Catalyst‐free Decarboxylation and Decarboxylative Giese Additions of Alkyl Carboxylates through Photoactivation of Electron Donor‐Acceptor Complex

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings

(2019) Shane Plunkett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Redox-Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

(2019) Thomas van Leeuwen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Copper-Catalyzed Coupling of Terminal Alkynes and Alkyl Iodides

(2018) Avijit Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative reactions with and without light – a comparison

(2018) Johanna Schwarz et al.   GREEN CHEMISTRY

Cis-Selective Decarboxylative Alkenylation of Aliphatic Carboxylic Acids with Vinyl Arenes Enabled by Photoredox/Palladium/Uphill Triple Catalysis

(2018) Chao Zheng et al.   ORGANIC LETTERS

Irradiation-Induced Palladium-Catalyzed Decarboxylative Heck Reaction of Aliphatic N-(Acyloxy)phthalimides at Room Temperature

(2018) Guang-Zu Wang et al.   ORGANIC LETTERS

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers To Synthesize Functionalized Aryl Alkyl Ketones

(2018) Weiguang Kong et al.   ORGANIC LETTERS

Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides

(2018) Rui Shang et al.   SYNTHESIS-STUTTGART

N -(Acyloxy)phthalimides as Redox-Active Esters in Cross-Coupling Reactions

(2018) Sandip Murarka   ADVANCED SYNTHESIS & CATALYSIS

Stereocontrolled Synthesis of 1,4-Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals

(2018) Giulio Goti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system

(2018) Wan-Min Cheng et al.   Nature Communications

Decarboxylative Giese-Type Reaction of Carboxylic Acids Promoted by Visible Light: A Sustainable and Photoredox-Neutral Protocol

(2017) Nieves P. Ramirez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Irradiation-Induced Heck Reaction of Unactivated Alkyl Halides at Room Temperature

(2017) Guang-Zu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

(2017) Corey H. Basch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N-Hydroxyphthalimide Esters

(2017) Lisa Candish et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative alkenylation

(2017) Jacob T. Edwards et al.   NATURE

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms

(2016) Tian Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free, visible-light-mediated, decarboxylative alkylation of biomass-derived compounds

(2016) Johanna Schwarz et al.   GREEN CHEMISTRY

Redox-Active Esters in Fe-Catalyzed C–C Coupling

(2016) Fumihiko Toriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Ni-Catalyzed Aryl–Alkyl Cross-Coupling of Secondary Redox-Active Esters

(2016) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

(2016) Craig P. Johnston et al.   NATURE

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents

(2016) T. Qin et al.   SCIENCE

Photoredox/Brønsted Acid Co-Catalysis Enabling Decarboxylative Coupling of Amino Acid and Peptide Redox-Active Esters with N-Heteroarenes

(2016) Wan-Min Cheng et al.   ACS Catalysis

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-induced chemoselective reductive decarboxylative alkynylation under biomolecule-compatible conditions

(2015) Jie Yang et al.   CHEMICAL COMMUNICATIONS

Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis

(2015) Gerald Pratsch et al.   JOURNAL OF ORGANIC CHEMISTRY

Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products

(2015) Daniel S. Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis

(2015) Guang-Zu Wang et al.   ORGANIC LETTERS

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore

(2014) Zhiwei Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

(2014) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Transformation of Biomass into Commodity Chemicals Using Enzymes or Cells

(2013) Adrie J. J. Straathof   CHEMICAL REVIEWS

Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates

(2013) Gregory L. Lackner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition

(2012) Martin J. Schnermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Total Synthesis of Aplyviolene

(2011) Martin J. Schnermann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reducing the Cost, Smell, and Toxicity of the Barton Reductive Decarboxylation: Chloroform as the Hydrogen Atom Source

(2011) Eun Jung Ko et al.   ORGANIC LETTERS

Transition metal-catalyzed decarboxylative cross-coupling reactions

(2011) Rui Shang et al.   Science China-Chemistry

Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetates with Aryl Halides and Triflates

(2010) Rui Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fresh Look at Electron-Transfer Mechanisms via the Donor/Acceptor Bindings in the Critical Encounter Complex

(2008) Sergiy V. Rosokha et al.   ACCOUNTS OF CHEMICAL RESEARCH