Review
Energy & Fuels
Dunyu Liu, Chaoran Wang, Yunpei Fan, Qiuqi Liu, Xudong Wang, Kailong Xu, Jing Jin, Jingjing Ma, Jinchen Ma
Summary: Chemical looping combustion (CLC) of coal for carbon capture utilization and storage is an effective technology to reduce carbon emission. However, there is uncertainty in mercury emission from both air and fuel reactor. This paper aims to reveal the mechanisms for the transformation of mercury-related species.
Article
Chemistry, Physical
Muflih A. Adnan, Abdulhadi A. Al-Zahrani, Tamanna I. Haque, Shaikh A. Razzak, Mohammad M. Hossain
Summary: A new oxygen carrier material was developed for fluidized chemical looping combustion process, serving as both a catalyst and a source of solid phase oxygen. Cerium modification improved the thermal stability of γ-Al2O3, reducing its interaction with MnOx. Experimental results showed that Ce modification enhanced the thermal stability of γ-Al2O3 and improved the reduction and re-oxidation performance of the samples.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Richard A. Newby, Dale L. Keairns, Robert W. Stevens
Summary: The objective of this study was to estimate the cost of commercial production of oxygen carriers (OCs) for large-scale application in the chemical looping combustion (CLC) power generation industry. Two production facility scenarios were considered, and two OC production techniques were addressed. The estimated OC product costs can be used to guide development and determine the maximum OC makeup rate for achieving a designated cost-of-electricity (COE) reduction goal.
Article
Energy & Fuels
Pietro Bartocci, Alberto Abad, Arturo Cabello Flores, Margarita de las Obras Loscertales
Summary: To address the scale-up challenges of Chemical Looping Processes, the development of efficient and affordable oxygen carriers is crucial. Ilmenite, an ore-derived oxygen carrier, has been identified as an abundant and low-cost option. This paper provides insights into its preparation, reactivity, and performance compared to other carriers, along with its thermodynamic properties and kinetics. The paper also explores its compatibility with various fuels (solid, liquid, gaseous, including biofuels) and discusses important considerations such as cost, environmental sustainability, oxygen transport capacity, as well as issues related to fluidized bed reactors, such as agglomeration and attrition behavior. Furthermore, the paper investigates the interaction between ilmenite and fuels, including the impact of impurities and coke deposition on the gasification rate of solid fuels.
Article
Energy & Fuels
Yanxin Yang, Yu Qiu, Zhenwu Zhang, Sheng Wang, Hui Chen, Dewang Zeng, Rui Xiao
Summary: Chemical looping methane steam reforming using Ni-promoted Fe2O3/Al2O3 catalysts showed high CH4 conversion, H2 yield, and low carbon deposition due to the facilitation of CH4 activation and enhancement of Fe2O3 reduction by Ni. The synergistic effect between Ni and Fe2O3 can lead to the development of highly active and stable oxygen carriers.
Article
Energy & Fuels
Weixiang Zhang, Lina Zhang, Sijia Pei, Jiarui Wang, Dawei Liu, Xiaoxun Ma, Maohong Fan, Long Xu
Summary: One of the most significant topics in chemical looping reforming technology is the design and preparation of appropriate oxygen carriers with high reactivity and excellent stability. This study focuses on the chemical looping reforming of methane using cobalt-doped Ce-based oxygen carriers synthesized via the solution combustion method with the assistance of coconut shell. The introduction of cobalt decreases the crystallite size, increases oxygen vacancy concentration and lattice oxygen mobility, and the addition of coconut shell further enhances these positive changes and the interaction between Ce and Co.
Article
Chemistry, Applied
Shiwei Ma, Fang Cheng, Junguang Meng, Huijun Ge, Ping Lu, Tao Song
Summary: The feasibility of using Ni-enhanced red mud in chemical looping steam methane reforming (CL-SMR) was evaluated. It was found that the Ni-enhanced red mud displayed desirable reactivity and cyclic stability, with CO selectivity reaching 94.1% and H-2/CO ratio of 2.01 at the most suitable temperature of 900 C. The Ni species effectively activated the C-H bond of methane and facilitated the transfer of lattice oxygen.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Applied
Jun Young Kim, Zezhong John Li, Naoko Ellis, C. Jim Lim, John R. Grace
Summary: A jet attrition model has been developed to predict the evolution of particle size distribution in fluidized beds, showing good agreement with experimental results. The model considers fragmentation, abrasion, and material fatigue, with fitting parameters determined based on nonlinear least squares regression.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Chemistry, Applied
Xinfei Chen, Luwen Wang, Yan Lin, Tao Zeng, Zhen Huang, Yongqi Zhang, Ya Xiong, Jun Li, Lisheng Deng, Hongyu Huang
Summary: Ca2Fe2O5/Zr0.5Ce0.5O2 exhibited excellent reactivity in chemical looping dry reforming of methane. The migration of lattice oxygen during redox process was explored, revealing the release of lattice oxygen, structural change, and crystalline phase transformation. The understanding of oxygen migration provides a reference for improving the cyclic stability of Ca2Fe2O5/Zr0.5Ce0.5O2.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Energy & Fuels
Ambrose Ugwu, Mogahid Osman, Abdelghafour Zaabout, Shahriar Amini
Summary: Gas switching dry reforming (GSDR) efficiently converts CO2 and CH4 into syngas for GTL syntheses through redox cycles with alternating supply of reducing and oxidizing gases. Experimental demonstrations show achievable H-2/CO molar ratios suitable for methanol production.
Article
Thermodynamics
Haodong Huang, Jinchen Ma, Haibo Zhao, Chuguang Zheng
Summary: This work investigates the behavior of coal-derived chlorine in chemical looping combustion (CLC) and the potential adverse impacts of primary gaseous chlorine (HCl) on a Cu-based oxygen carrier (OC). The inactivation mechanism of the sol-gel-derived CuO/Al2O3 OC is studied. It is found that HCl is the main gaseous chlorine in coal CLC and shows high reactivity towards CuO. The presence of HCl can result in corrosion and degradation of the OC.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2023)
Article
Energy & Fuels
Ranjani Siriwardane, Jarrett Riley, William Benincosa, Samuel Bayham, Michael Bobek, Douglas Straub, Justin Weber
Summary: The Copper-Ferri-Manganese-Aluminate spinel oxygen carrier developed at NETL has shown promising results for chemical looping combustion with methane, with high attrition resistance and oxygen transfer capacity. The carrier prepared at a commercial manufacturing facility displayed similar performance to lab scale preparations, demonstrating satisfactory methane conversion and high particle durability during testing.
Article
Engineering, Chemical
Jon Powell, Suwimol Wongsakulphasatch, Rungrote Kokoo, Nichamon Noppakun, Chaiwat Prapainainar, M. A. A. Aziz, Suttichai Assabumrungrat
Summary: The study investigated the impact of operating conditions on hydrogen production and process thermal efficiency for the SE-CL-SMR process, finding that factors such as CaO/C ratio, MeO/C ratio, and oxidising agent species play a significant role. The introduction of CaO reduces coke formation, while increasing MeO/C and S/C enhances hydrogen yield and purity. The presence of CuO allows for adiabatic reactor operation and an increase in NiO:CuO ratio leads to higher methane conversion rates.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2021)
Article
Energy & Fuels
Giovanny S. de Oliveira, Ciro E. S. Lobo, Carlos E. A. Padilha, Domingos F. S. Souza, Juan A. C. Ruiz
Summary: Brazil aims to reduce its CO2 emissions by utilizing glycerin in Chemical Looping Combustion (CLC). The study evaluates the feasibility of using glycerin in CLC and finds that the addition of ethanol improves combustion efficiency, while the addition of methanol reduces efficiency.
Article
Thermodynamics
Feng Liu, Jing Liu, Yu Li, Ruixue Fang, Yingju Yang
Summary: The study found that spinel NiFe2O4 can be directly reduced into Ni-Fe alloy in CO atmosphere, with a reaction rate two times faster than Fe2O3. Factors such as reaction temperature, CO concentration, and heating rate can enhance the reactivity of NiFe2O4. The reactivity of lattice oxygen in NiFe2O4 is primarily influenced by the coordination environment of oxygen formed by different Ni/Fe atoms.