Journal
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 67, Issue 4, Pages 585-591Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201900189
Keywords
1; 2-bis(benzimidazol-2-yl)ethane; antioxidant activity; copper(II) complex; crystal structure; electrochemistry; photophysical property
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1,2-Bis(benzimidazol-2-yl)ethane (bbe) and its copper(II) complex, {[Cu(bbe)Br-2](2)}center dot 2DMF (1), have been synthesized and characterized by elemental analysis, ultraviolet-visible, and infrared spectra. The single crystal structure analysis of 1 shows two crystallographically independent but chemically identical [Cu(bbe)Br-2] molecules. The coordination geometry of the copper atoms may best be described as a distorted tetrahedron (tau(4) = 0.740 for Cu1 and 0.696 for Cu2). The cyclic voltammogram of complex 1 represents quasi-reversible Cu2+/Cu+ pairs. in vitro antioxidant tests showed that complex 1 has significant antioxidant activity against superoxide and hydroxy radicals. Photoluminescence investigations showed that the fluorescence intensity of complex 1 is significantly weaker than that of the ligand. This may be due to the paramagnetic effect of divalent copper to cause quenching of fluorescence.
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