Article
Chemistry, Physical
Qihao Lin, Guoqing Chen, Shiwen Zou, Wenlong Zhou, Xuesong Fu, Shuyan Shi
Summary: Copper and its alloys are widely used in marine environments, and anisotropic corrosion affects the corrosion kinetics of copper. This paper studied the corrosion behavior of Cu(100) and Cu(111) using electrochemical impedance spectroscopy (EIS) after OCP tests. The results showed that Cu(100) exhibited better corrosion resistance. The corrosion mechanism of Cu(100)/Cu(111) in different stages was proposed based on the equivalent electrical circuit (EEC) diagrams.
Article
Automation & Control Systems
Dulyawat Doonyapisut, Byeongkyu Kim, Jung Kyu Kim, Eunseok Lee, Chan-Hwa Chung
Summary: Advancements in energy storage, photocatalysis, and sensors have generated large amounts of electrochemical impedance (EIS) data. Interpreting this data is challenging, but recent progress in machine learning (ML) models for EIS classification has been made. However, most models lack physical descriptor representation. In this study, variational autoencoders (VAE) were applied to EIS data analysis, achieving accurate classification, parameter prediction, and physical descriptor visualization.
ENGINEERING APPLICATIONS OF ARTIFICIAL INTELLIGENCE
(2023)
Article
Engineering, Electrical & Electronic
Maxime Van Haeverbeke, Michiel Stock, Bernard De Baets
Summary: An identification algorithm based on gene expression programming is introduced to support researchers in deciding which equivalent electrical circuit to use for analyzing electrochemical impedance spectroscopy measurements. This algorithm enhances the interpretability of resulting circuits by removing redundant components and departing from an initial population of widely applied circuits, enabling quick identification of known circuits capable of modeling the data.
IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT
(2021)
Article
Chemistry, Multidisciplinary
Funan Sun, Xiao Peng, Xiangling Bai, Zhiwei Chen, Ruizhen Xie, Bin He, Pengju Han
Summary: The corrosion behavior of copper under the influence of a conductive medium at different temperatures was investigated. A mathematical model was established to analyze the electrochemical properties of copper and a method for determining physical parameters was proposed.
Article
Electrochemistry
Hangyue Li, Zewei Lyu, Minfang Han
Summary: The Equivalent Circuit Model (ECM) is a powerful technique to analyze and compare Electrochemical Impedance Spectroscopy (EIS) data. However, noise poses a challenge to the accuracy of ECM. In this paper, a robust and fast algorithm is proposed to detect outliers, weigh the EIS data, and fit an ECM within a second, significantly reducing the impact of noise.
ELECTROCHIMICA ACTA
(2022)
Article
Computer Science, Information Systems
Maxime Van Haeverbeke, Michiel Stock, Bernard De Baets
Summary: In this review, the use of equivalent electrical circuits (EEC) in various application domains of electrochemical systems is explored. The aim is to assist electrochemical impedance spectroscopy (EIS) practitioners in evaluating and selecting EEC-based data analysis methods based on recent progress. The review covers EEC usage and interpretation, as well as providing software for automatically searching for relevant EECs in literature to fit user-supplied EIS measurements. Additionally, a comparison of impedimetric behavior and circuit modeling approaches is presented, along with discussions on complementary EIS data analysis strategies.
Article
Electrochemistry
William Ait-Idir, Peizhe Wu, Ricardo Sgarbi, Quentin Labarde, Salah Touhami, Meriem Daoudi, Assma El Kaddouri, Jean-Christophe Perrin, Jerome Dillet, Clemence Marty, Fabrice Micoud, Marian Chatenet, Olivier Lottin, Julia Mainka
Summary: In PEM fuel cells, oxygen diffusion is influenced by both the gas diffusion layer and the cathode catalyst layer. Experimental data shows that the low-frequency diffusion impedance is mainly related to the gas diffusion layer, while the high-frequency impedance is primarily affected by the ionomer film in the cathode catalyst layer. Therefore, the appropriate equivalent electrical circuit is the series connection of the Kulikovsky diffusion impedance and the ORR kinetics circuit.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Xiaohu Zhang, Xiong Zhang, Xianzhong Sun, Yabin An, Shuang Song, Chen Li, Kai Wang, Fangyuan Su, Cheng-Meng Chen, Fangyan Liu, Zhong-Shuai Wu, Yanwei Ma
Summary: This study analyzed the impedance characteristics of LICs and established an ECM model to describe their impedance behavior. It was found that the charging-discharging cut-off voltage and cycle numbers greatly influence the impedance and capacity retention rate of LICs.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Graziella Scandurra, Emanuele Cardillo, Carmine Ciofi, Luigi Ferro
Summary: This paper presents a method using Electrical Impedance Spectroscopy to characterize different commercial milks, allowing for classification of types and detection of lactose-free milk. It also has the capability to identify milk degradation before it is visible and distinguish between storage conditions and expiry.
APPLIED SCIENCES-BASEL
(2022)
Review
Biochemical Research Methods
Yang Liu, DongMing Li, Ji Qian, Bao Di, Gang Zhang, ZhenHui Ren
Summary: This review summarizes the application of electrical impedance spectroscopy (EIS) in plant root measurement, discussing experimental schemes, instruments, electrode, excitation frequency range, root electrical characteristics, equivalent circuit, and the combination of EIS with artificial intelligence. It suggests future research should focus on the miniaturization of measurement equipment, standardization of planting environment, and intelligentization of root diagnosis.
Article
Chemistry, Physical
Davood Peyrow Hedayati, Gita Singh, Michael Kucher, Tony D. Keene, Robert Boehm
Summary: This study aims to improve the performance of solid-state supercapacitors (SSCs) by simulating their impedance using a defined equivalent circuit (EC) model. Two models, a mathematical model and a physicochemical model, were used and the impedance was measured using electrochemical impedance spectroscopy (EIS). The physicochemical model showed higher approximation ability due to its more complex circuit design, but also required more modeling and optimization effort.
Article
Chemistry, Physical
Yuejiu Zheng, Zhihe Shi, Dongxu Guo, Haifeng Dai, Xuebing Han
Summary: In this paper, a low-frequency domain equivalent circuit model (LECM) based on the principle of electrochemical impedance spectroscopy (EIS) is proposed to simplify elements in the high-frequency region, identifying model parameters using only the low-frequency region of the EIS. It addresses the issue of traditional ECM dependence on time-domain working conditions.
JOURNAL OF POWER SOURCES
(2021)
Article
Materials Science, Multidisciplinary
Ru Bai, Shuguang Liu, Liqiang Yin, Changwang Yan, Ji Zhou, Lihe Lu, Lin Li
Summary: In this work, the damage degree of freeze-thaw of engineered cementitious composites (ECC) was assessed by electrochemical impedance spectroscopy (EIS) technique. The results showed that the EIS behavior of ECC varied with the freeze-thaw cycles, with the diameter of the Nyquist curve in high frequency gradually reduced and the volume resistance decreasing. A simplified microstructure and conductive paths were used to describe the freeze-thaw damage mechanism of ECC, and an equivalent circuit model of ECC exposed to freeze-thaw cycles was proposed.
MATERIALS & DESIGN
(2023)
Article
Green & Sustainable Science & Technology
Roma Agrahari, Radha Rani
Summary: A litre-scale multi-modular microbial fuel cell was operated using exo-electrogenic inoculum enriched from cow-dung for 45 days in batch mode, under three different circuit connections. Electrochemical analysis showed that the individual circuit had the highest power output and the lowest internal resistance. Additionally, the study reported COD removal rate and columbic efficiency of the MFC.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Chemistry, Physical
Marcel Esser, Gunnar Rohde, Christian Rehtanz
Summary: This paper demonstrated the development of a setup that performs impedance spectroscopy on commercial lithium-ion battery cells and packs using standard measurement equipment. The setup allows for a wider range of measurements and applications compared to commercial devices.
JOURNAL OF POWER SOURCES
(2022)
Article
Engineering, Chemical
Nagarjuna Reddy Paluvai, Hassan Hafeez, Dong-Ho Han, Heon-Yul Ryu, Choon-Soo Lee, Jin-Goo Park
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
(2017)
Article
Physics, Applied
Guk-Jin Kim, In-Seon Kim, Sung-Gyu Lee, Michael Yeung, Min-Su Kim, Jin-Goo Park, Hye-Keun Oh
JAPANESE JOURNAL OF APPLIED PHYSICS
(2017)
Article
Engineering, Electrical & Electronic
Guk-Jin Kim, In-Seon Kim, Sung-Gyu Lee, Michael Yeung, Min-Su Kim, Jin-Goo Park, Hye-Keun Oh
JOURNAL OF MICRO-NANOLITHOGRAPHY MEMS AND MOEMS
(2017)
Article
Materials Science, Multidisciplinary
Min-Su Kim, Nagarjuna Reddy Paluvai, Hyun-Tae Kim, Jin-Goo Park
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2017)
Article
Chemistry, Physical
Min-Su Kim, Muthukrishnan Purushothaman, Hyun-Tae Kim, Hee-Jin Song, Young-Woong Kim, Jin-Ho Ahn, Hye-Keun Oh, Jin-Goo Park
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2018)
Article
Engineering, Chemical
Hassan Hafeez, Heon-Yul Ryu, Nagarjuna Reddy Paluvai, Jin-Goo Park
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
(2018)
Article
Physics, Multidisciplinary
Sungmo Park, Changho Lee, Ilsin An, Min-Su Kim, Jin-Goo Park, Jin-ho Ahn
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
(2018)
Article
Engineering, Electrical & Electronic
Dong-Hwan Lee, Hyun-Tae Kim, Sung-Hae Jang, Jae-Hwan Yi, Eun-Suck Choi, Jin-Goo Park
MICROELECTRONIC ENGINEERING
(2018)
Article
Engineering, Mechanical
Hae-Jung Pyun, Muthukrishnan Purushothaman, Byoung-Jun Cho, Jung-Hwan Lee, Jin-Goo Park
TRIBOLOGY INTERNATIONAL
(2018)
Article
Materials Science, Multidisciplinary
Heon-Yul Ryu, Myeong-Jun Kim, Nagendra Prasad Yerriboina, Ramanathan Srinivasan, Jin-Goo Park
ELECTRONIC MATERIALS LETTERS
(2019)
Article
Materials Science, Multidisciplinary
Heon-Yul Ryu, Byoung-Jun Cho, Nagendra Prasad Yerriboina, Chan-Hee Lee, Jun-Kil Hwang, Satomi Hamada, Yutaka Wada, Hirokuni Hiyama, Jin-Goo Park
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
(2019)
Article
Materials Science, Multidisciplinary
In-Chan Choi, Hyun-Tae Kim, Nagendra Prasad Yerriboina, Jung-Hwan Lee, Lieve Teugels, Tae-Gon Kim, Jin-Goo Park
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
(2019)
Article
Chemistry, Physical
Min-Su Kim, Muthukrishnan Purushothaman, Hyun-Tae Kim, Hee-Jin Song, Jin-Goo Park
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2017)
Proceedings Paper
Optics
Guk-Jin Kim, In-Seon Kim, Michael Yeung, Min-Su Kim, Jin-Goo Park, Hye-Keun Oh
EXTREME ULTRAVIOLET (EUV) LITHOGRAPHY VIII
(2017)
Article
Materials Science, Multidisciplinary
Daekyun Jeong, Chefwi Lim, Myeonggi Kim, Kyunghoon Jeong, Jae-Hun Kim, Jiyoung Kim, Jin-Goo Park, Kyeong-Sik Min, Jaegab Lee
ELECTRONIC MATERIALS LETTERS
(2017)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)