Journal
INORGANIC CHEMISTRY
Volume 58, Issue 19, Pages 13426-13439Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02324
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Funding
- German Israel Foundation [I-1264-302.5/2014]
- Technion Guangdong Fellowship
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Synthesis and characterization of a new family of aluminum, magnesium, and zinc complexes supported by (benz)-imidazolin-2-iminato ligands are reported herein. Under different reaction conditions, (benz)imidazolin-2-imine ligands reacted with metal alkyl precursors to afford the corresponding complexes, displaying mononuclear, binuclear, and trinuclear structures. Reaction in 1:1 stoichiometry at room temperature afforded the simple Lewis acid-base adducts, which exhibited distorted tetrahedral geometries around the metal centers, whereas high temperature reactions gave rise to dimeric complexes, with each metal bridging two (benz)imidazolin-2-imine ligands to form a four-membered metallacycle ring at the center of the complexes. The catalytic ring opening polymerization (ROP) of epsilon-caprolactone was studied using these complexes as precatalysts in the presence of isopropanol, and very high activities were observed, affording high/medium molecular weight poly(epsilon-caprolactone) products with low polydispersity indices. Detailed kinetic studies revealed that the polymerizations proceeded in a living manner and molecular weights of the polymers could be precisely controlled.
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