Article
Energy & Fuels
Rui Tan, Pengchao Wang, Yan He
Summary: In this study, a new horizontal biaxial stirring instrument was used to prepare cyclopentane hydrate, and computational fluid dynamics (CFD) numerical simulation was used to study the flow, pressure, and velocity fields. The results showed that the complex secondary flow promoted the mixing of cyclopentane and water, reduced the dead zone area, and decreased the risk of adherent growth of hydrate.
Article
Energy & Fuels
Qingyun Liao, Bohui Shi, Shangfei Song, Xu Duan, Fengrui Yang, Jing Gong
Summary: This study investigates the effect of wax molecules on methane hydrate growth in waxy oil-water-hydrate systems using molecular dynamics simulations. The results show that different wax molecular structures have different effects on hydrate growth by adsorbing methane molecules and altering the structure of interface water molecules.
Article
Chemistry, Physical
Man Li, Keyao Li, Lei Yang, Yan Su, Jiafei Zhao, Yongchen Song
Summary: Isotopes are ideal for studying intermolecular interactions in clathrates. By replacing methane with deuterated methane, a strong anharmonic effect was discovered. This effect was also confirmed to exist in methane hydrate, but with lower intensity. This finding provides a tool for characterizing intermolecular behavior in guest-host systems.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Physical
Man Li, Keyao Li, Lei Yang, Yan Su, Jiafei Zhao, Yongchen Song
Summary: Isotopes play an important role in studying intermolecular interactions in clathrates by replacing atoms without destroying the geometry structure, revealing previously unrecognized effects. This study provides a tool for characterizing the guest-host system and can be universally applied to similar isotopic supramolecular compounds.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Energy & Fuels
Yu Wei, Maeda Nobuo
Summary: This study investigates the nucleation kinetics of CO2 hydrate and compares it to the nucleation kinetics of methane/propane mixed gas hydrate. The results show that stainless-steel walls promote the nucleation of CO2 hydrate and CO2 hydrate has higher nucleation rates than methane/propane mixed gas hydrate.
Article
Geosciences, Multidisciplinary
Guimin Yu, Hao Jin, Qingwen Kong
Summary: Hydrate plug in the drainage line is a serious flow assurance problem for offshore natural gas hydrate production. This study focuses on the water-dominated multiphase flow system in the drainage line, which is normally a bubbly flow. A new model is developed to study the temperature and pressure distribution in the drainage line considering the bubbly flow pattern. The hydrate formation region in the drainage line can be determined based on the model and methane hydrate phase equilibrium curve. The risk of hydrate formation increases as the hydrate concentration exceeds 6%.
FRONTIERS IN EARTH SCIENCE
(2022)
Article
Energy & Fuels
Qing-Ping Li, Xin Lv, Wei-Xin Pang, Hai-Yuan Yao, Yang Ge, Jun-Ao Wang
Summary: This study investigates the impact of permeability on the decomposition characteristics of hydrate-bearing sediments using a laboratory model. Results show that cores with low permeability experience faster pressure reduction, while cores with high permeability exhibit quicker gas production rates.
Article
Energy & Fuels
Xingxun Li, Cunning Wang, Qingping Li, Qi Fan, Guangjin Chen, Changyu Sun
Summary: In this study, the growth behavior of methane hydrate film on pore interior surfaces was directly visualized and studied using a transparent high-pressure glass microfluidic chip with a porous structure. The results showed that the thickening growth process of the film is mainly determined by water molecule diffusion in the confined pores.
Article
Energy & Fuels
Yingfei Wang, Bo Dong, Ping Wang, Lunxiang Zhang, Cong Chen, Yan Qin, Yang Liu, Weizhong Li, Yongchen Song
Summary: This study develops a model to investigate the effects of initial water on CO2-CH4 dynamic replacement in a hydrate in a pore network, and validates the model with a previous experiment. The results show that the presence of initial water leads to a faster carbon dioxide displacement, weaker methane hydrate dissociation, more pure carbon dioxide hydrate formation, similar mixed hydrate generation, and a lower exchange rate. The exchange reaction starts at the edges of hydrate distribution areas and progresses towards the inside.
Article
Energy & Fuels
Zhuangzhuang Wang, Nengyou Wu, Gaowei Hu, Changling Liu, Yizhao Wan, Qingtao Bu
Summary: This study used microscopic visualization experiments to observe the crystal growth behavior of methane hydrate and investigate the growth patterns and control mechanisms. Two typical hydrate growth patterns were identified: solution gas-water and free gas-water, which affect the crystal growth rate under different conditions.
Article
Chemistry, Physical
Meisam Adibifard, Olufemi Olorode
Summary: The energy content of methane hydrate reservoirs is double that of conventional fossil fuels, making them a commercially attractive resource for development. However, there is concern regarding the potentially uncontrollable release of methane due to global warming. To address this concern, understanding the kinetics of thermal hydrate dissociation is crucial to safely harness these resources and prevent environmental methane emissions. Previous studies on thermal dissociation have often used small simulation domains, limiting the capture of transient processes. In this study, larger-scale coarse-grained molecular dynamics simulations were performed, revealing the formation of an unstable secondary dissociation path and providing insights into the three-stage kinetics of thermal dissociation.
JOURNAL OF PHYSICAL CHEMISTRY B
(2023)
Article
Chemistry, Multidisciplinary
Liwen Li, Xiao Wang, Youguo Yan, Joseph S. Francisco, Jun Zhang, Xiao Cheng Zeng, Jie Zhong
Summary: This study investigates the nucleation process of natural gas hydrates at different degrees of supercooling using molecular dynamics simulations. The concept of a transition layer is proposed to explain the distinct nucleation phenomena observed at different supercoolings.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Xiaodong Shen, Yang Li, Yanxia Li, Long Shen, Nobuo Maeda, Yinde Zhang, Heng Wang, Xiaoguang Wang
Summary: The study found that l-tryptophan has a promoting effect on the formation kinetics and macroscopic morphology of methane hydrates. Even at a stirring rate of 200 rpm, the promotion effect of l-tryptophan remains almost unchanged with increasing concentration. At a concentration of 0.1 wt%, the ultimate gas consumption increased by 46.52% and t (90) decreased by 33.67%. The ultimate gas consumption and t (90) increased when the temperature was raised from 273.65 K to 277.15 K. When the concentration of l-tryptophan was greater than 0.5 wt%, hydrates cropped out from several sites of the hydrate film and continued to grow upward.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Engineering, Environmental
Yu Feng, Man Li, Yuze Han, Qingping Li, Xin Lv, Jiafei Zhao, Lei Yang, Yanzhen Liu, Yongchen Song
Summary: It was found that different components in crude oil have varying effects on the formation and growth of natural gas hydrate. Saturates promote hydrate nucleation and growth, while aromatics and resins inhibit hydrate formation. The direction of gas flow also determines the behavior of hydrate growth.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Guodong Zhang, Zhe Liu, Daming Liu, Yan Lin, Fei Wang
Summary: Researchers prepared a composite nano-porous material of ZIF-8@AC to address the contradiction between the volume and gravimetric adsorption capacities of nano-porous materials. The methane adsorption capacity in the nano-porous material was enhanced due to the hybrid effect of adsorption and hydration.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Yin-de Zhang, Xiaodong Shen, Nobuo Maeda
Article
Energy & Fuels
Zhenjie Wang, Tayfun Babadagli, Nobuo Maeda
Summary: The study aimed to screen effective emulsifiers for oil-in-water emulsions from a wide range of solid nanoparticles, and investigate the stability mechanisms of nanoparticles to enhance emulsion stability. With pH or salt adjustment, nanoparticles showed good stability, and the particle concentration and water/oil ratio significantly affected the stability of emulsions.
SPE RESERVOIR EVALUATION & ENGINEERING
(2021)
Article
Energy & Fuels
Zhenjie Wang, Tayfun Babadagli, Nobuo Maeda
Summary: This study investigates the use of naturally occurring nanoparticles in reservoirs (clays) to generate Pickering emulsions for low-cost heavy oil recovery. It found that emulsions generated using different types of clays exhibit varying stability under different conditions, and injecting low salinity fluids (such as DIW) can improve sweep efficiency for oil recovery.
Review
Biochemistry & Molecular Biology
Nobuo Maeda
Summary: The nucleation of ice is crucial in various fields such as cloud physics, medicine, and food engineering. However, two major unresolved challenges are the lack of a molecular-level picture of ice nucleation at an interface and limitations of classical nucleation theory.
Article
Engineering, Chemical
Xin Zhang, Huazhou Li, Nobuo Maeda
Summary: The experimental setup allows for accurate determination of ice nucleation rates, demonstrating that nucleation rates increase with system supercooling. The entire nucleation curve shifts somewhat downward with the use of a slower cooling rate, indicating the importance of cooling rate in ice nucleation studies.
CHEMICAL ENGINEERING SCIENCE
(2021)
Article
Energy & Fuels
Yu Wei, Nobuo Maeda
Summary: The specific surface free energy of a solid is a fundamental physical quantity that affects cohesion, adhesion, and other phenomena. Experimental difficulties have led to a lack of specific surface free energy values for clathrate hydrates, but techniques like the Zisman plot can be used to determine these values for different materials. In this study, the specific surface free energy of THF hydrate was found to be somewhat lower than that of ice.
Article
Energy & Fuels
Xiao-dong Shen, Yin-de Zhang, Zi-yue Shao, Nobuo Maeda
Summary: The study found that CMC-Na and PVP have different inhibition effects on the formation of CO2 hydrate, with the inhibition effects of CMC-Na decreasing with concentration and PVP slowing down the growth rate of CO2 hydrate. Under stirring conditions, CO2 hydrate grows faster.
Article
Chemistry, Physical
Zhenjie Wang, Tayfun Babadagli, Nobuo Maeda
Summary: Enhancing oil recovery through emulsification is possible without using expensive surfactants, as stable Pickering emulsions can be generated instead. Optimal conditions for stable W/O emulsions include 0.5 wt% asphaltene concentration, pH of 10, and 1 wt% salinity. In-situ formation of emulsions in porous medium can improve recovery, with recommendations for choosing the optimal formulation provided for heavy-oil recovery.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Energy & Fuels
Yu Wei, Qimeng Yang, Xuehua Zhang, Nobuo Maeda
Summary: This study investigated the shear strength of THF hydrate on substrates with different hydrophobicity and the impact of PVP. The results showed a decrease in critical shear stress with heating and an increase with the addition of PVP. Interestingly, the hydrates exhibited higher adhesive strength on hydrophobic substrates compared to hydrophilic ones.
Article
Engineering, Chemical
Xin Zhang, Nobuo Maeda
Summary: Ice nucleation plays a crucial role in various fields, but the problem of reliable ice nucleation promoters persists. This study ranks the efficacy of a range of organic and inorganic additives through experimental tests.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Engineering, Chemical
Yu Wei, Nobuo Maeda
Summary: The memory effect in gas hydrate nucleation refers to the phenomenon that gas hydrates form easier or faster in water with a history of gas hydrate formation. Despite several proposed hypotheses, the cause of the memory effect remains a mystery. This study examines the impact of guest gas supersaturation on the memory effect.
CHEMICAL ENGINEERING SCIENCE
(2023)
Review
Biochemistry & Molecular Biology
Yu Wei, Nobuo Maeda
Summary: Applications of clathrate hydrate require fast formation kinetics, which has been limited by mass transfer and heat transfer. Surfactants and mechanical stirring have been used to accelerate hydrate formation but have drawbacks. Dry water, a water-in-air dispersion stabilized by hydrophobic nanosilica, is an effective promoter for hydrate formation. It shifts the hydrate phase boundary, increases formation rate and improves gas storage capacity. Reusability and knowledge gaps in dry water research are highlighted.
Article
Chemistry, Multidisciplinary
Xiaodong Shen, Yang Li, Yanxia Li, Long Shen, Nobuo Maeda, Yinde Zhang, Heng Wang, Xiaoguang Wang
Summary: The study found that l-tryptophan has a promoting effect on the formation kinetics and macroscopic morphology of methane hydrates. Even at a stirring rate of 200 rpm, the promotion effect of l-tryptophan remains almost unchanged with increasing concentration. At a concentration of 0.1 wt%, the ultimate gas consumption increased by 46.52% and t (90) decreased by 33.67%. The ultimate gas consumption and t (90) increased when the temperature was raised from 273.65 K to 277.15 K. When the concentration of l-tryptophan was greater than 0.5 wt%, hydrates cropped out from several sites of the hydrate film and continued to grow upward.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)