Article
Materials Science, Multidisciplinary
Tingting Liu, Cheng Zhang, Xiaofeng Li
Summary: The fundamental processes of hot-carrier in 2D MXenes (Mo2C and Ti3C2) were studied using first-principles calculation. It was found that Mo2C and Ti3C2 have higher hot-carrier generation efficiencies than Au for energies over 1 eV. Biaxial strain was used to optimize the hot-carrier transport properties of Mo2C. A Mo2C/MoGeSiN4 hot-electron photodetector was proposed, showing a significantly higher responsivity compared to existing hot-carrier devices.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ting-Hsuan Wu, Hao-Yu Cheng, Wei-Chiao Lai, Raman Sankar, Chia-Seng Chang, Kung-Hsuan Lin
Summary: We found that the presence of photocarriers in exfoliated InSe led to shrinkage in the optical bandgap. Furthermore, the carrier recombination rate increased with reduced thickness and was dominated by surface recombination.
Article
Physics, Applied
T. Venanzi, M. Selig, A. Pashkin, S. Winnerl, M. Katzer, H. Arora, A. Erbe, A. Patane, Z. R. Kudrynskyi, Z. D. Kovalyuk, L. Baldassarre, A. Knorr, M. Helm, H. Schneider
Summary: Using terahertz radiation to modulate the optical properties of semiconductors is a promising approach for the development of opto-electronic technology. This study demonstrates the dynamical control of photoluminescence emission in few-layer InSe using picosecond terahertz pulses and reveals the underlying mechanism.
APPLIED PHYSICS LETTERS
(2022)
Article
Chemistry, Physical
Gaoyuan Yang, Yibo Tu, Jingchuan Ye, Ruochuan Liu, Yue Zang, Lijian Zhang, Yu Wang, Guodong Li, Qin Zhou, Liang Chu, Wensheng Yan
Summary: Perovskite solar cells (PSCs) are the most promising candidate for next-generation photovoltaics. Manipulating the hot carriers has the potential to achieve ultrahigh-efficiency solar cells. However, the carrier dynamics behavior in the femtosecond time scale is difficult to be detected, and this challenge is effectively addressed by femtosecond transient absorption techniques.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Hengyue Lv, Lingrui Chu, Xiaoli Sun, Feng Chen
Summary: In this work, we have systematically examined the saturable absorption properties of InSe/Graphene heterostructures with different thicknesses of InSe. We have established a positive correlation between the third-order nonlinear absorption coefficient and the thickness of the heterostructure. Furthermore, we have revealed the interplay of carrier dynamics within the heterostructures, showing prolonged interlayer transfer times and slowed carrier relaxation as InSe thickness increases. These findings shed light on the potential of InSe/Graphene heterostructures for advanced optoelectronic devices and contribute to further advancements in this field.
Review
Chemistry, Multidisciplinary
Krishan Kumar, Maria Waechtler
Summary: The use of colloidal nanocrystals in artificial photosynthetic systems has gained attention due to their strong light absorption and tunable properties. However, complete photocatalytic conversion of water to its components still remains a challenge. This review discusses recent progress in understanding charge carrier dynamics in semiconductor nanocrystals and the influence of parameters such as dimension and composition. Transient absorption spectroscopy and the challenges associated with accumulating multiple charge carriers for targeted chemical reactions are also addressed.
Article
Chemistry, Physical
Yuanzhi Jiang, Junli Wei, Mingjian Yuan
Summary: Quasi-2D perovskites are seen as next-generation materials for light-emitting applications due to their excellent radiative efficiency and processability. They possess an energy-funneling process and can meet the requirements of stable emission and display technologies through various engineering strategies, providing promising directions for future advancements.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Yiqing Shu, Zijun Zhong, Chunyang Ma, Penglai Guo, Leiming Wu, Zhitao Lin, Xun Yuan, Jianqing Li, Weicheng Chen, Quanlan Xiao
Summary: In this research, a two-dimensional BP/InSe heterostructure was successfully fabricated and its optical properties were studied. By preparing an SA based on BP/InSe, stable soliton pulses and harmonic mode locking were achieved. The findings demonstrate the potential of 2D BP/InSe heterostructure in the applications of nano-photonics devices.
Article
Chemistry, Multidisciplinary
Le-Yang Dang, Zhan Wei, Jing Guo, Tian-Hao Cui, Yongjie Wang, Jie-Cai Han, Gui-Gen Wang
Summary: This study presents a type-I heterojunction consisting of 2D Bi2O2Se and lead-free bismuth perovskite CsBi3I10 for fast response and broadband detection. Through effective charge transfer and strong coupling effect at the Bi2O2Se/CsBi3I10 interfaces, the response time is accelerated, and the detection range is expanded, exhibiting excellent photo-response performance.
Article
Chemistry, Multidisciplinary
Silvia G. Motti, Manuel Kober-Czerny, Marcello Righetto, Philippe Holzhey, Joel Smith, Hans Kraus, Henry J. Snaith, Michael B. Johnston, Laura M. Herz
Summary: Metal halide perovskite (MHP) semiconductors have revolutionized optoelectronic technologies for high-efficiency photovoltaic applications. This study investigates the charge carriers and their transport mechanisms in low-dimensional MHPs using ultrafast optical and terahertz spectroscopy. The findings provide new insights into the interplay of exciton and free-carrier populations in 2D MHPs and demonstrate the potential of these semiconductors for solar cells, transistors, and electrically driven light sources.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Physics, Multidisciplinary
Eugenio Cinquanta, Eva Arianna Aurelia Pogna, Lorenzo Gatto, Salvatore Stagira, Caterina Vozzi
Summary: This review discusses the rich ultrafast response at terahertz frequencies of two-dimensional materials. It explores the potential of van der Waals organic and inorganic 2D materials, such as graphene and transition metal dichalcogenides, for nano-electronic and nano-photonic device development. The review provides an overview of experimental schemes for inspecting the ultrafast response of 2D materials, presents the relevant results, and discusses the emergence of tools for characterizing ultrafast THz dynamics at the nanoscale.
ADVANCES IN PHYSICS-X
(2023)
Article
Materials Science, Multidisciplinary
Chenduan Chen, Ningning Dong, Jiawei Huang, Xin Chen, Hongqiang Wang, Zixin Wang, Jun Wang
Summary: This study investigates the nonlinear optical properties and ultrafast carrier dynamics of indium selenide nanosheets obtained via liquid-phase exfoliation under pulsed excitation with different durations. InSe nanosheets exhibit varying saturable absorption responses and scattering phenomena under different pulse durations, attributed to thermal effects and dynamic spatial self-phase modulation. Pump-probe measurements reveal ultrafast saturable absorption and photoinduced absorption processes in InSe dispersions, potentially caused by free carrier absorption or bandgap renormalization.
ADVANCED OPTICAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yu Wang, Huang Wu, Weigang Zhu, Xiaotao Zhang, Zheyuan Liu, Yishi Wu, Changfu Feng, Yanfeng Dang, Huanli Dong, Hongbing Fu, Wenping Hu
Summary: Large-area 2D cocrystals with strong near-infrared absorption have been successfully designed and prepared through intermolecular charge-transfer interactions. Tuning the growth solvents and processes allows for morphological control, resulting in enhanced CT absorption and excellent device performance in the NIR region. Transient absorption spectroscopy and device configuration optimization play key roles in generating long-lived free charge carriers and improving the responsivity and response time of the cocrystals.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Jialin Li, Lizhen Wang, Yuzhong Chen, Yujie Li, Haiming Zhu, Linjun Li, Limin Tong
Summary: Interface interactions in 2D vertically stacked heterostructures are important in optoelectronic applications, and recent research has shown promising performance of photodetectors based on graphene/InSe heterostructures. However, there is still insufficient understanding of the nonlinear optical properties of graphene/InSe heterostructures. In this study, a graphene/InSe heterostructure was fabricated by mechanical exfoliation and the optically induced charge transfer between the heterostructures was investigated. The results revealed a large built-in electric field at the interface and demonstrated the potential application of the heterostructure in a mode-locked laser. This work provides deeper insights into the interface interactions and enriches the range of saturable absorbers for ultrafast photonics applications.
Article
Chemistry, Physical
Shakeel Ahmed, Wang Rui, Faizah Altaf, Jahanzeb Khan, Patrizia Bocchetta, Han Zhang
Summary: The carrier dynamics of 2D tri-TMDCs provide a platform for studying excitons. In this study, ZrTe3 nanosheets were investigated using transient absorption spectrometer. Different carrier dynamics were observed at different pump powers and wavelengths. The shorter decay constant is related to electron-phonon relaxation, while the longer decay constant represents charge separation. TA spectroscopy provides insight into carrier lifetime, cooling dynamics, diffusion, and excitations.
Article
Computer Science, Artificial Intelligence
Weichun Huang, Yixue Yang, Xiaohui Huang, Zhiying Peng, Liyan Xiong
Summary: In recent years, a new fine-grained task called emotion-cause pair extraction (ECPE) has been proposed in sentiment analysis field, aiming to extract all emotions and their causes from a document. However, existing methods often ignore the relationship between emotion clauses and cause clauses. To address this, we propose an end-to-end framework that uses interactive attention and fusion mechanism to learn the relationship between emotions and causes, achieving better results than state-of-the-art baselines.
APPLIED INTELLIGENCE
(2023)
Article
Chemistry, Multidisciplinary
Xi Zhang, Kangpu Li, Bo Wen, Jiang Ma, Dongfeng Diao
Summary: In this study, a distance contribution descriptor (DCD) was constructed using machine learning (ML) and density functional theory (DFT) was used to calculate the Gibbs free energies (AGH) of 46,000 *H binding sites on the Pt@PdNiCuP surface. The results revealed that the H-metal bonding configuration in the H-Pt distance region of 2.0-2.5 A was mainly bridge or hollow bonding. The contribution analysis of DCD indicated that the catalytic behavior of the amorphous alloy was determined by the joint effect of Pt, Pd, and Ni atoms.
CHINESE CHEMICAL LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Tianzhong Li, Jinyong Wang, Tongkai Chen, Swelm Wageh, Ahmed A. Al-Ghamdi, Jiangtian Yu, Zhongjian Xie, Han Zhang
Summary: In this study, a drug formulation based on lactic acid bacteria (LAB) was developed to produce reactive oxygen species (ROS) in tumors and induce host immunity. The LAB were modified with zeolitic imidazolate framework-67 (ZIF-67) and effectively delivered into tumor cells, leading to the generation of ROS upon light exposure. The bacterial hybrid induced tumor shrinkage through photodynamic therapy and stimulated inflammation to attract immune cells for cancer elimination.
SCIENCE CHINA-MATERIALS
(2023)
Article
Optics
J. I. N. F. E. N. Hong, J. I. N. H. A. I. Zou, Y. U. S. H. U. Wang, Q. I. U. J. U. N. Ruan, T. I. N. G. T. I. N. G. Chen, Y. A. N. G. Cheng, Y. I. K. U. N. Bu, Z. H. E. N. G. Q. I. A. N. Luo
Summary: We present a compact continuous-wave all-fiber cyan laser, which achieves downconversion cyan lasing at 491.5 nm with a maximum output power of 97.5 mW, a slope efficiency of 23.7%, and a power fluctuation of less than 0.41%. This all-fiber cyan laser has great significance in expanding the color reproduction range of laser displays and has potential applications in fluorescence imaging, underwater communication, and detection.
Article
Optics
Hang Wang, Yadi Yang, Jinfen Hong, Xin Zhou, Qiujun Ruan, Zhipeng Dong, Mikhail Melkumov, Sergey Firstov, Alexey Lobanov, Zhengqian Luo
Summary: In this study, we demonstrate a dissipative soliton resonance (DSR) in a bismuth-doped phosphosilicate fiber (Bi-PSF) laser operating at dual-wave bands of 1.3/1.4 μm. By utilizing a homemade Raman fiber laser at 1239 nm as the pump source and a non-linear amplifying loop mirror for initiating mode-locking, stable DSR operation is achieved at the wavelengths of 1343 nm and 1406 nm with large spectral bandwidths. This work opens up opportunities for various applications, including all-spectral-band communications, bio-medical imaging, and terahertz difference frequency generation.
Article
Materials Science, Multidisciplinary
Dapeng Huang, Fei Liang, Ruiqi Guo, Dazhi Lu, Jiyang Wang, Haohai Yu, Huaijin Zhang
Summary: In this study, the broadband self-trapped exciton (STE) states are demonstrated for the first time in Mo-vacancy-rich MoSi2N4 films. The modulation effect of STE states on nonlinear optical processes is verified, which opens up new possibilities for the construction of novel devices and practical applications.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Zhiheng Ren, Jixiao Li, Minghui Cai, Ruonan Yin, Jianneng Liang, Qianling Zhang, Chuanxin He, Xiantao Jiang, Xiangzhong Ren
Summary: Polymer electrolytes (PEs) synthesized from an in situ polymerization strategy have been developed to improve interfacial compatibility. However, most of these PEs still face challenges such as low lithium-ion transference number (tLi+) and insufficient ionic conductivity at room temperature (RT). In this study, copolymer electrolytes (CPEs) consisting of 1,3-dioxolane (DOL) and 1,3,5-trioxane (TXE) monomers were synthesized, which exhibited excellent ionic conductivity and high lithium-ion transference number at RT. The CPEs also showed good performance and safety in various battery systems.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Editorial Material
Chemistry, Multidisciplinary
Mengke Wang, Weichun Huang
Article
Optics
Tianran Li, Ziyu Wang, Jinhai Zou, Jinfen Hong, Qiujun Ruan, Hang Wang, Zhipeng Dong, Zhengqian Luo
Summary: This study demonstrates, for the first time, the direct generation of millijoule-level green pulses from a fiber laser, overcoming the limitations of near-IR laser frequency conversion and providing a model for compact, high-efficiency, and high-energy visible fiber pulsed lasers.
PHOTONICS RESEARCH
(2023)
Article
Biochemistry & Molecular Biology
Ching-Han Liu, Shih-Chung Huang, Chun-Hao Yin, Wei-Chun Huang, Jin-Shuen Chen, Yao-Shen Chen, Su-Ting Gan, Shiow-Jyu Tzou, Ching-Tsai Hsu, Hao-Ming Wu, Wen-Hwa Wang
Summary: Individuals of Asian descent have a higher risk of developing hyperuricemia and gout compared to Western populations. Urate-lowering therapy is effective in treating hyperuricemia and gout. However, the association between febuxostat, a type of urate-lowering therapy, and atrial fibrillation (AF) in Asian populations has not been properly investigated.
Article
Optics
Liquan Zhu, Zhipeng Dong, Jinhai Zou, Linxiao Deng, Ting Li, Yuantong Chen, Chun Gu, Lixin Xu, Zhengqian Luo
Summary: This study investigates the use of optical fiber lasers in display systems by integrating a Pr3+-doped green all-fiber laser into a laser projection display system. A 520 nm semiconductor green laser diode module was integrated as a control group for comparison. The color gamut and speckle performances were studied and compared. The experimental group showed slightly better performance in color gamut volume, and the speckle contrast rapidly decreased with increasing power. This study is the first to apply a fiber laser to a laser display system, providing insights for developing speckle-free or speckle-reduced laser display systems.
Article
Engineering, Environmental
Jiahui Hou, Junhao Lin, Lin Fang, Xi Zhang, Rui Ma, Juan Luo
Summary: Steel slag can be converted into catalysts with multi-metal oxide fractions by regulating the pH of the pretreatment process and using microwave calcination technology, enhancing its catalytic and microwave absorption functions for the conversion of waste engine oil into light fuel.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Electrical & Electronic
Zhipeng Dong, Hang Wang, Wencheng Jia, Jinhai Zou, Zhengqian Luo
Summary: In this study, a 488 nm blue picosecond pulse was generated by frequency doubling a homemade 977 nm picosecond fiber laser. The original laser had a 977.84 nm central wavelength, 0.13 nm spectral width, 12.94 ps pulse duration, 76.09 MHz repetition rate, and 5.12 mW average power. After scaling up the power to 2.06 W, the pulse duration and spectral width slightly increased to 16.84 ps and 0.24 nm, respectively. The blue picosecond laser achieved a central wavelength of 488.92 nm and a linewidth of 0.17 nm. This compact and high-power laser has potential applications in high-resolution imaging, underwater detection, and material processing.
IEEE PHOTONICS TECHNOLOGY LETTERS
(2023)
Article
Engineering, Electrical & Electronic
Hang Wang, Ziyu Wang, Wencheng Jia, Luming Song, Tingting Chen, Jinhai Zou, Zhipeng Dong, Zhengqian Luo
Summary: A 978 nm ultrafast fiber laser was demonstrated with a robust all-polarization-maintaining mode-locking using a phase-biased nonlinear amplifying loop mirror. It achieved a stable self-starting mode-locking with an average output power of 2.12 W. The laser was further amplified and used for second harmonic generation, producing a 489 nm ultrashort laser.
IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS
(2023)
Article
Optics
Hang Wang, Wencheng Jia, Yongjia Yao, Xinyun Yang, Mikhail Melkumov, Sergey Firstov, Alexey Lobanov, Zhipeng Dong, Zhengqian Luo
Summary: In this study, a 1.3/1.4μm random fiber laser (RFL) was successfully generated using bismuth-doped phosphosilicate fiber. The RFL showed excellent long-term operational stability and a wide emission spectrum. Compared to traditional laser sources, the RFL reduced the speckle contrast of images.
CHINESE OPTICS LETTERS
(2023)