4.7 Article

Relationship between the enthalpies of structural relaxation, crystallization and melting in metallic glass-forming systems

Journal

SCRIPTA MATERIALIA
Volume 166, Issue -, Pages 6-9

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2019.02.030

Keywords

Metallic glasses; Structural relaxation; Crystallization; Melting; Enthalpy

Funding

  1. Ministry of Education and Science of the Russian Federation [3.1310.2017/4.6]
  2. Deutscher Akademischer Austauschdienst (DAAD)

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A calorimetric study of structural relaxation, crystallization and melting of eleven metallic glass-forming systems is performed. It is found that the total heat release upon structural relaxation and crystallization approximately equals the heat absorption during melting, in line with a general thermodynamic consideration. A physical interpretation of this fact is presented. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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