4.7 Review

Recent advances in metal-organic frameworks for lithium metal anode protection

Journal

CHINESE CHEMICAL LETTERS
Volume 31, Issue 3, Pages 609-616

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.06.013

Keywords

Metal-organic frameworks; Li anode; Lithium metal batteries; Li dendrite; Protection

Funding

  1. National Natural Science Foundation of China [21625102, 21471018]
  2. Beijing Municipal Science and Technology Project [Z181100004418001]
  3. Beijing Institute of Technology Research Fund Program

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The lithium metal battery has been considered as a promising candidate for next generation batteries. However, safety concerns caused by uncontrollable lithium dendrite growth on lithium anode are severely hampering the commercial application. Metal-organic frameworks (MOFs) become one of the most attractive materials due to the high porosity, structural designability and tunability. With unique open channels and pores as well as functional components in MOFs, the transportation and deposition of lithium ions can be regulated, which leads to enhanced electrochemical properties. Various strategies for lithium metal protection are proposed in recent works on applications of MOFs in lithium metal batteries. In this review, we highlight latest key approaches in this field and discuss the prospects for MOFs in advanced Li anodes. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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