Journal
CARBON
Volume 148, Issue -, Pages 91-104Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.01.067
Keywords
Energy storage; Titanium nitride; VRFB; High-power density; Nitrided TiO2 decorated carbon electrodes; Negative electrodes for VRFB
Funding
- Fundacion Ramon Areces from BatLimet project
- CERCA Program [2017SGR1246]
- XaRMAE network
- European Regional Development Funds (ERDF, FEDER)
- MINECO coordinated projects [MAT2014-59961, ENE2017-85087]
- QEERI [NPRP9-158-1-029]
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This work describes the design of an electrode with enhanced performance applied to all-vanadium redox flow batteries (VRFBs). This new electrode consists of a structural porous carbon felt decorated with TiO2 rutile nanoparticles, which has been nitrided using ammonolysis at 900 degrees C. An outstanding charge and mass transfer over the electrode-electrolyte interface was observed as a consequence of the synergetic effect of N- and O-functionalization over carbon felt (CF) and the partial formation of TiN (metallic conductor) phase. Moreover, this material has not only improved in terms of catalysis towards the V3+/V2+ redox reaction (k(0) = 1.6 x 10(-3) cm s(-1)), but also inhibited the hydrogen evolution reaction (HER), which is one of the main causes of imbalances that lead to battery failure. This led to an impressive high-power peak output value up to 700 mW cm(-2), as well as work at high current density in galvanostatic conditions (i.e. 150 mA cm(-2)), exhibiting low ohmic losses (overpotential) and great redox single cell reversibility, with a superior energy efficiency of 71%. An inexpensive, earth abundant and scalable synthesis method to boost VREBs technology based on nitrided CF@TiO2 is presented, being able to overcome certain constrains, and therefore to achieve high energy and power densities. (C) 2019 Elsevier Ltd. All rights reserved.
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