4.6 Article

Large-Area 3D Plasmonic Crescents with Tunable Chirality

Journal

ADVANCED OPTICAL MATERIALS
Volume 7, Issue 15, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.201801770

Keywords

chirality; colloidal lithography; multipole decomposition; plasmonics; split-ring resonator

Funding

  1. Deutsche Forschungsgemeinschaft (DFG) [VO 1824/434 5-1]

Ask authors/readers for more resources

Chiral plasmonic nanostructures hold promise for enhanced chiral sensing and circular dichroism spectroscopy of chiral molecules. It is therefore of interest to fabricate chiral plasmonic nanostructures with tailored chiroptical properties over large areas with reasonable effort. Here, a colloidal lithography approach is used to produce macroscopic arrays of sub-micrometer 3D chiral plasmonic crescent structures over areas >1 cm(2). The chirality originates from symmetry breaking by the introduction of a step within the crescent structure. This step is produced by an intermediate layer of silicon dioxide onto which the metal crescent structure is deposited. It is experimentally demonstrated that the chiroptical properties in such structures can be tailored by changing the position of the step within the crescent. These experiments are complemented by finite element simulations and the application of a multipole expansion to elucidate the physical origin of the circular dichroism of the crescent structures.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Acoustic Crystallization of 2D Colloidal Crystals

Johannes Menath, Reza Mohammadi, Jens Christian Grauer, Claudius Deters, Maike Boehm, Benno Liebchen, Liesbeth M. C. Janssen, Hartmut Loewen, Nicolas Vogel

Summary: 2D colloidal crystallization is a simple strategy for producing defined nanostructure arrays over large areas. The study introduces a loudspeaker setup for the acoustic crystallization of 2D colloidal crystals at liquid interfaces, which increases the average grain size significantly. The process is optimized using frequency and amplitude of sound waves, and computer simulations show the mechanisms behind defect removal. The experimentally simple process provides access to highly defined nanostructure arrays for various research communities.

ADVANCED MATERIALS (2023)

Article Chemistry, Multidisciplinary

A Continuous Gradient Colloidal Glass

Marius Schoettle, Tobias Lauster, Lukas J. Roemling, Nicolas Vogel, Markus Retsch

Summary: Researchers have developed a general synthetic approach to creating continuous size gradient colloidal ensembles. By synthesizing a dispersion with a specifically designed gradual particle size distribution and then allowing self-assembly, they obtained a photonic colloidal glass with a continuous size gradient. Characterization methods demonstrated the potential of this mesostructure, including vivid structural colors and superior light scattering across the gradient.

ADVANCED MATERIALS (2023)

Article Chemistry, Multidisciplinary

Sustainable Repellent Coatings Based on Renewable Drying and Nondrying Oils

Katharina E. Dehm, Teresa Walter, Matthias Weichselgartner, Ryan W. Crisp, Kirsten Wommer, Martin Aust, Nicolas Vogel

Summary: This study presents a sustainable coating process based on renewable materials to prepare surface coatings with superhydrophobic and liquid-infused properties. It uses natural drying oils as polymeric binder and silica particles for surface topographies that create self-cleaning and slippery features. The study demonstrates the potential of renewable oils as lubricants and their applicability in reducing adhesion in real-world scenarios.

ADVANCED MATERIALS INTERFACES (2023)

Article Chemistry, Multidisciplinary

Full Control of Plasmonic Nanocavities Using Gold Decahedra-on-Mirror Constructs with Monodisperse Facets

Shu Hu, Eoin Elliott, Ana Sanchez-Iglesias, Junyang Huang, Chenyang Guo, Yidong Hou, Marlous Kamp, Eric S. A. Goerlitzer, Kalun Bedingfield, Bart de Nijs, Jialong Peng, Angela Demetriadou, Luis M. Liz-Marzan, Jeremy J. Baumberg

Summary: Bottom-up assembly of nanoparticle-on-mirror (NPoM) nanocavities enables precise inter-metal gap control down to approximate to 0.4 nm for confining light to sub-nanometer scales, thereby opening opportunities for developing innovative nanophotonic devices. However limited understanding, prediction, and optimization of light coupling and the difficulty of controlling nanoparticle facet shapes restricts the use of such building blocks.

ADVANCED SCIENCE (2023)

Article Materials Science, Multidisciplinary

Electrostatic Powder Coating as a Novel Process for High-Voltage Insulation Applications

Moritz Scholl, Nicolas Vogel, Steffen Lang

Summary: This article presents a novel strategy for manufacturing the main insulation of high-voltage rotating machines using electrostatic powder coating equipment. The process is fully automated, allowing for precise and reproducible application of homogeneous powder coating layers. The strategy improves powder adhesion and minimizes defect density, surpassing the state-of-the-art process in terms of partial discharge activity.

ADVANCED ENGINEERING MATERIALS (2023)

Article Chemistry, Multidisciplinary

How Colloidal Lithography Limits the Optical Quality of Plasmonic Nanohole Arrays

Eric S. A. Goerlitzer, Meichen Zhan, Sukyung Choi, Nicolas Vogel

Summary: Colloidal lithography is a simple and convenient method for fabricating complex nanostructures using self-assembled particle monolayers as lithographic masks. However, imperfections in the process can impair the optical quality of arrayed nanostructures. This study emphasizes the importance of detailed structure-property relationships and reveals the individual role of packing order, organic impurities, and solid polymer bridges on the optical properties of nanohole arrays.

LANGMUIR (2023)

Article Chemistry, Multidisciplinary

Quantitative Optical and Structural Comparison of 3D and (2+1)D Colloidal Photonic Crystals

Lukas J. Roemling, Gudrun Bleyer, Eric S. A. Goerlitzer, Georgy Onishchukov, Nicolas Vogel

Summary: Colloidal crystals are ideal models for studying self-assembly and structural coloration due to their periodic nature aligning with visible light wavelengths. This study compares two assembly methods for colloidal crystals and examines the influence of imperfections on structural coloration. The findings demonstrate the robustness of structural coloration in the presence of defects and irregularities.

LANGMUIR (2023)

Article Nanoscience & Nanotechnology

Molecular-Induced Chirality Transfer to Plasmonic Lattice Modes

Eric Sidney Aaron Goerlitzer, Mario Zapata-Herrera, Ekaterina Ponomareva, Deborah Feller, Aitzol Garcia-Etxarri, Matthias Karg, Javier Aizpurua, Nicolas Vogel

Summary: Molecular chirality is transferred to plasmonic lattice modes, providing a effective and tunable means to control chirality. Non-close packed, periodic arrays of achiral gold nanoparticles embedded in a polymer film are used to demonstrate this chirality transfer. The surface lattice resonances become optically active in the presence of chiral molecules, showing handedness-dependent excitation. Numerical simulations and a semi-analytical model rationalize this chirality transfer.

ACS PHOTONICS (2023)

Article Optics

A high-precision silicon-on-insulator position sensor

Paul Beck, Laura C. Wynne, Simone Iadanza, Liam O'Faolain, Sebastian A. Schulz, Peter Banzer

Summary: In this study, a high-precision optical position sensor is presented, which is fabricated on a silicon-on-insulator platform. The sensor utilizes the principle of position-dependent directional waveguide coupling by exciting a monolithically integrated scatterer using a tightly focused polarization-tailored beam. A spatial resolution of 7.2 nm, corresponding to approximately ?/200, is demonstrated.

APL PHOTONICS (2023)

Article Chemistry, Multidisciplinary

Fast Gas-Adsorption Kinetics in Supraparticle-Based MOF Packings with Hierarchical Porosity

Atsushi Fujiwara, Junwei Wang, Shotaro Hiraide, Alexander Goetz, Minoru T. Miyahara, Martin Hartmann, Benjamin Apeleo Zubiri, Erdmann Spiecker, Nicolas Vogel, Satoshi Watanabe

Summary: Metal-organic frameworks (MOFs) are microporous adsorbents with unique adsorption characteristics for high-throughput gas separation. However, compacting these particles into macroscopic pellets can lead to mass-transport limitations. This study addresses this issue by forming materials with structural hierarchy using a supraparticle-based approach. The results demonstrate that pellets packed with supraparticles exhibit a significantly faster adsorption rate compared to unstructured pellets, highlighting the importance of controlling structural hierarchy for maximizing material performance.

ADVANCED MATERIALS (2023)

Article Materials Science, Multidisciplinary

Mechanical Stability of Liquid-Infused Surfaces Based on Mussel-Inspired Polydopamine Chemistry

Salvatore Chiera, Melissa Ghetina, Thomas Zimmermann, Susanne Wintzheimer, Claudia Stauch, Peer Loebmann, Karl Mandel, Nicolas Vogel

Summary: Liquid-infused surfaces with remarkable repellency properties have wide applications in maintaining clean and high-performing surfaces. The use of polydopamine (PDA) as a base layer offers the advantage of adhering to any substrate and being chemically modified. Strategies to improve the mechanical stability of these coatings have been explored, including incorporating imidazole during film formation and forming a composite with a siliceous porous coating. These strategies exhibit improved resistance to shearing and dynamic impact, and the enhanced mechanical properties are successfully transferred to liquid-infused surfaces.

MACROMOLECULAR MATERIALS AND ENGINEERING (2023)

Article Nanoscience & Nanotechnology

Stiffness influence on particle separation in polydimethylsiloxane-based deterministic lateral displacement devices

Julius Marhenke, Tobias Dirnecker, Nicolas Vogel, Mathias Rommel

Summary: This study focuses on the challenges and issues encountered with PDMS material in microfluidic deterministic lateral displacement (DLD) devices, particularly the pressure-induced effects related to particle separation. The study found that PDMS deformation can be solved by thermal annealing, leading to improved separation performance in the devices. However, increased stiffness also constrains the maximum applicable throughput. The study derives an iterative model for calculating pressure distribution and deformation using measurements and numerical simulations, explaining the observed separation characteristics and throughput constraints.

MICROFLUIDICS AND NANOFLUIDICS (2023)

Article Chemistry, Multidisciplinary

Preparation and Surface Functionalization of a Tunable Porous System Featuring Stacked Spheres in Cylindrical Pores

M. Christhy V. V. Ruiz, Markus Terlinden, Matthias Engelhardt, Giulia Magnabosco, Georg Papastavrou, Nicolas Vogel, Matthias Thommes, Julien Bachmann

Summary: A geometrically tunable nanoporous system with enhanced active surface area is fabricated by stacking spheres in cylindrical pores. Straight, constricted pores are obtained through anodization of metallic aluminum. Polystyrene spheres are assembled inside the pores and serve as a filter. The system's geometry is determined by mechanical stacking rather than surface chemical interactions.

ADVANCED MATERIALS INTERFACES (2023)

No Data Available