4.8 Article

Angle-Resolved Electron Scattering from H2O near 0°

Journal

PHYSICAL REVIEW LETTERS
Volume 123, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.123.033401

Keywords

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Funding

  1. Engineering and Physical Sciences Research Council (UK) [EP/P009395/1]
  2. Hungarian Scientific Research Foundation (OTKA Grant) [K128621]
  3. EPSRC [EP/P009395/1] Funding Source: UKRI

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An electron beam, characterized by a high-angular discrimination (similar or equal to 0.7 degrees), has been used to measure the total (elastic plus inelastic) cross section of H2O in the energy range 3-100 eV. Broad coincidence is found with recent experiments, including a pronounced shoulder in the 6-12 eV region. However, at energies less than or similar to 6 eV, the present cross sections are similar or equal to 30% higher. Furthermore, forward scattering has been probed in the angular range 0 degrees-3.5 degrees and measures of the average (rotationally and vibrationally summed) differential elastic cross sections for incident energies <= 12 eV are obtained at a scattering angle similar or equal to 1 degrees. The measurements, which provide the first test of theoretical predictions in an angular region experimentally unexplored until now, are found to be within 1 standard deviation of corresponding ab initio R-matrix calculations.

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