Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 42, Pages 7058-7062Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901413
Keywords
Alkynylation; Cycloisomerization; Domino reactions; Fluorescence; Isomerization
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Funding
- German Academic Exchange Service (DAAD)
- Iran Science Elites Federation (ISEF)
- Deutsche Forschungsgemeinschaft [Mu 1088/91]
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A Pd/Cu-catalyzed base mediated domino process of ortho-halo (hetero)aryl carboxaldehydes and propargyl alcohols unexpectedly furnish 2-(hydroxymethylene)indenones in good to excellent yield as a result of a coupling-isomerization-cycloisomerization reaction (CICIR). In addition, the title compounds constitute an interesting class of luminophores with tunable emission solvatochromicity.
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