Journal
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Volume 51, Issue 12, Pages 903-908Publisher
WILEY
DOI: 10.1002/kin.21318
Keywords
crystallization kinetics; crystallization mechanism; isothermal crystallization; local activation energy; metallic glass
Categories
Funding
- Natural Science Foundation of China [51371133, 51401156, 51671151]
- 973 programs [2013CB632904]
- Science and Technology Program of Shaanxi Province [2016KJXX-87]
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The crystallization kinetics of Cu55Zr45 (at%) glassy alloy is studied under isothermal condition using differential scanning calorimetry (DSC). The plot of correlation between the crystallized volume fraction alpha and annealing time t shows a sigmoid-type curve, which is steeper with higher annealing temperature. Furthermore, in isothermal crystallization condition, local activation energy E-alpha values, determined using the Arrhenius equation, range from 181.1 to 187.8 kJ/mol, which is nearly a constant. The local Avrami exponent n(alpha) values, obtained by the Johnson-Mehl-Avrami equation, which range from 2.2 to 4.0 at different annealing temeperatures, which indicates that the crystallization mechanism is diffusion-controlled transformation. Moreover, n(alpha) becomes greater with increasing annealing temperature, which indicates that annealing temperature can affect nucleation rate and growth type.
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