4.7 Article

Development of Ti1.02Cr2-x-yFexMny (0.6≤x≤0.75, y=0.25, 0.3) alloys for high hydrogen pressure metal hydride system

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 44, Issue 29, Pages 15087-15099

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2019.03.241

Keywords

Intermetallic; Hydrogen storage; Ti-x(CrFeMn)(2) alloy; Heat treatment; Hydrogen refueling station

Funding

  1. Beijing Municipal Commission of Science and Technology [Z17110000091702]
  2. National Natural Science Foundation of China [51431001, 51771002, U1607126, 21321001, 51804174]
  3. Natural Science Foundation of Shandong Province [ZR2017BEE010]

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To save compressor investment and promote operation efficiency of hydrogen refueling station, the hydrogen storage alloys for high-pressure hydrogen metal hydride tank is developed. Ti1.02Cr2-x-yFexMny (0.6 <= x <= 0.75, y=0.25, 0.3) alloys with main structure of C14 type Laves phase and low dehydrogenation enthalpy were prepared by plasma arc melting and heat treatment. Pressure-composition-temperature measurements show that hydrogen desorption plateau pressures increase with Cr substituted by Fe increasing. The maximum and reversible hydrogen storage capacities are more than 1.85 and 1.65 wt% at 201 K respectively. The hydrogen desorption plateau slopes are all less than 0.5. The symmetry weakening of 2a sites may deteriorate the plateau slop characteristic. Ti1.02Cr0.95Fe0.75Mn0.3 and Ti1.02Cr1.0Fe0.75Mn0.25 alloys are suitable for high pressure hybrid tank which can supply the effective hydrogen (more than 70 MPa) about 40.0, 44.2, 46.9 kg/m(3) with 45, 70, 90 MPa compressor, respectively. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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