4.4 Article

An immobilized vanadium-binaphthylbishydroxamic acid complex as a reusable catalyst for the asymmetric epoxidation of allylic alcohols

Journal

TETRAHEDRON LETTERS
Volume 60, Issue 23, Pages 1518-1521

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.05.013

Keywords

Immobilized vanadium catalyst; Chiral hydroxamic acid; Reusable catalyst; Asymmetric epoxidation; Allylic alcohols

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An immobilized polymer-supported vanadium-binaphthylbishydroxamic acid (PS-VBHA) has been developed as an efficient, reusable catalyst for the asymmetric epoxidation of allylic alcohols. This PS-VBHA catalyst shows comparable catalytic performance to that of the parent V-BBHA catalyst and can be reused five times without significant loss of enantioselectivity. (C) 2019 Elsevier Ltd. All rights reserved.

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