4.7 Article

The prominent combination of ultrahigh strength and superior tensile plasticity in Cu-Zr nanoglass connected by oxide interfaces: A molecular dynamics study

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 801, Issue -, Pages 318-326

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.06.097

Keywords

Nanoglass; Oxidation; Interface; Shear transformation; Molecular dynamics

Funding

  1. National Science Fund for Distinguished Young Scholars of China [51725504]
  2. National Natural Science Foundation of China [51705168, 51805181]
  3. Research Grants Council of the Hong Kong Special Administrative Region, China [PolyU152607/16E]
  4. China Postdoctoral Science Foundation [2017M610473]

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A novel Cu-Zr nanoglass consisting of glassy nano-cells connected by oxide interfaces is proposed. Compared to conventional nanoglasses, the novel oxide-connected nanoglass presents ultrahigh tensile strength and superior tensile plasticity at ambient temperature. Subjected to tensile loading, the oxide interfaces are found to promote the nucleation of shear transformation zones (STZs) due to the existence of excess free volume. Meanwhile, the strong bonding between metallic and oxygen atoms in the oxide interface makes it difficult for STZs to propagate through. Thus, the STZs are effectively proliferated and confined inside the cell interior without any mature shear band (SB) formed. The results provide new ideas for toughening metallic glasses with a decent combination of plasticity and strength, thus making it possible to overcome the longstanding strength-ductility trade-off dilemma. (C) 2019 Elsevier B.V. All rights reserved.

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