Journal
APPLIED PHYSICS LETTERS
Volume 108, Issue 11, Pages -Publisher
AIP Publishing
DOI: 10.1063/1.4943973
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Funding
- EPSRC [EP/L000202, EP/M009580/1, EP/J017361/1, EP/M009602/1, EP/M011631/1]
- EPSRC [EP/K016288/1, EP/M009580/1, EP/M009602/1, EP/J017361/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [1413788, EP/K016288/1, EP/M009602/1, EP/J017361/1, EP/M009580/1] Funding Source: researchfish
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The ternary V-VI-VII chalcohalides consist of one cation and two anions. Trivalent antimony-with a distinctive 5s(2) electronic configuration-can be combined with a chalcogen (e.g., S or Se) and halide (e.g., Br or I) to produce photoactive ferroelectric semiconductors with similarities to the Pb halide perovskites. We report-from relativistic quasi-particle self-consistent GW theory-that these materials have a multi-valley electronic structure with several electron and hole basins close to the band extrema. We predict ionisation potentials of 5.3-5.8 eV from first-principles for the three materials, and assess electrical contacts that will be suitable for achieving photovoltaic action from these unconventional compounds. (C) 2016 AIP Publishing LLC.
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