Article
Chemistry, Multidisciplinary
Gui Yang, Yujun Liang, Jian Yang, Kun Wang, Zikang Zeng, Zhuoran Xiong
Summary: By growing ultrathin fish scale-like bismuth oxybromide (BiOBr) nanosheets on the surfaces of bismuth molybdate (Bi6Mo2O15) sub-microwires to achieve a BiOBr/Bi6Mo2O15 edge-on heterojunction, the vertical growth of BiOBr nanosheets facilitated electron transport and provided large interfacial contact areas, resulting in outstanding performance for tetracycline removal.
Article
Engineering, Environmental
Hanxiang Chen, Zhao Mo, Zeming Wang, Pengcheng Yan, Peipei Sun, Guanyu Wu, Jinyuan Zhang, Xianglin Zhu, Liang Wang, Hui Xu
Summary: Mimicking natural photosynthesis by using carbon nitride-based photocatalysts to convert solar power into hydrogen energy has been hindered by the addition of metallic cocatalysts. To overcome this issue, a metal-free photocatalytic system was developed by grafting nitrogen-doped graphene quantum dots (NGQDs) onto porous ultrathin carbon nitride (PUCN). The integration of N-GQDs enhanced the hydrogen production rate of the photocatalyst by 208 times compared to PUCN. This new metal-free photocatalyst outperforms most carbon nitride-based photocatalysts with metallic cocatalysts, offering potential for practical applications in photocatalytic water splitting.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Dong Jin Kim, Je Min Yoo, Yeonjoon Suh, Donghoon Kim, Insung Kang, Joonhee Moon, Mina Park, Juhee Kim, Kyung-Sun Kang, Byung Hee Hong
Summary: Recent studies have shown the potential therapeutic efficacy of graphene quantum dots (GQDs) derived from coffee waste against Parkinson's disease, providing a novel environmentally friendly approach for converting waste materials into nanodrugs. This research highlights the promising prospect of utilizing GQDs as a treatment for Parkinson's disease and demonstrates the potential of waste-to-treasure methods in drug development.
Article
Environmental Sciences
Wei Wu, Haomin Song, Qiaoqiang Gan, Dongxia Liu
Summary: By investigating the decomposition of DMMP vapor on an ultrathin film TiO2 photocatalytic light absorber, the study overcame the trade-off between optical absorption and charge carrier extraction efficiency, significantly boosting the photocatalytic activity compared to a benchmark catalyst. The effects of reactant partial pressure and reaction temperature on the decomposition process were studied, and the kinetics were described by the Langmuir-Hinshelwood model.
Article
Engineering, Chemical
Meng-Lin Hsieh, Ruey-Shin Juang, Yasser Ashraf Gandomi, Chun-Chieh Fu, Chien-Te Hsieh, Wei-Ren Liu
Summary: In this study, a heterogeneous graphene quantum dot (GQD)/ZnO composite was proposed as a photocatalyst for degrading antibiotics, and the introduction of N-GQDs significantly enhanced the photocatalytic activity and reaction rate. Optimizing the composition of the GQD/ZnO catalyst achieved high removal ratio and significantly improved rate constant.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Materials Science, Multidisciplinary
Xiaofen Xu, Gang He, Leini Wang, Wenhao Wang, Shanshan Jiang, Zebo Fang
Summary: This work presents a solution-processed high-performance graphene quantum dots decorated amorphous InGaZnO thin-film transistor. Experimental results demonstrate the superior performance and stability of the device, as well as its potential application in logic circuits.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Maryam Karami, Qahtan A. Yousif, Mojgan Ghanbari, Kamran Mahdavi, Masoud Salavati-Niasari
Summary: In this research, CaSiO3 nanostructures were synthesized by hydrothermal method and combined with graphene quantum dots (GQDs) to develop oxide perovskite materials with good photocatalytic performance. The results showed that the CaSiO3/GQDs samples with high concentration exhibited higher visible-light photocatalytic activity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Chemical
Jiawei Liu, Zhen Wang, Wenwen Li, Xuliang Wang, Yanlei Su
Summary: This work reported a significant improvement of nanofiltration (NF) membranes for desalination with high separation performance. The graphene quantum dots (GQDs) enhanced polyamide (PA) composite membranes (GPA) consisted of porous substrates and nanofilms. The nanofilms, fabricated by support-free interfacial polymerization, had an ultrathin thickness below 8.0 nm. The synergistic strategy of GQDs regulation on PA nanofilm structure and arginine post-treatment modification may provide a reliable and efficient technique for the design of NF membranes.
Article
Chemistry, Physical
Sudhakar Narra, Sumit S. Bhosale, Aparna K. Kharade, Sue-min Chang, Eric Wei-Guang Diau
Summary: Femtosecond transient absorption spectral investigations were conducted to understand carrier relaxation mechanism in perovskite nanocrystals. The study found that Cs(1-x)FA(x)PbBr(3) (CF) samples exhibited slower charge recombination rates compared to CsPbBr3 (CS) samples, consistent with their photocatalytic performances.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Environmental Sciences
Changchang Ma, Won Cheol Seo, Jeongwoo Lee, Youjoong Kim, Hyun Jung, Woochul Yang
Summary: This study reports a novel composite photocatalyst BiVO4/rGH, which exhibited excellent photocatalytic efficiency for the degradation of tetracycline hydrochloride. The enhanced photocatalytic activity of BiVO4/rGH is attributed to the synergistic effects of the structure and the crucial role of active species.
Article
Chemistry, Physical
Yanan Liu, Chang Liu, Chunli Shi, Wei Sun, Xue Lin, Weilong Shi, Yuanzhi Hong
Summary: By modifying carbon nitride quantum dots (CNQDs) and nitrogen-doped carbon quantum dots (NCQDs) with BiVO4 heterojunctions, the photocatalytic performance, especially the Rhodamine B (Rh B) photodegradation activity, was significantly improved. The enhancement is attributed to the effective photoinduced charge separation and inhibition of interfacial charge recombination by the ms/tz-BiVO4 heterojunction.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Chemical
Guoxiang Yang, Longyang Wang, Chencheng Zhang, Ping Li, Hao Du, Yanjie Mao, Mengyi Qiu, Qiang Li, Derek Hao, Qi Wang
Summary: A novel photocatalyst GQDs/NH2-MIL-125 was prepared by solvothermal method for efficient photocatalytic disinfection. The addition of GQDs enhanced visible light absorption and accelerated photogenerated electron transfer, greatly improving the photocatalytic performance. The 2-GQDs/NH2-MIL-125 sample exhibited the best antibacterial properties, achieving a killing efficiency of 92% and 93% against E. coli and S. aureus within 60 minutes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Engineering, Environmental
Fahimeh Kazeminava, Siamak Javanbakht, Mojtaba Zabihi, Mahmoud Abbaszadeh, Vahid Fakhrzadeh, Hossein Samadi Kafil, Zainab Ahmadian, Marjan Joulaei, Zahra Zahed, Alireza Motavalizadehkakhky, Zeinab Latifi, Hosein Eslami
Summary: In this study, antibacterial flexible hydrogel films were prepared by crosslinking biopolymer chitosan (CS) with silver-sulfur doped graphene quantum dots (Ag@S-GQD), which are among the most potent materials for wound dressing construction.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Chemistry, Physical
Ting Song, Linquan Hou, Bei Long, Atif Ali, Guo-Jun Deng
Summary: The research introduced ultrathin Ti3C2 (TiC) nanosheets with excellent conductivity into ultrathin metal-free black phosphorus (BQ)/ultrathin g-C3N4 (UCN) heterojunction to improve photocatalytic H-2 production activity. The optimized composite displayed advantages such as strong interfacial contact and enhanced visible-light capture, leading to accelerated charge transfer and fast separation of photoinduced carriers. The composite exhibited significantly higher photocatalytic activity compared to bulk g-C3N4 (BCN) and UCN, showing great potential for high solar energy utilization in MXene (Ti3C2)-based catalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Environmental Sciences
Rafael R. Solis, Daily Rodriguez-Padron, Maria Angeles Martin-Lara, Monica Calero, Rafael Luque, Mario J. Munoz-Batista
Summary: An environmentally friendly solvent-free approach using spent coffee as a biomass sacrificial template was used to prepare TiO2 modified with CeOx. The use of coffee as a template allowed for the preparation of a nanostructured heterojunction without the need for a solvent. The incorporation of ceria in the structure significantly improved the photocatalytic benzaldehyde production.
Article
Chemistry, Applied
Yuting Liang, Zhi Jiang, Wenfeng Shangguan
Summary: This study investigated the photocatalytic reaction behavior of DEHP over surface platinized TiO2, with the oxidation state of platinum found to be crucial in determining the photocatalytic activity. Platinized titania with oxidized Pt species showed higher photocatalytic activity compared to metallic Pt. Photocatalysis coupled with thermal catalysis can enhance the degradation of DEHP, and Pt oxide, particularly PtO, can improve the photocatalytic oxidation efficiency by promoting the separation efficiency of photo generated carriers.
Article
Chemistry, Physical
Mengyang Zhou, Shuai Chen, Jing Bai, Jiachen Wang, Yan Zhang, Tingsheng Zhou, Jinhua Li, Wenfeng Shangguan, Baoxue Zhou
Summary: Oxygen concentration and distribution in hematite significantly affect holes transfer efficiency, ultimately influencing the performance of photoelectrocatalytic water splitting. Thermal treatment leads to changes in oxygen, impacting holes transfer efficiency.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Environmental
Yuting Liang, Jiayi Li, Yaoyu He, Zhi Jiang, Wenfeng Shangguan
Summary: The study found that as the temperature increases, the model SVOC DMP gradually oxidizes on the surface of supported catalysts, with carbon dioxide as the main product, but aromatic products and small molecule products are still observed at different temperatures.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Physical
Peifen Wang, Jing Wang, Xiaowei An, Jin Shi, Wenfeng Shangguan, Xiaogang Hao, Guangwen Xu, Bing Tang, Abuliti Abudula, Guoqing Guan
Summary: The facile agar-gel method was successfully applied to prepare homogenous Mn-Co mixed oxides with different Mn/Co molar ratios for total toluene oxidation catalysis. The obtained Mn2Co1 mixed oxide displayed high catalytic activity, durability, and tolerability in water vapor environment. Characterizations and measurements indicated the optimum Mn-Co mixed oxide had high surface area, various species, strong oxygen adsorption, good reducibility, and excellent O2 adsorption ability, making it suitable for VOCs oxidation design.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Engineering, Environmental
Yong Zhu, Chen Chen, Jianwei Shi, Mingxia Chen, Wenfeng Shangguan
Summary: Experimental results showed that the collection efficiency could reach up to 92.9%, 96.7%, and 97.7% for 0.25 µm, 0.35 µm, and 0.45 µm diameter particles at 4 m/s gas velocity, respectively. Electric field strength had a moderate effect on collection efficiency, with an index factor of about 18 at a collection length of 30 cm. Charger current, gas velocity, collection length, and electric field strength sequentially affected the ozone concentration.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Yong Zhu, Shanlong Tao, Chen Chen, Jiahua Liu, Mingxia Chen, Wenfeng Shangguan
Summary: An integrated two-stage electrostatic precipitator was developed and tested to efficiently remove PM2.5, showing excellent collection efficiency at different gas velocities and providing suggestions for secondary entrainment suppression and application strategies.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Xiang Liu, Binfen Wang, Qianqian Heng, Wei Chen, Xiying Li, Liqun Mao, Wenfeng Shangguan
Summary: The construction of a ternary 3D interconnected nanocomposite Ti3C2/MoS2/CdS with closely interfacial contact has been successfully achieved. This composite material exhibits excellent photocatalytic H-2 evolution activity by accelerating electron transfer and inhibiting carrier recombination.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yawei Jiang, Yan Mi, Chufan Li, Wenjian Fang, Xiaochuan Li, Xianghua Zeng, Yongsheng Liu, Wenfeng Shangguan
Summary: In this study, the solid solution Bi3-xYxO4Cl was successfully synthesized with tunable absorption edge and bandgap by adjusting the Bi content and Y/Bi ratio, showing excellent visible-light photocatalytic water splitting performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Weiqi Guo, Pengfei Yu, Haolin Luo, Jiasheng Chi, Zhi Jiang, Xiaosong Liu, Wen Wen, Wenfeng Shangguan
Summary: The solid solution photocatalyst is crucial for designing one-step excitation water splitting systems. This study synthesized Bi0.5Y0.5VO4 solid solution and investigated the influence of surface structure variations at different temperatures on the catalytic activity.
JOURNAL OF CATALYSIS
(2022)
Article
Engineering, Environmental
Yuting Liang, Jiayi Li, Yingying Xue, Ting Tan, Zhi Jiang, Yaoyu He, Wenfeng Shangguan, Jiuzhong Yang, Yang Pan
Summary: This study investigated the degradation process of benzene in non-thermal plasma using SVUV-PIMS technology, identifying key products and highlighting the significance of previously overlooked byproducts.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Chemical
Yong Zhu, Shanlong Tao, Chen Chen, Jiahua Liu, Mingxia Chen, Wenfeng Shangguan
Summary: This paper develops a novel approach for evaluating charged particles' collision probability in the external electric field of a regular two-stage electrostatic precipitator. Numerical simulation is used to analyze the factors influencing particle collision, with results showing that the R-AC external electric field is more beneficial for particle collision. Frequency and plate spacing do not have a significant impact on collision probability, while applied voltage has a promotional effect. The dimensionless coefficient analysis provides valuable information for optimizing working conditions in different types of external electric fields.
Article
Chemistry, Physical
Hui Yuan, Fenjian Fang, Jing Dong, Weiwei Xia, Xianghua Zeng, Wenfeng Shangguan
Summary: MoS2/g-C3N4 composites exhibit good activity and stability in photocatalytic hydrogen generation, which can be attributed to their typical layered structure and the presence of few-layer MoS2.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Review
Energy & Fuels
Zhi Jiang, Zhen Ye, Wenfeng Shangguan
Summary: This paper provides a summary of the cutting-edge research in solar energy-driven photocatalytic water splitting, including the overall water splitting system and photocatalytic reaction engineering. It gives an overview of recent progress and emphasizes the challenges and opportunities in the current system.
FRONTIERS IN ENERGY
(2022)
Article
Chemistry, Physical
Jing Dong, Wenjian Fang, Hui Yuan, Weiwei Xia, Xianghua Zeng, Wenfeng Shangguan
Summary: The preparation of efficient noble-metal-free catalysts through MoS2/ZnCdS/ZnS dual heterostructures has led to high hydrogen production rates and stability in water-splitting reactions.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Applied
Weiqi Guo, Haolin Luo, Zhi Jiang, Wenfeng Shangguan
Summary: This study constructs S-scheme heterojunctions in photocatalysts through pressure-induced phase transition and finds that this structure can significantly enhance the overall water splitting activity. Characterization of carrier dynamics demonstrates that S-type heterojunctions contribute to improved carrier separation.
CHINESE JOURNAL OF CATALYSIS
(2022)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
