Journal
CELLULOSE
Volume 26, Issue 16, Pages 8557-8573Publisher
SPRINGER
DOI: 10.1007/s10570-019-02646-z
Keywords
Biomass valorization; Biorefinery; Green solvent; Lignocellulosic biomass; Waste management
Funding
- Ministry of Higher Education, Malaysia [FRGS-MRSA/1/2018/WAB01/MUSM/02/1]
- Monash University Malaysia
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Cost-effective pretreatments are essential to overcome the recalcitrant properties of lignocellulosic biomass in order to reutilize cellulosic components within the biomass for value-added products. In this study, a sequential pretreatment of low concentration (< 1.00 vol%) alkaline hydrogen peroxide (AHP) at ambient temperature (similar to 25 degrees C) and pressure (1 atm.) with Type III deep eutectic solvent (DES) was used to fractionate oil palm fronds (OPF). A combination of AHP (0.25 vol%, 90 min) and DES (120 degrees C, 4 h) at the later stage resulted in a pretreated OPF with a delignification of 18.99%, remarkably improved DES-alone delignification extent by 1.6 folds. The characterizations of pretreated OPF confirmed that mild conditions AHP + DES pretreatment could synergically improve the delignification efficiency. Thus, the use of this sequential pretreatment enabled the lignin extraction and effectively disrupted the recalcitrant structure of OPF, yielding a potential feedstock for a biorefinery process at the later stage.
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