Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 12, Pages 8185-8193Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01173
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Funding
- IISER Kolkata
- SERB [PDF/2017/000028, ECR/2016/001654]
- UGC
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Herein, we report on manganese-catalyzed regioselective Markovnikov addition and [2+2+2] cycloaddition of 2-carbonyl indanones with terminal alkynes. This method provides an efficient approach for the construction of all-carbon quaternary centers and complex polycyclic hydrocarbon frameworks by the formation of new carbon carbon single bonds in a regio- and stereoselective manner. Preliminary mechanistic experiments involving deuterium labeling, kinetic, catalytic, and stoichiometric reactions with plausible intermediates were performed to shed light on the reaction mechanism.
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