Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites

The Effect of the Active-Site Structure on the Activity of Copper Mordenite in the Aerobic and Anaerobic Conversion of Methane into Methanol

(2018) Vitaly L. Sushkevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution of active sites during selective oxidation of methane to methanol over Cu-CHA and Cu-MOR zeolites as monitored by operando XAS

(2018) Elisa Borfecchia et al.   CATALYSIS TODAY

Homogeneous Copper-Catalyzed Conversion of Methane to Methyl Trifluoroacetate in High Yield at Low Pressure

(2018) Manoj Ravi et al.   ChemCatChem

Stepwise methane-to-methanol conversion on CuO/SBA-15

(2018) Ha Vu Le et al.   CHEMISTRY-A EUROPEAN JOURNAL

Second-Sphere Effects on Methane Hydroxylation in Cu-Zeolites

(2018) Benjamin E. R. Snyder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Stepwise Oxidation of Methane to Methanol over Cu–SiO2

(2018) Selmi E. Bozbag et al.   ACS Catalysis

Direct Methane to Methanol: The Selectivity–Conversion Limit and Design Strategies

(2018) Allegra A. Latimer et al.   ACS Catalysis

Cation-exchanged zeolites for the selective oxidation of methane to methanol

(2018) Ambarish R. Kulkarni et al.   Catalysis Science & Technology

On the Mechanism Underlying the Direct Conversion of Methane to Methanol by Copper Hosted in Zeolites; Braiding Cu K-Edge XANES and Reactivity Studies

(2018) Mark A. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationally Designing the Mixed Cu-(μ-O)-M (M=Cu, Ag, Zn, Au) Centers over Zeolite Materials with High Catalytic Activity towards Methane Activation

(2018) Guiru Wang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Viewpoint on the Partial Oxidation of Methane to Methanol Using Cu- and Fe-Exchanged Zeolites

(2018) Kimberly T. Dinh et al.   ACS Catalysis

The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment

(2018) Dimitrios K. Pappas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Modified Zeolites and Silica for Conversion of Methane to Methanol

(2018) Xueting Wang et al.   Catalysts

Methane Oxidation to Methanol Catalyzed by Cu-Oxo Clusters Stabilized in NU-1000 Metal–Organic Framework

(2017) Takaaki Ikuno et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methane to Methanol: Structure–Activity Relationships for Cu-CHA

(2017) Dimitrios K. Pappas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assessing the relative stability of copper oxide clusters as active sites of a CuMOR zeolite for methane to methanol conversion: size matters?

(2017) Dennis Palagin et al.   Nanoscale

Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts

(2017) Junjun Shan et al.   NATURE

Selective anaerobic oxidation of methane enables direct synthesis of methanol

(2017) Vitaly L. Sushkevich et al.   SCIENCE

Formation of [Cu2O2]2+ and [Cu2O]2+ toward C–H Bond Activation in Cu-SSZ-13 and Cu-SSZ-39

(2017) Bahar Ipek et al.   ACS Catalysis

Roles of Zeolite Confinement and Cu–O–Cu Angle on the Direct Conversion of Methane to Methanol by [Cu2(μ-O)]2+-Exchanged AEI, CHA, AFX, and MFI Zeolites

(2017) M. Haris Mahyuddin et al.   ACS Catalysis

Solid-State Ion-Exchanged Cu/Mordenite Catalysts for the Direct Conversion of Methane to Methanol

(2017) Ha V. Le et al.   ACS Catalysis

Methane conversion into different hydrocarbons or oxygenates: current status and future perspectives in catalyst development and reactor operation

(2017) Evgenii V. Kondratenko et al.   Catalysis Science & Technology

Isothermal Cyclic Conversion of Methane into Methanol over Copper-Exchanged Zeolite at Low Temperature

(2016) Patrick Tomkins et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis gas technology large-scale applications

(2016) Ib Dybkjaer et al.   CANADIAN JOURNAL OF CHEMICAL ENGINEERING

Selective Oxidation of Methane to Methanol Over Cu- and Fe-Exchanged Zeolites: The Effect of Si/Al Molar Ratio

(2016) Christos Kalamaras et al.   CATALYSIS LETTERS

Correlation between Cu ion migration behaviour and deNOx activity in Cu-SSZ-13 for the standard NH3-SCR reaction

(2016) A. M. Beale et al.   CHEMICAL COMMUNICATIONS

Catalytic conversion of methane to methanol on Cu-SSZ-13 using N2O as oxidant

(2016) B. Ipek et al.   CHEMICAL COMMUNICATIONS

Synthesis of single-site copper catalysts for methane partial oxidation

(2016) S. Grundner et al.   CHEMICAL COMMUNICATIONS

A radical rebound mechanism for the methane oxidation reaction promoted by the dicopper center of a pMMO enzyme: a computational perspective

(2016) Júlio C. S. Da Silva et al.   DALTON TRANSACTIONS

Stability and reactivity of copper oxo-clusters in ZSM-5 zeolite for selective methane oxidation to methanol

(2016) Guanna Li et al.   JOURNAL OF CATALYSIS

Low-Temperature Conversion of Methane to Methanol on CeOx/Cu2O Catalysts: Water Controlled Activation of the C–H Bond

(2016) Zhijun Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis in a Cage: Condition-Dependent Speciation and Dynamics of Exchanged Cu Cations in SSZ-13 Zeolites

(2016) Christopher Paolucci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Location and Distribution of Al Sites in ZSM-5 on the Formation of Cu-Oxo Clusters Active for Direct Conversion of Methane to Methanol

(2016) Monica A. C. Markovits et al.   TOPICS IN CATALYSIS

Roles of Water Molecules in Modulating the Reactivity of Dioxygen-Bound Cu-ZSM-5 toward Methane: A Theoretical Prediction

(2016) Takashi Yumura et al.   ACS Catalysis

Theoretical Insights into the Selective Oxidation of Methane to Methanol in Copper-Exchanged Mordenite

(2016) Zhi-Jian Zhao et al.   ACS Catalysis

Direct Conversion of Methane to Methanol by Metal-Exchanged ZSM-5 Zeolite (Metal = Fe, Co, Ni, Cu)

(2016) M. Haris Mahyuddin et al.   ACS Catalysis

Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis: Challenges and Opportunities

(2016) Alma I. Olivos-Suarez et al.   ACS Catalysis

Monocopper Active Site for Partial Methane Oxidation in Cu-Exchanged 8MR Zeolites

(2016) Ambarish R. Kulkarni et al.   ACS Catalysis

Methane to methanol over copper mordenite: yield improvement through multiple cycles and different synthesis techniques

(2016) Selmi E. Bozbag et al.   Catalysis Science & Technology

Catalytic Oxidation of Methane into Methanol over Copper-Exchanged Zeolites with Oxygen at Low Temperature

(2016) Karthik Narsimhan et al.   ACS Central Science

Improved Efficiency for Partial Oxidation of Methane by Controlled Copper Deposition on Surface-Modified ZSM-5

(2015) Thomas Sheppard et al.   ChemCatChem

Conversion of methane to methanol on copper-containing small-pore zeolites and zeotypes

(2015) M. J. Wulfers et al.   CHEMICAL COMMUNICATIONS

Optimal dynamic allocation of mobile plants to monetize associated or stranded natural gas, part I: Bakken shale play case study

(2015) Siah Hong Tan et al.   ENERGY

Spectroscopic Definition of the Copper Active Sites in Mordenite: Selective Methane Oxidation

(2015) Pieter Vanelderen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic oxygen activation versus autoxidation for industrial applications: a physicochemical approach

(2015) Xi Liu et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction

(2015) E. Borfecchia et al.   Chemical Science

Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

(2015) Sebastian Grundner et al.   Nature Communications

A low temperature, isothermal gas-phase system for conversion of methane to methanol over Cu–ZSM-5

(2014) T. Sheppard et al.   CHEMICAL COMMUNICATIONS

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

Quasicatalytic and catalytic oxidation of methane to methanol by nitrous oxide over FeZSM-5 zeolite

(2014) Mikhail V. Parfenov et al.   JOURNAL OF CATALYSIS

Main-Group Compounds Selectively Oxidize Mixtures of Methane, Ethane, and Propane to Alcohol Esters

(2014) B. G. Hashiguchi et al.   SCIENCE

Methane on the Rise--Again

(2014) E. G. Nisbet et al.   SCIENCE

Oxidation of methane to methanol on the surface of FeZSM-5 zeolite

(2013) Eugeny V. Starokon et al.   JOURNAL OF CATALYSIS

Biological conversion of methane to methanol

(2013) Donghyun Park et al.   KOREAN JOURNAL OF CHEMICAL ENGINEERING

Control of substrate access to the active site in methane monooxygenase

(2013) Seung Jae Lee et al.   NATURE

Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen

(2012) Emil Roduner et al.   ChemCatChem

Two different cationic positions in Cu-SSZ-13?

(2012) Ja Hun Kwak et al.   CHEMICAL COMMUNICATIONS

Oxidative Methane Upgrading

(2012) Ceri Hammond et al.   ChemSusChem

DFT study of the mechanism for methane hydroxylation by soluble methane monooxygenase (sMMO): effects of oxidation state, spin state, and coordination number

(2012) Shu-Ping Huang et al.   DALTON TRANSACTIONS

Current status and development of membranes for CO2/CH4 separation: A review

(2012) Yuan Zhang et al.   International Journal of Greenhouse Gas Control

Dioxygen Activation in Soluble Methane Monooxygenase

(2011) Christine E. Tinberg et al.   ACCOUNTS OF CHEMICAL RESEARCH

High-rate conversion of methane to methanol by Methylosinus trichosporium OB3b

(2011) Changhong Duan et al.   BIORESOURCE TECHNOLOGY

Direct methane conversion routes to chemicals and fuels

(2011) M.C. Alvarez-Galvan et al.   CATALYSIS TODAY

Catalytic conversion of methane to methanol over Cu–mordenite

(2011) Evalyn Mae Alayon et al.   CHEMICAL COMMUNICATIONS

Cu-ZSM-5: A biomimetic inorganic model for methane oxidation

(2011) Pieter Vanelderen et al.   JOURNAL OF CATALYSIS

Room-Temperature Oxidation of Methane by α-Oxygen and Extraction of Products from the FeZSM-5 Surface

(2011) Eugeny V. Starokon et al.   Journal of Physical Chemistry C

Optimization of lab scale methanol production by Methylosinus trichosporium OB3b

(2010) Hee Gon Kim et al.   BIOTECHNOLOGY AND BIOPROCESS ENGINEERING

Cu-ZSM-5 Zeolites for the Formation of Methanol from Methane and Oxygen: Probing the Active Sites and Spectator Species

(2010) Nadzeya V. Beznis et al.   CATALYSIS LETTERS

Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes

(2010) Simone Friedle et al.   CHEMICAL SOCIETY REVIEWS

Oxygen Precursor to the Reactive Intermediate in Methanol Synthesis by Cu-ZSM-5

(2010) Pieter J. Smeets et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of methane to methanol and formaldehyde over Co–ZSM-5 molecular sieves: Tuning the reactivity and selectivity by alkaline and acid treatments of the zeolite ZSM-5 agglomerates

(2010) Nadzeya V. Beznis et al.   MICROPOROUS AND MESOPOROUS MATERIALS

A [Cu2O]2+core in Cu-ZSM-5, the active site in the oxidation of methane to methanol

(2009) Julia S. Woertink et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Energy-Efficient Syngas Production through Catalytic Oxy-Methane Reforming Reactions

(2008) Tushar V. Choudhary et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION