Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 33, Pages 5736-5739Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900917
Keywords
Amination; Dearomatization; Homogeneous catalysis; Naphthol; Rhodium
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Funding
- National Key R&D Program of China [2016Y-FA0202900]
- NSFC [21821002]
- Program of Shanghai Subject Chief Scientist [16XD1404300]
- CAS [XDB20000000, QYZDY-SSW-SLH012]
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An efficient Rh-catalyzed aminative dearomatization of naphthols was achieved. In the presence of Rh-2(esp)(2) and HOSA as an inexpensive and readily available aminating reagent, a series of unprotected alpha-amino-beta-naphthalenones was afforded in good yields under mild reaction conditions. This reaction features good tolerance of functional groups and multi mmol-scale reaction.
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