4.4 Article

An amphiphilic supramolecular polymer: Construction, self-assembly and pH-responsive behavior in water

Journal

TETRAHEDRON LETTERS
Volume 60, Issue 26, Pages 1727-1731

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.05.058

Keywords

Self-assembly; Supramolecular polymer; Amphiphilic; pH-responsive

Funding

  1. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
  2. Hunan Graduate Science and Technology Innovation Projects [2018-400]
  3. Program for Innovative Talent Team of Hengyang [2017-1]
  4. Key Project of Hengyang Science and Technology Department [2017KJ166]

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A novel amphiphilic supramolecular polymer (ASP) with rigid linear main chain has been constructed by the co-assembly of a rigid amphiphilic monomer and cucurbit[8]uril (CB[8]) in water, driven by CB[8]-based host-guest interactions. The ASP could further self-assemble into well-defined architectures including nanotubes and 2D films, depending on its concentration. Moreover, pH-responsive behavior of the ASP was also observed. (C) 2019 Elsevier Ltd. All rights reserved.

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