4.7 Article

Selenium-doped phenolic resin spheres: Ultra-high adsorption capacity of noble metals

Journal

REACTIVE & FUNCTIONAL POLYMERS
Volume 142, Issue -, Pages 223-230

Publisher

ELSEVIER
DOI: 10.1016/j.reactfunctpolym.2019.06.019

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Funding

  1. National Natural Science Foundation of China [21871200]
  2. Joint Research Project of Jiangsu Province [BY2016051-01]
  3. Educational Commission of Jiangsu Province of China [17KJA150008]
  4. Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions

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Selenium-doped phenolic resin spheres (Se-RS) was synthesized by the reaction of 4,4'-selenodiphenol and resorcinol with formaldehyde catalyzing by ammonia. The whole reaction was completed within 5 min under the acceleration of ultra-sonication. Se-RS with controlled Se-content and Se-distribution were prepared in such manner. The obtained Se-RS showed enhanced Pd2+ and Au3+ adsorption capacity in aqueous solution. The adsorbed Au3+ can be further reduced to Au-0 at the surface of Se-RS in situ without additional reducing agent. The Se-RS exhibited exceptional extract capacity of gold from e-waste sewage and other aqua even its Au3+ concentration was extremely low.

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