Article
Multidisciplinary Sciences
Changwei Zhao, Yanjun Zhang, Yuewen Jia, Bojun Li, Wenjing Tang, Chuning Shang, Rui Mo, Pei Li, Shaomin Liu, Sui Zhang
Summary: By controlling the spatial and temporal aspects of interfacial polymerization, a nanofiltration membrane with fast permeation and high Cl-/SO42- selectivity has been constructed. This membrane demonstrates ultra-permeability and excellent ion-ion separation, making it ideal for sustainable water treatment applications such as water purification and desalination.
NATURE COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Tianshi Yang, Kai-Yu Wang, Tai-Shung Chung
Summary: The study successfully fabricated TFC NF hollow fiber membranes using pressure-assisted interfacial polymerization technique, showing high pure water permeability and molecular weight cut-off, as well as high rejection rates towards magnesium sulfate and cephalexin. These membranes also demonstrated stable rejection performance in high salinity solutions, suggesting great potential for applications in chlor-alkali and pharmaceutical industries.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Multidisciplinary Sciences
Hao Yang, Jinhui Xu, Hui Cao, Jie Wu, Dan Zhao
Summary: Transition metal-based homogeneous photocatalysts offer a wealth of opportunities for organic synthesis, but they can be rare and challenging to immobilize for recycling. In this study, the authors successfully recovered ruthenium and iridium photocatalysts using covalent organic framework (COF) membranes with tunable pore sizes. The recovered catalysts showed high catalytical performance, recovery rates, and permeance in multiple photochemical reactions, and the COF membranes also facilitated the isolation and purification of small organic molecules. These findings have the potential to revolutionize pharmaceutical and fine chemical synthesis.
NATURE COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Yahui Li, Daoguang Wang, Junfeng Wang, Yi Nie
Summary: Efficient separation of organic compounds from high salinity brines is crucial for achieving zero liquid discharge. This study investigated the separation of major organic components and ions from reverse osmosis concentrate using commercial nanofiltration membranes. The results showed that the membranes had high rejection efficiency for organic compounds and ions in high salinity brines.
Article
Engineering, Environmental
Huihui Deng, Jing Huang, Cunqi Qin, Tianhui Xu, Huagang Ni, Peng Ye
Summary: Graphene-based membranes, especially the composite membrane of hydroxylated graphene (GOH) and graphene oxide (GO), exhibit high water permeability and effective molecule retention, making them suitable for separation applications.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Engineering, Chemical
Huawen Peng, Yongjin Hu, Shaoping Li, Jingyi Rao, Qiang Zhao
Summary: This study utilized sulfonium salts to modify polyamide nanofiltration membranes for high performance Mg2+/Li+ separation. The modification resulted in enhanced positive charge and loose structures of the membranes, leading to a 4.3 times improved permeance. The modified membrane exhibited high water permeance and good Mg2+/Li+ selectivity, along with good stability. This study demonstrates the promising potential of sulfoniums for engineering advanced lithium extraction membranes.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Chi Siang Ong, Huang Teik Lay, Navin Raj Tamilselvam, Jia Wei Chew
Summary: The study involved the preparation of an organic solvent-resistant membrane through urethane bonds formation and further cross-linking with BDG for enhanced stability. The cross-linked polycarbonate membranes showed improved solvent resistance with a maximum swelling degree of 6%, as well as better mechanical and thermal stability, and excellent permeance and rejection performance. BDG was demonstrated as an attractive cross-linker for transforming polycarbonate microfiltration membranes towards organic solvent filtration applications.
Article
Engineering, Chemical
Manas Ranjan Puhan, Bhaumik Sutariya, Santanu Karan
Summary: This study revisited the alkali hydrolysis post-treatment of a polyamide nanofiltration membrane. It was found that the post-treatment increased the pure water permeance without affecting solute rejection, possibly due to the physical restructuring of the polyamide layer or the restructuring of the support layer and interface.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Natalia Garcia Domenech, Finn Purcell-Milton, Adrian Sanz Arjona, Maria-Luisa Casasin Garcia, Maeve Ward, Marc Brunet Cabre, Aran Rafferty, Kim McKelvey, Peter Dunne, Yurii K. Gun'ko
Summary: Nanotechnology has led to the development of sustainable water purification technologies, and two-dimensional nanomaterials show great promise as nanofiltration membranes. This study demonstrates the production and testing of a highly efficient nanofiltration membrane made from water-exfoliated boron nitride, which effectively removes water-soluble dyes. Comparison with membranes produced using different methods highlights the superior performance of water-exfoliated BN membranes.
Article
Chemistry, Multidisciplinary
Zhijie Zhang, Xiao Xiao, Yihao Zhou, Linjun Huang, Yanxin Wang, Qinglin Rong, Zhenyang Han, Huaijiao Qu, Zhijun Zhu, Shumao Xu, Jianguo Tang, Jun Chen
Summary: A high-performance graphene oxide membrane was constructed by introducing positively charged polyethylenimine-grafted GO to negatively charged GO nanosheets, showing high water permeance and precise molecular separation ability. The membrane exhibited excellent water permeance and organic removal selectivity, providing valuable insights for the development of smart nanofiltration technology.
Article
Engineering, Chemical
Yuxi Feng, Huawen Peng, Qiang Zhao
Summary: By synthesizing a new QBPD monomer and modifying the PEI membrane, the rejection rate and pure water flux of MgCl2 were improved, showing good stability and potential for lithium extraction from salt lakes with high Mg2+/Li+ ratio.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Yawen Zhang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jinghui He, Jianmei Lu
Summary: In this study, stable lamellar membranes were prepared by electrostatic attraction and hydrogen bond formation between polycation polyethyleneimine (PEI) and negatively charged MXene. The interlayer d-spacing of the membrane could be changed by adjusting the suspension pH, allowing for precise molecular separation and high organic solvent penetration. Moreover, the insertion of PEI did not hinder the passage of water molecules. The optimized MXene-PEI membranes showed excellent channel stability.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Chemical
Xufei Liu, Yuxi Feng, Yunxia Ni, Huawen Peng, Shaoping Li, Qiang Zhao
Summary: This study demonstrates that charge intensification of loose structure nanofiltration membranes can achieve high flux and selective separation of Mg2+/Li+ mixtures. A new electrolyte monomer (QTHIM) was synthesized to modify the polyethyleneimine-based polyamide membranes (PEI-TMC), resulting in a high-permeance nanofiltration membrane (PEI-TMC-QTHIM). The modified membrane exhibited loose structures, enhanced positive charge, high water permeance (-33 L m-2 h-1 bar-1), good MgCl2 rejection (-92%), and high flux for a mixture with a Mg2+/Li+ ratio of 100 (-170 L m-2 h-1). Notably, the flux of the modified membrane was approximately 6 times higher than that of the original membrane.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Physical
Hao Luo, Huawen Peng, Qiang Zhao
Summary: A new monomer HMTAB was designed to improve the performance of lithium extraction nanofiltration membranes, showing higher water flux and stable performance in the experiment.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Chemical
Huimin Zhou, Xuesong Li, Yang Li, Ruobin Dai, Zhiwei Wang
Summary: By utilizing functionalized nanovesicles to modify nanofiltration membranes, the surface charge density and pore size can be tuned to efficiently separate dye and salt at high salinity, while maintaining high separation stability and water permeability.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Chemical
Ming-Jian Tang, Mei-Ling Liu, Lu Li, Guo-Jiang Su, Xiang-Yu Yan, Can Ye, Shi-Peng Sun, Weihong Xing
Summary: Molecular desalination is widely used in various industries and requires efficient and anti-fouling separation technologies. Interfacial polymerization is a promising method for constructing selective nanofiltration membranes, but the hydrolysis of residual acyl chlorides hinders fine desalination and anti-fouling. A solvation-amination-synergy strategy is proposed to inhibit hydrolysis and promote amination, resulting in a quantitatively fabricated electroneutral nanofiltration membrane with high water permeance and superb anti-fouling abilities.
Article
Engineering, Chemical
Jun Pan, Fangli Zhang, Zhaohui Wang, Shi-Peng Sun, Zhaoliang Cui, Wanqin Jin, Omar Bamaga, Hani. Abulkhair, Mohammed Albeirutty, Enrico Drioli
Summary: The composite hydrophobic PFPE/PVDF membranes show promising anti-fouling and anti-wetting performance, making them highly suitable for membrane distillation and membrane crystallization applications.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Environmental
Qian Wang, Qin-Yuan He, Liu-Lin Zhao, Yue Wang, Rong Fang, Cong Luo, Wei-Tong Lu, Hong-Ya Jiang, Shi-Peng Sun, Xue-Li Cao
Summary: This study constructed core-shell nanofibrous substrates with tunable wettability using coaxial electrospinning technology. Defect-free thin-film nanofibrous composite membranes were prepared via interfacial polymerization, and cucurbit[6]uril was embedded to enhance the solvent transport channels and improve methanol permeance. The membrane shows potential for solvent recovery in chemical and pharmaceutical fields, and provides new ideas for the design and modification of novel nanofiltration membranes.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Sheng-Nan Tao, Yue Wang, Zheng-Jun Fu, Yi-Meng Wang, Qing-Lin Lu, Ming-Jian Tang, Wei-Jian Wang, Bhekie B. Mamba, Shi-Peng Sun, Zhen-Yuan Wang
Summary: An efficient NaClO activation method is developed to tailor the selective layer of cross-linked PI/PES dual-layer hollow fiber membranes, resulting in a negatively charged surface and a more open pore structure. These membranes show high separation efficiency and long-term stability for the separation of mono/divalent ions in industries.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Review
Environmental Sciences
Zhengzhong Zhou, Tian-Dan Lu, Shi-Peng Sun, Qian Wang
Summary: This article summarizes the application of coordination chemistry in nanofiltration membranes. The participation of coordination chemistry has resulted in membranes with uniform pores, better antifouling properties, and high hydrophilicity. The effects and mechanisms of coordination chemistry on membrane performance are discussed, and prospects for further advancements in nanofiltration processes are given.
Article
Energy & Fuels
Jiawen Li, Chao Wang, Haoyu Wu, Jiaxuan Zhang, Ming Zhang, Qian Zhu, Yiqun Fan, Hui Liu, Wenshuai Zhu
Summary: Using alkaline ternary deep eutectic solvents (DESs) as absorbents, an effective and reversible strategy for capturing and recycling SO2 was proposed, showing great potential for environmental protection and high-value utilization.
Article
Engineering, Chemical
Lele Xu, Zhuotai Jia, Mengke Guo, Zai-Sha Mao, Yiqun Fan, Qinghua Zhang, Chao Yang
Summary: A V-shaped punched baffle (VSPB) is developed to enhance fluid mixing in a stirred tank. Experimental results show that VSPB reduces mixing time by a maximum of 23% and 14.7% compared to standard baffles (SB) and standard punched baffles (SPB) at low speeds. Simulation results demonstrate that the punched baffle significantly increases fluid velocity and turbulence in the baffle region, forming tiny vortices.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Engineering, Chemical
Shenglan Liu, Yishu Yan, Yinxiang Xu, Chao Yang, Yiqun Fan, Junbo Xu
Summary: The stiffness of phenolic resins is affected by methylene bridges and branched phenolic rings. Introducing naphthols does not significantly improve stiffness due to the counterbalance between nonbonded energies and the decrease in methylene bridges. In the case of cyanate ester modified phenolic resins (CEPF), chain-to-chain bridges of triazine rings increase the Young's modulus and contribute more to stiffness compared to rigid naphthols. The trend from plastic to cured state can be observed in the mean squared displacement and Young's modulus. These findings support the molecular design of phenolic resins to optimize stiffness.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Biotechnology & Applied Microbiology
Long Wang, Liu-Lin Zhao, Qin-Yuan He, Dan-Dan Shao, Shi-Peng Sun, Xue-Li Cao
Summary: By constructing photocatalytic membranes based on Fe3O4-doped g-C3N4 (FeCN)/TiO2, the problem of dye adsorption on the membrane was successfully solved, and the separation efficiency and stability of the membrane were improved. This work provides new opportunities for designing high-efficiency self-cleaning membranes to solve membrane fouling based on low-cost materials.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2023)
Article
Engineering, Chemical
Qian Chen, Lan Hong, Shang-Kun Jiang, Chun-Xu Zhang, Shan Wang, Wei-Xing Li, Shi-Peng Sun, Mei -Ling Liu
Summary: Organic solvent nanofiltration (OSN) is an effective tool for purification, concentration, and solvent exchange of high-value-added products. The introduction of a ZIF-8 interlayer can optimize the performance of OSN membranes through regulating the interfacial polymerization process. Inspired by birds' nesting processes, a fast, eco-friendly, and ordered method using PEG and ZIF precursor was developed for in-situ growth of ZIF-8, resulting in a composite membrane with enhanced stability and uniform morphology.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Liu-Lin Zhao, Xue-Li Cao, Cong Luo, Qian Wang, Tian-Dan Lu, Ming-Jian Tang, Shi-Peng Sun, Weihong Xing
Summary: A bottom-up patterning strategy of locking micron-sized carbon nanotube cages (CNCs) onto a nanofibrous substrate is developed, which enables excellent wettability and antigravity water transport. The CNCs-patterning and CB6 modification result in a high water permeability and rejection rate, surpassing that of commercial membranes by an order of magnitude, providing guidance for the design of next-generation separation membranes.
Article
Engineering, Chemical
Jian Sun, Peng Xu, Dawei Gong, Xiangli Kong, Kaiyun Fu, Xianfu Chen, Minghui Qiu, Yiqun Fan
Summary: The performance of ceramic membrane absorption for the removal of atmospheric CO2 using NaOH as absorbent was studied. The hydrophilic membrane showed the best absorption performance at a NaOH concentration of 2 mol/L, which remained stable even when NaOH utilization reached 75%. Suitable gas and liquid operating parameters were also confirmed. The great absorption stability demonstrated the huge potential of ceramic membrane contactor for direct air capture.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Engineering, Chemical
Mei-Ling Liu, Lan Hong, Yueming Zhu, Razi Epsztein, Ting Shi, Yuanxia Sun, Zhijun Xu, Shi-Peng Sun, Weihong Xing
Summary: This study presents the fabrication of an enzyme-catalyzed nanochannel membrane with a hierarchical structure for selective and directional isomeric conversion and separation. The membrane shows high stability and retains 95% of its initial activity after multiple reaction cycles. It is found that the hierarchical layers of the membrane promote unidirectional diffusion of products and significantly increase the conversion rate of the isomerization reaction.
Article
Engineering, Chemical
Mei-Ling Liu, Yu-Xuan Sun, Ying Tang, Zheng-Jun Fu, Qian Wang, Zhen-Yuan Wang, Shi-Peng Sun
Summary: Traditional technologies for solvent/water separation are energy intensive, but state-of-the-art organic solvent nanofiltration (OSN) membranes have limited solvents discrimination ability. This study used a pressure-assisted cross-linking strategy to coat graphene oxide (GO) on hollow fiber membranes, resulting in improved stability in solvent environments. The GO layer exhibited rapid transport of acetonitrile while impeding water penetration, and the cross-linked GO hollow fiber (CGHF) membrane showed high acetonitrile permeance and the ability to concentrate dilute acetonitrile solutions. This research provides a promising prospect for energy-efficient solvent dehydration and OSN.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Engineering, Chemical
Dan-Dan Shao, Rong Fang, Long Wang, Yue Wang, Xue-Li Cao, Mei-Ling Liu, Xianghong Li, Shi-Peng Sun
Summary: Nanomaterial-based membranes with sub-nanometer structural precision are a research hot spot for selective separation at the molecular scale, but their complex preparation processes restrict their development. The use of dispersant-poly (maleic acid-co-acrylic acid) sodium salt (PMAS) enables the mild formation of amine-carbon quantum dots (CQDs-NH2) membrane at room temperature through interfacial polymerization. PMAS improves the deposition behavior of CQDs-NH2 particles through electric double layer formation, strengthening electrostatic forces and lowering long-range forces. The resulting membrane shows high water permeance and selective separation, making it promising for wastewater treatment and resource recovery.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)