Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 40, Pages 36666-36675Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b12063
Keywords
transition-metal oxides; oxygen vacancies; lattice refining strategy; catalytic oxidation; oxidative desulfurization
Funding
- National Natural Science Foundation of China [21722604, 21576122, 21808092]
- China Postdoctoral Science Foundation [2019M651743]
- Natural Science Research for Universities in Jiangsu Province [19KJB530005]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [SJKY19_2575]
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Surface oxygen vacancy can greatly affect the properties of transition-metal oxides. However, engineering oxygen vacancy-abundant transition-metal oxides with high specific surface area (SSA) remains challenging. At present, the generation of oxygen vacancies in metal oxides is time-consuming and less environmentally friendly by chemical leaching methods that usually require additional waste treatment. Herein, a series of oxygen vacancy-abundant transition-metal oxides with high SSA are constructed via a lattice refining strategy. This strategy is realized by urea-assisted ball milling pyrolysis and is green, efficient, and universal. The oxygen vacancies promote the mobility of oxygen, leading to a boosted catalytic oxidation performance of aromatic sulfides. Such a strategy provides an efficient approach to manufacturing oxygen vacancies on transition-metal oxides, which may be beneficial for various related applications as an effective catalytic material.
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