Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction

Electrochemical and Photochemical Reduction of CO2 Catalyzed by Re(I) Complexes Carrying Local Proton Sources

(2019) Laura Rotundo et al.   ORGANOMETALLICS

Changing the Selectivity of O2 Reduction Catalysis with One Ligand Heteroatom

(2019) Soumalya Sinha et al.   ACS Catalysis

Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

(2019) Hunter Shirley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction

(2019) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water

(2018) Peter T. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic Reduction of CO2 to Formate by an Iron Schiff Base Complex

(2018) Asa W. Nichols et al.   INORGANIC CHEMISTRY

Urea-Based Multipoint Hydrogen-Bond Donor Additive Promotes Electrochemical CO2 Reduction Catalyzed by Nickel Cyclam

(2018) Eva M. Nichols et al.   ORGANOMETALLICS

Carbon Dioxide Reduction by Iron Hangman Porphyrins

(2018) Charles G. Margarit et al.   ORGANOMETALLICS

Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins

(2018) Eva M. Nichols et al.   Chemical Science

Mechanisms of catalytic reduction of CO2 with heme and nonheme metal complexes

(2018) Shunichi Fukuzumi et al.   Chemical Science

Kinetic and Mechanistic Effects of Bipyridine (bpy) Substituent, Labile Ligand, and Brønsted Acid on Electrocatalytic CO2 Reduction by Re(bpy) Complexes

(2018) Melissa L. Clark et al.   ACS Catalysis

Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry of Systems Approaching Reversibility

(2018) Jean-Michel Savéant   ACS Catalysis

Homogeneous Catalysis of Electrochemical Reactions: The Steady-State and Nonsteady-State Statuses of Intermediates

(2018) Cyrille Costentin et al.   ACS Catalysis

Organometallic Polymer Electrolyte Membrane Fuel Cell Bis-Ligand Nickel(Ii) Complex of 1,5-Di-P -Tolyl-3,7-Dipyridine-1,5,3,7-Diazadiphosphacyclo-Octane Catalyst

(2018) Marsil K. Kadirov et al.   Energy Technology

Pendant Hydrogen-Bond Donors in Cobalt Catalysts Independently Enhance CO2 Reduction

(2018) Alon Chapovetsky et al.   ACS Central Science

Electrocatalytic CO2 Reduction with Cis and Trans Conformers of a Rigid Dinuclear Rhenium Complex: Comparing the Monometallic and Cooperative Bimetallic Pathways

(2018) Weiwei Yang et al.   INORGANIC CHEMISTRY

Unexpected Solvent Effect in Electrocatalytic CO2 to CO Conversion Revealed Using Asymmetric Metalloporphyrins

(2018) Soumalya Sinha et al.   INORGANIC CHEMISTRY

A Thiourea Tether in the Second Coordination Sphere as a Binding Site for CO2 and a Proton Donor Promotes the Electrochemical Reduction of CO2 to CO Catalyzed by a Rhenium Bipyridine-Type Complex

(2018) Eynat Haviv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand “noninnocence” in coordination complexes vs. kinetic, mechanistic, and selectivity issues in electrochemical catalysis

(2018) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups

(2017) S. A. Chabolla et al.   FARADAY DISCUSSIONS

Dinuclear Rhenium Complex with a Proton Responsive Ligand as a Redox Catalyst for the Electrochemical CO2 Reduction

(2017) Alexander Wilting et al.   INORGANIC CHEMISTRY

Electrocatalytic CO 2 reduction using rhenium(I) complexes with modified 2-(2′-pyridyl)imidazole ligands

(2017) Soumalya Sinha et al.   INORGANICA CHIMICA ACTA

Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions

(2017) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Bimetallic Nickel–Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride

(2017) Ryan C. Cammarota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid

(2017) Souvik Roy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes

(2017) Ken T. Ngo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

(2017) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-light-driven methane formation from CO2 with a molecular iron catalyst

(2017) Heng Rao et al.   NATURE

Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups

(2017) S. A. Chabolla et al.   FARADAY DISCUSSIONS

Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction

(2017) Ming Gong et al.   ACS Central Science

Interrogating heterobimetallic co-catalytic responses for the electrocatalytic reduction of CO2 using supramolecular assembly

(2016) Charles W. Machan et al.   DALTON TRANSACTIONS

Electrochemical CO2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution

(2016) Zhe Weng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials

(2016) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Assisted Reduction of CO2 by Cobalt Aminopyridine Macrocycles

(2016) Alon Chapovetsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 through Supramolecular Assembly with Amino Acid-Modified Ligands

(2016) Charles W. Machan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective

(2016) Sumit Sahu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A pendant proton shuttle on [Fe4N(CO)12]− alters product selectivity in formate vs. H2 production via the hydride [H–Fe4N(CO)12]−

(2016) Natalia D. Loewen et al.   Chemical Science

A highly active nickel electrocatalyst shows excellent selectivity for CO2 reduction in acidic media

(2016) Gaia Neri et al.   Chemical Science

Bio-inspired cofacial Fe porphyrin dimers for efficient electrocatalytic CO2 to CO conversion: Overpotential tuning by substituents at the porphyrin rings

(2016) Zaki N. Zahran et al.   Scientific Reports

Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

(2015) Wonwoo Nam   ACCOUNTS OF CHEMICAL RESEARCH

Efficient electrocatalytic CO2 reduction with a molecular cofacial iron porphyrin dimer

(2015) Eman A. Mohamed et al.   CHEMICAL COMMUNICATIONS

Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates

(2015) Shunichi Fukuzumi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tailoring Electrocatalysts for Selective CO2 or H+ Reduction: Iron Carbonyl Clusters as a Case Study

(2015) Atefeh Taheri et al.   INORGANIC CHEMISTRY

Design of a Catalytic Active Site for Electrochemical CO2 Reduction with Mn(I)-Tricarbonyl Species

(2015) Jay Agarwal et al.   INORGANIC CHEMISTRY

Push or Pull? Proton Responsive Ligand Effects in Rhenium Tricarbonyl CO2 Reduction Catalysts

(2015) Gerald F. Manbeck et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Reductive Disproportionation of Carbon Dioxide by an Alkyl-Functionalized Pyridine Monoimine Re(I) fac-Tricarbonyl Electrocatalyst

(2015) Charles W. Machan et al.   ORGANOMETALLICS

An Iron Electrocatalyst for Selective Reduction of CO2 to Formate in Water: Including Thermochemical Insights

(2015) Atefeh Taheri et al.   ACS Catalysis

Influence of Weak Brønsted Acids on Electrocatalytic CO2 Reduction by Manganese and Rhenium Bipyridine Catalysts

(2015) Christoph Riplinger et al.   ACS Catalysis

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

(2014) Bojana Ginovska-Pangovska et al.   ACCOUNTS OF CHEMICAL RESEARCH

Arginine-Containing Ligands Enhance H2Oxidation Catalyst Performance

(2014) Arnab Dutta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A local proton source in a [Mn(bpy-R)(CO)3Br]-type redox catalyst enables CO2 reduction even in the absence of Brønsted acids

(2014) Federico Franco et al.   CHEMICAL COMMUNICATIONS

Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight

(2014) Wan-Hui Wang et al.   ChemSusChem

The Mechanism of Homogeneous CO2 Reduction by Ni(cyclam): Product Selectivity, Concerted Proton–Electron Transfer and C–O Bond Cleavage

(2014) Jinshuai Song et al.   INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Combined steric and electronic effects of positional substitution on dimethyl-bipyridine rhenium(I)tricarbonyl electrocatalysts for the reduction of CO 2

(2014) Steven A. Chabolla et al.   INORGANICA CHIMICA ACTA

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis

(2014) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Formation of a Mn-Based CO2 Reduction Catalyst Revealed by Pulse Radiolysis with Time-Resolved Infrared Detection

(2014) David C. Grills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential

(2014) Charles W. Machan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide

(2014) Christoph Riplinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

(2014) Kallol Ray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry

(2014) Charles W. Machan et al.   ORGANOMETALLICS

Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes

(2014) Yuki Suna et al.   ORGANOMETALLICS

Ultraefficient homogeneous catalyst for the CO2-to-CO electrochemical conversion

(2014) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO2Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry

(2013) Eric E. Benson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organometallic Catalysts for Use in a Fuel Cell

(2013) Takahiro Matsumoto et al.   ChemCatChem

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

The molybdenum oxotransferases and related enzymes

(2013) Russ Hille   DALTON TRANSACTIONS

Direct observation of the reduction of carbon dioxide by rhenium bipyridine catalysts

(2013) Matthew D. Sampson et al.   Energy & Environmental Science

Electrocatalytic Oxidation of Formate with Nickel Diphosphine Dipeptide Complexes: Effect of Ligands Modified with Amino Acids

(2013) Brandon R. Galan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Manganese as a Substitute for Rhenium in CO2 Reduction Catalysts: The Importance of Acids

(2013) Jonathan M. Smieja et al.   INORGANIC CHEMISTRY

Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst

(2013) Arnab Dutta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO2 Reduction by fac-Re(bpy)(CO)3Cl

(2013) John A. Keith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes

(2013) Wan-Hui Wang et al.   ACS Catalysis

Determining the Overpotential for a Molecular Electrocatalyst

(2013) Aaron M. Appel et al.   ACS Catalysis

Efficient H2generation from formic acid using azole complexes in water

(2013) Yuichi Manaka et al.   Catalysis Science & Technology

The Role of a Dipeptide Outer-Coordination Sphere on H2-Production Catalysts: Influence on Catalytic Rates and Electron Transfer

(2012) Matthew L. Reback et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

Binuclear rhenium(i) complexes for the photocatalytic reduction of CO2

(2012) Christian Bruckmeier et al.   DALTON TRANSACTIONS

Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure

(2012) Wan-Hui Wang et al.   Energy & Environmental Science

Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes

(2012) Candace S. Seu et al.   Energy & Environmental Science

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO

(2012) Jacob Schneider et al.   Energy & Environmental Science

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

(2012) Kendra P. Kuhl et al.   Energy & Environmental Science

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode

(2012) Jesse D. Froehlich et al.   INORGANIC CHEMISTRY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO

(2012) J. M. Smieja et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Directing the Reactivity of [HFe4N(CO)12]−toward H+or CO2Reduction by Understanding the Electrocatalytic Mechanism

(2011) M. Diego Rail et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Oxidation of Formate by [Ni(PR2NR′2)2(CH3CN)]2+Complexes

(2011) Brandon R. Galan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

(2009) Gabriele Centi et al.   CATALYSIS TODAY

Spectroelectrochemistry: the best of two worlds

(2009) Wolfgang Kaim et al.   CHEMICAL SOCIETY REVIEWS

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS