N. Farmer, Melissa K. Santala, Janet Tate
Summary: The transformation from amorphous to crystalline in TiO2 films in air leads to different polymorphs, which can be manipulated by introducing Sn into the system. Sn stabilizes the rutile structure at the Sn/TiO2 interfaces by scavenging oxygen, resulting in rutile formation.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Physical
Kasidid Yaemsunthorn, Wiktoria Adamowicz, Marcin Kobielusz, Wojciech Macyk
Summary: The photocatalytic selective reduction of 3-nitrophenol to 3-aminophenol was studied using titanium dioxide in different compositions. Both intrinsic and extrinsic parameters were found to affect the reaction progress, with intrinsic factors related to the chemical, structural, and electronic properties and extrinsic factors related to the reaction conditions. The analysis revealed that the performance of anatase and rutile materials varied due to differences in interfacial electron transfer, charge recombination, reduction driving force, and methanol photooxidation efficiency. The understanding of these factors could lead to the rational design of efficient and selective photocatalysts.
Article
Chemistry, Physical
Kolade Augustine Oyekan, Maarten Van de Put, Sabyasachi Tiwari, Carole Rossi, Alain Esteve, William Vandenberghe
Summary: This study investigates the role of subsurface oxygen vacancies in water splitting on titanium dioxide, finding that vacancy migration is essential for an exothermic pathway and only occurs in the presence of under-coordinated surface oxygen atoms. As water decomposition and surface oxygen saturation increase, migration of the subsurface V-O is inhibited.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Luis Antonio Garcia-Contreras, Jose Ocotlan Flores-Flores, Jesus Angel Arenas-Alatorre, Jose Alvaro Chavez-Carvayar
Summary: This study reports the morphological evolution and phase change of TiO2 nanobelts, as well as the synthesis of anatase, brookite, and rutile phases using different hydrochloric acid solutions. The materials were characterized using XRD, SEM, and 2D micro-Raman and infrared FT-IR spectroscopies.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Sekhar C. Ray, Dilip Kumar Mishra, Atala Bihari Panda, H. T. Wang, Sriparna Bhattacharya (Mitra), W. F. Pong
Summary: TiO2 thin films were prepared using the reactive magnetron cosputtering technique, and the modification in the electronic structure with the increase of annealing temperatures was studied. The results showed that the annealing temperature had a significant impact on the structure and bonding of the TiO2 thin films, leading to changes in the electronic properties.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Hao-Bo Li, Shunsuke Kobayashi, Chengchao Zhong, Morito Namba, Yu Cao, Daichi Kato, Yoshinori Kotani, Qianmei Lin, Maokun Wu, Wei-Hua Wang, Masaki Kobayashi, Koji Fujita, Cedric Tassel, Takahito Terashima, Akihide Kuwabara, Yoji Kobayashi, Hiroshi Takatsu, Hiroshi Kageyama
Summary: The study demonstrates that highly reduced oxides, such as SrCoO2, can be obtained through electrochemical protonation combined with thermal dehydration, resulting in novel crystal structures. This method expands the exploration of novel functional oxides by widening the possibilities for research.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Long Wang, Pingru Cai, Zuozhen Liu, Zailai Xie, Yuanxing Fang
Summary: This study investigates the use of carbon quantum dots (CQDs) as co-catalysts to promote water oxidation reaction (WOR) in a photocatalytic system. The results show that CQDs can significantly enhance the efficiency and stability of WOR. The in-situ characterizations reveal the mechanism of CQDs in facilitating WOR and provide insights for the application of carbon in photocatalytic systems.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Fengyang Yu, Xiaohua Wang, Haiyue Lu, Gen Li, Baicheng Liao, Hanqing Wang, Chunying Duan, Yu Mao, Liyong Chen
Summary: Low-cost high-efficiency H2 evolution is essential for large-scale applications. This research aims to build highly active photocatalysts for sunlight-driven H2 production through surface engineering. Single-atom Pt doped TiO2-x nanosheets (NSs) with Pt nanoparticles (NPs) at their edges are prepared by an oxygen vacancy engaged synthetic strategy. The Pt/TiO2-x-SAP exhibits ultrahigh photocatalytic performance with a quantum yield of 90.8% and a H2 generation rate of 607 mmol gcata-1 h-1.
INORGANIC CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Mehrdad Abbasi, Yutao Dong, Jun Meng, Dane Morgan, Xudong Wang, Jinwoo Hwang
Summary: The evolution of medium range ordering (MRO) and crystallization behavior of amorphous TiO2 films grown by atomic layer deposition were investigated using in situ four-dimensional scanning transmission electron microscopy. The degree of MRO increases with temperature and reaches the maximum when crystallization starts to occur. In addition, post-annealing only develops a small portion of MRO into crystal nuclei, while the remaining MRO regions undergo structural relaxation. Crystallographic defects within crystal phases were observed, which may affect the corrosion resistance of the film. Understanding and controlling MRO is important for optimizing ALD-grown amorphous films for future functional devices and renewable energy applications.