Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 80, Issue -, Pages 53-64Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2019.07.030
Keywords
Carbon-coating; Mg-Al LDO; Nanosheets; Cr(VI); Sorption capacity
Funding
- National Natural Science Foundation of China [51608512]
- Sichuan Science and Technology Program [2018JY0451]
- Major Training Program of the Education Department of Sichuan Province [17CZ0019]
- Science Foundation of the Education Department of Sichuan Province [17ZA0218]
- Science and Technology Support Program of Neijiang City [B018045]
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Carbon-coated Mg-Al layered double oxide (MgAl@C LDO) nanosheets were synthesized for the removal of hexavalent chromium (Cr(VI)) ions. Carbon coating could enhance the sorption capacity of Mg5Al1 LDO for the Cr(VI) removal. The sorption capacity of Mg5Al1@C LDO increased and then decreased with an increase in carbon-coated content, of which the Mg5Al1@C-2 with a carbon thickness of around 5.0 nm exhibited the best sorption capacity. The sorption behaviors of Mg5Al1@C-2 was explained by Langmuir sorption model, pseudo-second-order model, Weber-Morris model, and Boyd kinetic model. Mg5Al1@C-2 for Cr(VI) removal was a spontaneous, endothermic, and chemisorption process. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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