4.6 Article

An Efficient Support-Free Nanoporous Co Catalyst for Reverse Water-Gas Shift Reaction

Journal

CATALYSTS
Volume 9, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/catal9050423

Keywords

nanoporous Co; CO2 hydrogenation; hierarchical pores; dealloying

Funding

  1. Natural Science Foundation of Tianjin City [18JCYBJC89500]
  2. National Natural Science Foundation of China [21503028, 21506148]

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A Co-based catalyst is a great candidate for the hydrogenation of CO2. Herein, a support-free nanoporous Co catalyst with high surface area and hierarchical pores was prepared by chemical dealloying, which exhibited excellent performance in the reverse water-gas shift (RWGS) reaction. High conversion of 54.2% and RWGS reaction rate of 812 mol(CO2)/g(cat)/s could be obtained at a high weight hourly space velocity.

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