Article
Biotechnology & Applied Microbiology
Manuel Luna, Alvaro Cruceira, Ana Diaz, Jose Manuel Gatica, Maria Jesus Mosquera
Summary: This study investigates how small changes in the lower size range of AuNPs affect the photoactivity of Au/TiO2, aiming to maximize the performance of low-metal-loading photocatalysts. Au/TiO2 photocatalysts prepared by precipitation-deposition methods and a speciation-controlled incipient wetness impregnation method exhibited significantly higher NOx elimination capacity than pristine TiO2. Among the photocatalysts, the speciation-controlled incipient wetness impregnation method achieved the highest gold dispersion and Au-TiO2 contact perimeter, providing the most active photocatalysts, confirming the positive effect of AuNPs size reduction. Additionally, it is proposed that the adsorption of nitrogen oxides species on gold plays a relevant role in the NO photooxidation process.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Article
Construction & Building Technology
Souad Khannyra, Manuel Luna, M. L. Almoraima Gil, Mohammed Addou, Maria J. Mosquera
Summary: A self-cleaning nanostructured TiO2 coating has the ability to mitigate the negative effects of air pollution and has long-lasting efficiency for outdoor applications.
BUILDING AND ENVIRONMENT
(2022)
Article
Chemistry, Applied
Yi Wu, Kai Yan, Guilin Xu, Chenguang Yang, Dong Wang
Summary: Super-oleophobic TiO2/SiO2 composite coatings were achieved through a simple spraying method, with dendritic structures playing a critical role in providing the re-entrant geometry required for oleophobic surface. The introduction of micron-scale TiO2 particles and nano-scale SiO2 particles provided a dual-scale rough structure for the coating, resulting in superior repellence to high and low surface tension liquids as well as long-term durability. This design strategy may offer useful guidance for the fabrication of particle-based spray-coated super-oleophobic surfaces.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Biochemistry & Molecular Biology
Barbora Muzikova, Ivana Martiniakova, Eliska Mikyskova, Martin Mergl, Martin Kalbac, Radek Zouzelka, Jiri Rathousky
Summary: TiO2 is a highly studied photocatalyst due to its non-toxicity, chemical stability, and low cost. However, it has low activity in the visible region. This study focuses on preparing composite photocatalytic materials with altered light absorption properties and evaluates their ability to degrade NO in the gas phase.
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
(2023)
Article
Materials Science, Ceramics
Ka-Wai Yeung, Ling Chen, Chak-Yin Tang, Man-Tik Choy, Akeem Damilola Akinwekomi, Wing-Cheung Law, Gary Chi-Pong Tsui
Summary: This study developed a new protocol using a hybrid approach to successfully create a UV-resistant protective coating on high microwave transparent plastic surfaces, overcoming the challenge of temperature mismatch between the coating and substrate. Significant improvement in surface mechanical properties was achieved through a two-way susceptor-aided heating mechanism and the use of low microwave absorbing sol-gel derived composite coatings.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Environmental Sciences
Maria-Anna Gatou, Evangelos Fiorentis, Nefeli Lagopati, Evangelia A. Pavlatou
Summary: This study investigated the photocatalytic degradation of rhodamine B and phenol using TiO2/SiO2 composite nanoparticles under visible-light irradiation. The results showed that the composite material achieved 100% and 43.19% degradation of rhodamine B and phenol, respectively, within 210 minutes. The major reactive oxygen species involved in the photocatalytic degradation were found to be O-2(-), h(+) and e(-) for rhodamine B, and ?OH radicals for phenol. The TiO2/SiO2 composite catalyst demonstrated stable degradation efficiency after five cycles of reuse.
Article
Chemistry, Physical
Yu Tu, Weihua Ao, Chunhong Wang, Tianyu Ren, Lijuan Zhang, Jiaxin Zhong, Wei Li, Hao Ding
Summary: The modified microspheres were obtained by hydrolytic modification, resulting in an amorphous SiO2 shell layer and increased hydroxyl groups on the surface. The composite photocatalyst showed improved performance compared to pure nano-TiO2, highlighting the importance of loading capacity, dispersion, and active surface sites for enhancing the functional efficiency of nano-TiO2.
Article
Construction & Building Technology
Seonhyeok Kim, Joonho Seo, H. N. Yoon, H. K. Lee
Summary: The study explored the effects of CO2 exposure on TiO2-incorporated Portland cement, revealing that while the incorporation of TiO2 positively impacted the hydration process and early strength development, it did not significantly enhance strength at a later age. Additionally, exposure to CO2 led to a reduction in the NOx-removal performance of the samples, as the TiO2 particles on the surface were covered by calcium carbonate formed during carbonation.
JOURNAL OF BUILDING ENGINEERING
(2022)
Article
Construction & Building Technology
M. Luna, J. J. Delgado, I Romero, T. Montini, M. L. Almoraima Gil, J. Martinez-Lopez, P. Fornasiero, M. J. Mosquera
Summary: In this study, TiO2-SiO2 nanocomposites were developed as photoactive coatings for urban buildings, providing surfaces with antipollution and self-cleaning properties. The use of anatase titanium di-oxide with a high percentage of {001} facets improved the antipollution properties compared to similar sols based on P25. The treated titania nanosheets showed improved photocatalytic activity and effectively reduced concentrations of NOx, soot, and organic dyes under simulated sunlight radiation.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Environmental Sciences
Souad Khannyra, Maria Luisa Almoraima Gil, Mohammed Addou, Maria Jesus Mosquera
Summary: In this study, N-TiO2/SiO2 composites were synthesized via the sol-gel method, with nitrogen doping significantly enhancing the absorption of TiO2 in the visible region and improving photocatalytic activity. SEM characterization showed clusters distributed as aggregates on the sample surface, with high performance in methylene blue degradation and NO oxidation observed for the treated samples. Although NOx reduction capability was demonstrated, efficiencies varied among the synthesized photocatalysts.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Engineering, Environmental
Vignesh Kumaravel, Keerthi M. Nair, Snehamol Mathew, John Bartlett, James E. Kennedy, Hugh G. Manning, Barry J. Whelan, Nigel S. Leyland, Suresh C. Pillai
Summary: This study introduces the engineering of self-disinfecting surfaces using Titania (TiO2) nanocomposite antimicrobial coatings to tackle the spread of SARS-CoV-2, emphasizing on the disinfection efficiency, material composition, and enhanced antimicrobial properties on surfaces, dental and orthopaedic implants. Through evaluating the antimicrobial activity of TiO2 coatings and modifying them with other metals and non-metal materials, new strategies and methods have been proposed to combat the spread of pathogenic microorganisms.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Sudipto Pal, Sanosh Kunjalukkal Padmanabhan, Amruth Kaitheri, Mauro Epifani, Antonio Licciulli
Summary: A solar light active photocatalyst was developed by coating silver phosphate (Ag3PO4) onto titania-silica (TiO2-SiO2) microspheres. The Ag3PO4 particles covered the surface of the TiO2-SiO2 microspheres, allowing the composites to absorb the entire visible light spectrum. The composite photocatalyst exhibited higher efficiency compared to its pristine counterparts and a benchmark commercial TiO2.
Article
Materials Science, Multidisciplinary
Hao Huy Nguyen, Adriana Martinez-Oviedo, Tae-Ho Kim, Bhupendra Joshi, Lung Nhat Dang Quang, Gobinda Gyawali
Summary: The study found a significant correlation between NaOH concentration and the types of TiO2 nanostructured products obtained through microwave hydrothermal process. Lower NaOH concentrations resulted in a mixture of 1D and 2D nanostructures, while higher concentrations produced nanosheets and nanotube-like structures with larger specific surface areas. Additionally, TiO2 samples prepared at higher NaOH concentrations showed improved photocatalytic performance for NOx gas removal.
Article
Biodiversity Conservation
Hongyu Zhang, Xiao Zhang, Cong Xie, Wenbin Shi, Ping Yang
Summary: Accordion-like Ti3C2Tx MXene was successfully prepared via chemical etching, and TiO2 nanocrystals were grown on Ti3C2Tx nanosheets by in-situ oxidation using a powerful alkaline solution. The ratio of Ti3C2Tx and TiO2 was optimized, resulting in TiO2/Ti3C2Tx composites with excellent photocatalytic activity, especially for NO removal. The microstructure of TiO2/Ti3C2Tx composites contributed to the improvement of the separation and transfer efficiency of photogenerated carriers. The composite sample synthesized at 75 degrees Celsius showed the best NO removal efficiency, removing 70% of NO at a concentration of 600 ppb. This study offers a new approach for preparing high-performance MXene-based photocatalysts.
ECOLOGICAL INDICATORS
(2023)
Article
Nanoscience & Nanotechnology
Yi Yang, Tianyu Sun, Fuliang Ma, Liang-Feng Huang, Zhixiang Zeng
Summary: A Fe3+ doped TiO2 film with long-lasting superhydrophilicity and antifogging is prepared in this study, and experiments along with density-functional theory calculations are conducted to investigate the antifogging performance and the underlying microscopic mechanism of Fe3+ doped TiO2. The results show that Fe3+ doping can enhance the photolysis ability of TiO2 under sunlight exposure and stabilize the hydroxyl adsorbate on TiO2 surface, leading to a long-lasting superhydrophilicity.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Applied
Fazia Agueniou, Hilario Vidal, M. Pilar Yeste, Juan C. Hernandez-Garrido, Miguel A. Cauqui, Jose M. Rodriguez-Izquierdo, Jose J. Calvino, Jose M. Gatica
Summary: The study evaluated the performance of Ni catalysts supported by Ce-Zr oxide in dry reforming of methane, and the structured catalysts showed better performance at high temperatures without deactivation.
Article
Chemistry, Applied
Pilar Yeste, M. Amine Fellak, Hilario Vidal, Francisco M. Guerra, F. Javier Moreno-Dorado, Jose M. Gatica
Summary: In this study, a copper-iron mixed oxide was deposited on cordierite honeycomb monoliths using the washcoating procedure, creating an excellent heterogeneous catalyst. The prepared catalyst exhibited high yield and stability in the selective production of allylic ester in the Kharasch-Sosnovsky oxidation of cyclohexene with benzoic acid. The use of a structured catalyst offers an interesting alternative to homogeneous catalysis in synthetic chemistry.
Article
Construction & Building Technology
Souad Khannyra, Manuel Luna, M. L. Almoraima Gil, Mohammed Addou, Maria J. Mosquera
Summary: A self-cleaning nanostructured TiO2 coating has the ability to mitigate the negative effects of air pollution and has long-lasting efficiency for outdoor applications.
BUILDING AND ENVIRONMENT
(2022)
Article
Construction & Building Technology
M. Luna, J. J. Delgado, I Romero, T. Montini, M. L. Almoraima Gil, J. Martinez-Lopez, P. Fornasiero, M. J. Mosquera
Summary: In this study, TiO2-SiO2 nanocomposites were developed as photoactive coatings for urban buildings, providing surfaces with antipollution and self-cleaning properties. The use of anatase titanium di-oxide with a high percentage of {001} facets improved the antipollution properties compared to similar sols based on P25. The treated titania nanosheets showed improved photocatalytic activity and effectively reduced concentrations of NOx, soot, and organic dyes under simulated sunlight radiation.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Architecture
Jorge Feijoo, Ivan de Rosario, Teresa Rivas, Maria J. Mosquera, Rosa Benavides
Summary: This study presents the pre-consolidation of deteriorated granite using different consolidants and the subsequent desalination treatment using poultices. The results show that pre-treatment with a nanoconsolidant based on silicon oligomers (UCAD-2o) restores cohesion to the granite and improves the efficiency of desalination. This research provides new data to address the conservation issues of granitic monuments affected by soluble salts.
INTERNATIONAL JOURNAL OF ARCHITECTURAL HERITAGE
(2023)
Article
Chemistry, Physical
Natasha Di Benedetto, Carolina De los Santos, Maria Del Pilar Yeste, Jonder Morais, Maria Do Carmo Martins Alves, Alejandro Amaya, Leopoldo Suescun, Jose Manuel Gatica, Hilario Vidal, Jorge Castiglioni
Summary: Single-phase oxygen stoichiometric LaMnO3 and doped La(0.8)A(0.2)MnO(3) (A = Ca, Sr, Ba) perovskites were prepared by a simple one-step auto-combustion method. Cation-deficient LaMnO3+delta and La(0.8)A(0.2)MnO(3+delta) were obtained by calcination of the former samples in air at 750 degrees C. The catalytic activity of these oxides is influenced by the Mn4+/Mn3+ molar ratio on the surface of the samples and the cation-deficiency of the bulk perovskite structure.
Article
Construction & Building Technology
Giada M. C. Gemelli, Manuel Luna, Rafael Zarzuela, M. L. Almoraima Gil Montero, Maria Carbu, Ignacio Moreno-Garrido, Maria J. Mosquera
Summary: This manuscript presents a 4-year in-situ evaluation of a TiO2/SiO2-based product applied to a mortar seating in the bleachers of the Cadiz Roman Theatre. The product demonstrates good antifouling performance, reducing organic deposits by 40% and inhibiting biological growth by 61% compared to the untreated area. The study also suggests that the antifouling efficacy is more pronounced during the first two years.
BUILDING AND ENVIRONMENT
(2022)
Article
Engineering, Chemical
Farid Elhaddad, Manuel Luna, Giada M. C. Gemelli, M. L. Almoraima Gil, Maria J. Mosquera
Summary: This study applied a highly effective superhydrophobic nanomaterial in the archaeological site of Carteia and evaluated its effectiveness and durability in the laboratory and after one year of in situ exposure. The results showed that the product prepared in the laboratory exhibited high consolidant and superhydrophobic effectiveness, while the commercial products presented reduced protection.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Construction & Building Technology
Rafael Zarzuela, Manuel Luna, Jorge Gonzalez Coneo, Giada Gemelli, Dia Andreouli, Vasilis Kaloidas, Maria J. Mosquera
Summary: Many concrete structures in need of repair and protection can be treated using silane-based impregnation treatments, which produce silica and C-S-H gels and can be modified to create multifunctional treatments that also protect from water ingress. However, standard material validation may not always be representative of on-site application due to substrate properties and changes over time. In this study, three innovative silane-based impregnation treatments, two of which have superhydrophobic properties, were evaluated on mockup specimens that simulate the properties of cementitious materials from different heritage structures in Europe. The treatments showed compatibility, minimal aesthetic alterations, and improved mechanical properties.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Chemistry, Organic
Pablo Macias-Benitez, Alfonso Sierra-Padilla, M. Pilar Yeste, Jose Maria Palacios-Santander, Laura Cubillana-Aguilera, Jose M. Gatica, Hilario Vidal, Francisco M. Guerra, F. Javier Moreno-Dorado
Summary: A copper-iron-based catalyst was prepared using a low-temperature co-precipitation and sonication method. The use of high-energy ultrasound reduced the preparation time from one workweek to one day compared to conventional methods. The resulting material was characterized using various techniques and showed catalytic activity in the acyloxylation reaction. Microwave irradiation improved the outcome of the reaction in terms of cleanliness, yield, and time.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2023)
Editorial Material
Nanoscience & Nanotechnology
Maria J. Mosquera, Rafael Zarzuela, Manuel Luna
Summary: Despite being the most prominent building material of the twentieth century, the cultural heritage value of concrete buildings and the importance of their preservation are not well acknowledged. The European Union project InnovaConcrete aims to develop nanotechnology-based treatments for concrete preservation and raise public awareness about the significance of concrete-based heritage.
NATURE REVIEWS MATERIALS
(2023)
Article
Biotechnology & Applied Microbiology
Manuel Luna, Alvaro Cruceira, Ana Diaz, Jose Manuel Gatica, Maria Jesus Mosquera
Summary: This study investigates how small changes in the lower size range of AuNPs affect the photoactivity of Au/TiO2, aiming to maximize the performance of low-metal-loading photocatalysts. Au/TiO2 photocatalysts prepared by precipitation-deposition methods and a speciation-controlled incipient wetness impregnation method exhibited significantly higher NOx elimination capacity than pristine TiO2. Among the photocatalysts, the speciation-controlled incipient wetness impregnation method achieved the highest gold dispersion and Au-TiO2 contact perimeter, providing the most active photocatalysts, confirming the positive effect of AuNPs size reduction. Additionally, it is proposed that the adsorption of nitrogen oxides species on gold plays a relevant role in the NO photooxidation process.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Article
Construction & Building Technology
Rafael Zarzuela Sanchez, Jorge Gonzalez-Coneo, Manuel Luna, Ana Diaz, Maria Jesus Mosquera
Summary: Hydrophobic mortars are produced by combining a silane-based admixture with the pre-treatment of the aggregates with an alkoxysilane-ended fluoropolymer. A comparative study is conducted to evaluate the impact of different components and curing conditions on the hydrophobicity, mechanical performance, composition, and micro-structure. The combination of both strategies allows achieving hydrophobic properties under varying curing conditions, compensating for the limitations of silane admixtures.
JOURNAL OF BUILDING ENGINEERING
(2023)
Article
Engineering, Environmental
Manuel Luna, Adrian Gonzalez-Hidalgo, Ana Diaz, Daniel Goma, Jose Manuel Gatica, Maria Jesus Mosquera
Summary: This study explores the effect of SMSI induced by soft wet-chemistry in Au/TiO2 photocatalyst for environmental remediation. Different types of pollutants were evaluated, and the results showed that SMSI has a positive effect on photoactivity, promoting the removal of methylene blue and soot. However, SMSI did not provide any additional benefit in the elimination of NOx.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)
