Journal
INDUSTRIAL CROPS AND PRODUCTS
Volume 135, Issue -, Pages 30-38Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.indcrop.2019.03.050
Keywords
Lignin; Activated carbon; Template; NaCl
Categories
Funding
- Finnish innovation funding Business Finland [6886/31/2017]
Ask authors/readers for more resources
Chemical activation and template method using lignin have been considered efficient for producing microporous activated carbon. However, the limited accessibility of micropores and significant chemical consumption hinder the application of aforementioned methods. In order to save attractive properties of both activation routes and to overcome environmental impact, novel combined chemical-templated activation was investigated. A mixture of NaOH and NaCl was employed to produce carbon, which possessed high surface area and versatile porous structure. The process was optimised and described by mathematical models using the response surface method (RSM). The BET surface area and yield were selected as output performances (responses), whilst temperature, time and chemical ratio were chosen as variable inputs (factors). Macropore sizes were of the same NaCl crystal size confirmed by XRD and SEM indicating a template mechanism. Micropore origin was suggested by chemical reactions between NaOH and carbon with a formation of Na2CO3 confirmed by XRD standard patterns and corresponding FTIR peaks. According to RSM design, the most significant factor is chemical ratio for both responses. The experimental data of the BET surface area is in a good validity of the quadratic model, while yield matched the linear model well according to the ANOVA test. In this study, porous carbon was produced by new method overcoming the major challenges of templated and chemical activation and brings added value of lignin.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available