4.7 Article

Effect of hierarchical porosity and phosphorus modification on the catalytic properties of zeolite Y

Journal

APPLIED SURFACE SCIENCE
Volume 382, Issue -, Pages 302-308

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2016.04.146

Keywords

Zeolite Y; Hierarchical; Phosphorus; Desilication; Catalytic cracking

Funding

  1. China Petroleum & Chemical Corporation (SINOPEC) [ST12088]

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The zeolite Y is considered as a leading catalyst for FCC industry. The acidity and porosity modification play important roles in determining the final catalytic properties of zeolite Y. The alkaline treatment of zeolite Y by dealumination and alkaline treatment with NaOH and NaOH&TBPH was investigated. The zeolites were characterized by X-ray diffraction, low-temperature adsorption of nitrogen, transmission electron microscope, NMR, NH3-TPD and IR study of acidity. Accordingly, the hierarchical porosity and acidity property were discussed systematically. Finally, the catalytic performance of the zeolites Y was evaluated in the cracking of 1,3,5-TIPB. It was found that desilication with NaOH&TBPH ensured the more uniform intracrystalline mesoporosity with higher microporosity, while preserving higher B/L ratio and moderate Bronsted acidities resulting in catalysts with the most appropriated acidity and then with better catalytic performance. (C) 2016 Elsevier B.V. All rights reserved.

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