Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 44, Issue 41, Pages 22983-22990Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2019.07.008
Keywords
Copper selenide; Intersected-nanosheets; Nanotubes; Oxygen evolution reaction
Categories
Funding
- Foundation of National Key Basic Research and Development Program [2010CB631001]
- Graduate Innovation Fund of Jilin University [2016173]
- Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) [2017TD-09]
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Rational nanostructure design is the key point to prepare catalysts with superior catalytic performance, and tedious preparation method limits them large-scale application. Here, a Cu2Se with fluffy intersected-nanosheets decorating nanotubes structure were prepared by a simple and rapid solution-immersion method at room temperature. The hollow hierarchical structure on a good conductor Cu foam (CF) enlarges surface available sites, enhances the conductivity of electrode materials, then endowing the catalyst with quick charge/mass transportation and favorable oxygen evolution reaction (OER) performance. In alkaline medium, our as-prepared Cu2Se/CF electrode demonstrates high OER performance, especially for lower overpotential (200 mV at 10 mA cm(-2)) compared with the previously reported Cu-based catalysts. Moreover, the Cu2Se catalyst could afford galvanostatic test of 10 mA cm(-2) test over 12 h and present superior OER tolerance. These results indicate that the Cu2Se catalyst via cost efficiency and efficient solution-immersion method could be applied to large-scale efficient OER. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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