Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 20, Pages 3557-3560Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900391
Keywords
dehydrogenation; electrosynthesis; metal-organic frameworks; metal-organic layers; N-heterocycles
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Funding
- Ministry of Science and Technology of the People's Republic of China [2016YFA0200702] Funding Source: Medline
- National Natural Science Foundation of China [21671162, 21721001] Funding Source: Medline
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The catalytic acceptorless dehydrogenation (CAD) is an attractive synthetic route to unsaturated compounds because of its high atomic efficiency. Here we report electrochemical acceptorless dehydrogenation of N-heterocycles to obtain quinoline or indole derivatives using metal-organic layer (MOL) catalyst. MOL is the two-dimensional version of metal-organic frameworks (MOF), and it can be constructed on conductive multi-walled carbon nanotubes via facile solvothermal synthesis to overcome the conductivity constraint for MOFs in electrocatalysis. TEMPO-OPO32- was incorporated into the system through a ligand exchange with capping formate on the MOL surface to serve as the active catalytic centers. The hybrid catalyst is efficient in the organic conversion and can be readily recycled and reused.
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