4.7 Article

Effect of halloysite nanotubes filler on polydopamine properties

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 555, Issue -, Pages 394-402

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2019.07.100

Keywords

Polydopamine; Halloysite nanotubes; Nanocomposite; Environmental remediation

Funding

  1. University of Palermo

Ask authors/readers for more resources

Hypothesis: Polydopamine (PDA) is widely used as hydrophilic coating for several applications. However, most of the methods studied to improve or manipulate PDA properties are multistep and time-consuming, and there is a need for versatile strategies aimed at controlling and modifying the properties of PDA. Experiments: PDA-halloysite nanocomposites were produced under different oxidation conditions in alkaline and acidic media and were characterized by UV-visible and attenuated total refraction-Fourier Transform Infrared spectroscopies, thermogravimetric analysis, porosimetry, scanning electron microscopy, X-ray diffraction and contact angle measurements against the reference PDA polymer. Findings: Inclusion of the inorganic halloysite nanofiller in the PDA component was found to affect the thermal properties of the nanocomposite as well as its structure, depending on the experimental conditions. The ability of the nanocomposites to adsorb organic dyes as possible membrane coatings for environmental remediation was also investigated by different models, suggesting promising applications as adsorbents for the treatment of wastewaters. (C) 2019 Elsevier Inc. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Archaeology

The colours of Segesta. Searching for the traces of the lost pigments

Veronica Ciaramitaro, Francesco Armetta, Monica de Cesare, Maria Luisa Saladino

Summary: The analysis and identification of color traces found in architectural elements and artifacts from the Archeological Park of Segesta (Trapani, Italy) were conducted using various non-invasive techniques. The study identified several pigments, including hematite, umber, vegetable black, and bone black. Despite the limited amount of detectable pigment, the investigation provided insight into the ancient civilizations and allowed for a glimpse into the past.

JOURNAL OF CULTURAL HERITAGE (2023)

Article Materials Science, Multidisciplinary

Luminescent YPO4:Eu@PVA dispersions for anti-counterfeiting ink applications

Francesco Armetta, Vitalii Boiko, Dariusz Hreniak, Rosina C. Ponterio, Maria Luisa Saladino

Summary: A method was developed to prepare luminescent inks of YPO4:Eu dispersions with PVA. YPO4:Eu nanoparticles were prepared by precipitation and hydrothermal treatment. The process included systematic studies on preparing stable colloidal system, investigating the parameters affecting its stability and UV-excited YPO4:Eu emission intensity. The interaction responsible for the dispersion stability was also investigated.

MATERIALS LETTERS (2023)

Article Chemistry, Physical

Thermoresponsive behavior of cyclodextrin inclusion complexes with weakly anionic alkyl ethoxy carboxylates

Larissa dos Santos Silva Araujo, Giuseppe Lazzara, Leonardo Chiappisi

Summary: This study investigates the temperature responsive behavior of inclusion complexes formed by weakly anionic alkyl ethoxy carboxylates and alpha and beta-cyclodextrins. The research shows that the inclusion complexes formed with ionized surfactant soften with increasing temperature and exhibit in-plane crystallization. This study provides insights for designing multi-responsive supramolecular systems based on cyclodextrins.

SOFT MATTER (2023)

Article Mathematics, Applied

An automatic L 1-based regularization method for the analysis of FFC dispersion profiles with quadrupolar peaks

G. Landia, G. V. Spinelli, F. Zama, D. Chillura Martino, P. Conte, P. Lo Meo, V. Bortolotti

Summary: Fast Field-Cycling Nuclear Magnetic Resonance relaxometry is a non-destructive technique used to investigate molecular dynamics and structure in various applications. This paper models the parameter identification problem as a constrained L1-regularized non-linear least squares problem and proposes an algorithm to compute the regularization parameter and model parameters. The convergence properties of the algorithm are analyzed, and extensive testing on synthetic and real data is conducted.

APPLIED MATHEMATICS AND COMPUTATION (2023)

Article Agriculture, Multidisciplinary

1H NMR-Based Metabolomics to Assess the Impact of Soil Type on the Chemical Composition of Nero d?Avola Red Wines

Paola Bambina, Alberto Spinella, Giuseppe Lo Papa, Delia Francesca Chillura Martino, Paolo Lo Meo, Onofrio Corona, Luciano Cinquanta, Pellegrino Conte

Summary: The soil effect on the micro-component composition of Nero d'Avola wines obtained from different locations was investigated using 1H NMR-based metabolomics. The study found that the differences among wines were not only due to the concentrations of various analytes but also to the characteristics of the H-bond network. Furthermore, the H-bond network was found to be related to the soil properties.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

Non-invasive investigation on pigments of the Aeolian Islands Neolithic pottery

Francesco Armetta, Dario Giuffrida, Maria Clara Martinelli, Viviana Mollica Nardo, Maria Luisa Saladino, Rosina Celeste Ponterio

Summary: The goal of this work is to contribute to the study of Neolithic painted pottery through the chemical characterization of samples from the Aeolian Islands. Analysis of 16 different sherds revealed the presence of pigments, including some no longer visible to the naked eye, and provided information about pottery differentiation using FT-IR.

MATERIALS LETTERS (2023)

Article Materials Science, Multidisciplinary

Bone diagenesis of archaeological human remains from Apulia (Italy) investigated by ATR-FTIR and XRF spectroscopy

Angela Sciatti, Paola Marzullo, Gabriella Chirco, Elena Piacenza, Federica Arcidiacono, Elena Dellu, Delia F. Chillura Martino

Summary: The analysis of organic and mineral content in biological samples helps determine post-mortem changes and the preservation status of ancient human remains. This study focuses on the physical-chemical characterization of bone specimens from different historical periods found in Apulia, Italy. Specific infrared and X-ray spectroscopies were used to evaluate the extent of diagenetic processes and elemental composition. Physical-chemical post-mortem transformations were influenced by soil composition, tissue specificity, burial rituals, probable dietary customs, and pathologies.

MATERIALS LETTERS (2023)

Article Green & Sustainable Science & Technology

Almonds By-Product Microcrystalline Cellulose as Stucco for Wooden Artifacts

Giulia D'Agostino, Rosalia Merra, Francesco Sottile, Giuseppe Lazzara, Maurizio Bruno

Summary: In the field of cultural heritage conservation, traditional products have been widely used for the plastic reintegration of wooden artifacts, although not specifically designed for this purpose. This study explores the use of cellulose pulp, obtained from softwood almond shells, as the most suitable material for wood restoration due to its material compatibility and potential for waste reuse. The cellulose pulp was combined with different binders to manufacture stuccos for wood consolidants, and also combined with the essential oil of Thymus capitaus to create stuccos with biocidal properties against fungal colonization or insect infestation. The physical flexion properties of the new materials were tested.

SUSTAINABILITY (2023)

Article Chemistry, Multidisciplinary

Antifouling Systems Based on a Polyhedral Oligomeric Silsesquioxane-Based Hexyl Imidazolium Salt Adsorbed on Copper Nanoparticles Supported on Titania

Alessandro Presentato, Eleonora La Greca, Luca Consentino, Rosa Alduina, Leonarda Francesca Liotta, Michelangelo Gruttadauria

Summary: The reaction of octakis(3-chloropropyl)octasilsesquioxane with hexylimidazole or decylimidazole resulted in the synthesis of HQ-POSS and DQ-POSS. HQ-POSS demonstrated higher antimicrobial activity against both Gram-positive and Gram-negative microorganisms. Due to its viscous nature, HQ-POSS was adsorbed onto the surface of active oxides for application purposes.

NANOMATERIALS (2023)

Article Chemistry, Physical

Reduced graphene oxide/silver nanoparticles/β-cyclodextrin nanosponges composites with improved photocatalytic activity

Antonella Di Vincenzo, Delia Chillura Martino, Elena Piacenza, Pellegrino Conte, Alberto Pettignano, Giuseppe Lazzara, Paolo Lo Meo

Summary: Significant activity improvement was achieved by associating graphene oxide-silver composite photocatalysts with cyclodextrin-based nanosponge materials, due to the synergistic effect provided by the supramolecular host abilities of the nanosponge. The nanosponge-based materials showed enhanced performances in the oxidative photodegradation of organic pollutants and good recyclability. The local concentration effect provided by the nanosponge is attributed to the activity improvement.

APPLIED SURFACE SCIENCE ADVANCES (2023)

Article Chemistry, Multidisciplinary

Highly Functionalized SWCNTs with a Dopamine Derivative as a Support for Pd Nanoparticles: A Recyclable Catalyst for the Reduction of Nitro Compounds and the Heck Reaction

Vincenzo Campisciano, Laura Valentino, Maria Laura Alfieri, Valeria La Parola, Alessandra Napolitano, Francesco Giacalone, Michelangelo Gruttadauria

Summary: This study successfully functionalized SWCNTs by reacting with dopamine azide at high temperature while maintaining the integrity of the pi-network. The properties and composition of the functionalized material were characterized using various techniques, and palladium species were immobilized for use as a catalyst in reduction and Heck reactions.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

Article Chemistry, Applied

Origin of the solid-state luminescence of MIL-53(Al) and its connection to the local crystalline structure

L. G. Barbata, D. Scavuzzo, R. Ettlinger, M. M. Calvino, G. Lazzara, F. M. Gelardi, S. Agnello, M. Cannas, Russell E. Morris, G. Buscarino

Summary: Metal-organic frameworks (MOFs) are extensively studied for their unique surface properties, with Breathing MOFs gaining recent interest for their ability to undergo structural changes based on environmental factors. Understanding the relationship between crystal structures and photoluminescence properties is crucial for designing next-generation sensors or light emitting devices.

MICROPOROUS AND MESOPOROUS MATERIALS (2023)

Article Green & Sustainable Science & Technology

Opuntia ficus-indica (L.) Mill. and Opuntia stricta (Haw.) Haw. Mucilage-Based Painting Binders for Conservation of Cultural Heritage

Giulia D'Agostino, Rosalia Merra, Natale Badalamenti, Giuseppe Lazzara, Maurizio Bruno, Francesco Sottile

Summary: The possibility of using agricultural waste materials for the conservation of cultural and artistic heritage has led to important technological developments. This study investigates the binding properties of mucilage from two species of Opuntia plants collected in Sicily, Italy. Through chemical analysis, the composition of the mucilage was studied, revealing significant differences between the two species. The study also explores how different binders affect the appearance of dispersed pigments on different substrates.

SUSTAINABILITY (2023)

Article Chemistry, Multidisciplinary

Encapsulation of a-Lipoic Acid in Halloysite Nanotubes

Andrii Melnyk, Olena Chyhyrynets, Giuseppe Lazzara

Summary: This study investigated the degradation process of a-lipoic acid under the influence of ultraviolet radiation and thermal stress in its native state and in a halloysite-based nanocomposite. The results showed that adding a-lipoic acid to halloysite significantly improved its resistance to UV light and heat, making it a potential material for enhancing the photodegradation resistance of pharmaceutical drugs or sunscreen cosmetics.

APPLIED SCIENCES-BASEL (2023)

Article Biochemistry & Molecular Biology

From micro to macro: Physical-chemical characterization of wheat starch-based films modified with PEG200, sodium citrate, or citric acid

Veronica Ciaramitaro, Elena Piacenza, Paolo Lo Meo, Calogero Librici, Martina M. Calvino, Pellegrino Conte, Giuseppe Lazzara, Delia F. Chillura Martino

Summary: The researchers modified starch films by adding citric acid and polyethylene glycol 200, which improved their properties and inhibited starch chains' retrogradation and recrystallization. By observing the mobility of the polymer chains through ss-NMR, the study revealed a different polymer chain structural organization, which explained the film's higher resistance to thermal degradation and greater elongation at the break.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Chemistry, Physical

Mechanistic exploration of Co doping in optimizing the electrochemical performance of 2H-MoS2/N-doped carbon anode for potassium-ion battery

Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu

Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Addressing the synchronized impact of a novel strontium titanium over copolymerized carbon nitride for proficient solar-driven hydrogen evolution

Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng

Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Magnetic-driven Interleukin-4 internalization promotes magnetic nanoparticle morphology and size-dependent macrophage polarization

Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas

Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Polyamide nanofiltration membranes by vacuum-assisted interfacial polymerization: Broad universality of Substrate, wide window of monomer concentration and high reproducibility of performance

Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu

Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Comparing polymer-surfactant complexes to polyelectrolytes

Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott

Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Crosslinking alginate at water-in-water Pickering emulsions interface to control the interface structure and enhance the stress resistance of the encapsulated probiotics

Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu

Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Multi-layering of carbon conductivity enhancers for boosting rapid recharging performance of high mass loading lithium ion battery electrodes

Sang Ho Lee, Yige Sun, Patrick S. Grant

Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Defect engineering induces Mo-regulated Co9Se8/FeNiSe heterostructures with selenium vacancy for enhanced electrocatalytic overall water splitting in alkaline

Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing

Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Surfactant-free microemulsions (SFMEs) as a template for porous polymer synthesis

Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz

Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Morphology regulation of isomeric covalent organic frameworks for high selective light scattering detection of lead

Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao

Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Preparation and dynamic color-changing study of fluorescent polymer nanoparticles for individualized and customized anti-counterfeiting application

Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan

Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Employing polyaniline/viologen complementarity to enhance coloration and charge dissipation in multicolor electrochromic display with wide modulation range

Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li

Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Facile constructing Ti3C2Tx/TiO2@C heterostructures for excellent microwave absorption properties

Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu

Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Reversible crowdedness of pH-responsive and host-guest active polymersomes: Mimicking μm-sized cell structures

Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans

Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Potassium regulating electronic state of zirconia supported palladium catalyst and hydrogen spillover for improved acetylene hydrogenation

Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu

Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)