Article
Chemistry, Physical
Wanting Liu, Xue Yang, Yixia Ren, Meili Zhang, Zhixiang Wang, Jijiang Wang
Summary: Two 2D luminous zinc(II) coordination polymers were synthesized and characterized. These polymers exhibited 2D network structures and showed potential for sensing antibiotics and solvents.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Mengyu Niu, Xiaoping Yang, Yanan Ma, Wenxin Hao, Xilong Leng, Desmond Schipper
Summary: In this study, two NIR luminescent Zn(II)/Cd(II)-Yb(III) complexes were synthesized using a Schiff base ligand with a binaphthyl backbone. The Cd(II)-Yb(III) complex 2, with a triangular structure, showed interesting luminescent sensing activity towards antibiotics CPFX and NFX, unaffected by the presence of other antibiotics tested.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Hui-Yun Lo, Po-Min Chuang, Yu -Lin Liu, Jing-Yun Wu
Summary: The two isostructural luminescent Zn coordination polymers show good chemical stability and emit bright cyan- and blue-light fluorescence, making them good dual-responsive optical chemosensors for volatile iodine detection.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Zhao-Di Zhou, Zi-Long Xu, Dan Wang, Lin-Fang Jia, Han-Qing Zhao, Bao-Yi Yu, Chong-Chen Wang
Summary: Two coordination polymers with one- and two-dimensional architectures were synthesized using Zn(II) ion and different organic linkers. The two polymers displayed effective, sensitive, and selective abilities towards Fe3+ and Cr2O72- ions, while CP-1 showed better performance in sensing metamitron and CP-2 was highly sensitive towards imidacloprid. The quenching of fluorescence intensity involves the inner filter effect and the fluorescence resonance energy transfer effect.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Analytical
Po-Min Chuang, Yi-Jung Tu, Jing-Yun Wu
Summary: A benzothiadiazole-functionalized luminescent Zn(II) coordination polymer with solvent-responsive fluorescence and stability has been successfully constructed. It shows bright fluorescence in solid-state and solution-phase, with sensitivity to pH.
SENSORS AND ACTUATORS B-CHEMICAL
(2022)
Article
Chemistry, Multidisciplinary
Haitao Hong, Ni Wu, Mingxi Han, Zhiyong Guo, Hongbing Zhan, Shaowu Du, Banglin Chen
Summary: CTFs are a type of porous organic material that have become increasingly popular in research fields such as gas separation, heterogeneous catalysis, etc., due to their heteroatom effect and unique chemical stability. The DPA-CTF material studied in this research showed promising potential as a chemical sensor for nitroaromatic compounds and Fe3+ ions, exhibiting high sensitivity and detection performance.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Guang-Lin Wang, Yue Lu, Run Wang, Devyani Srivastava, Abhinav Kumar, Hiroshi Sakiyama, Mohd. Muddassir, Jian Guo, Jun-Cheng Jin
Summary: A robust 3D supramolecular Zn(II)-based coordination polymer has been synthesized and characterized, showing high environmental stability and efficient fluorescent response towards sulfasalazine (SLA) as a sensor material.
Article
Chemistry, Multidisciplinary
Ma Jianxin, Liu Xiaodong, Xu Na, Liu Guocheng, Wang Xiuli
Summary: A porous coordination polymer CP 1 was synthesized and characterized, which exhibited good fluorescent sensing performance, reversible electrochemical behavior, and potential application in removing organic pollutants.
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
(2022)
Article
Chemistry, Applied
Mingming Wei, Lilin Luo, Ruifang Cui, Xiong Wang, Jingyao Chen, Zelun Cai, Xia Li, Huibo Wei, Chen Wei, Zuqiang Bian
Summary: New lanthanide coordination polymers with high thermal and solvent stability were synthesized through a hydrothermal method. One of the coordination polymers showed a very high photoluminescence quantum yield and has potential applications in light conversion and antibiotic detection.
Article
Nanoscience & Nanotechnology
Sheeba Khan, Sanjay K. Mandal
Summary: Novel metal-organic coordination networks functionalized with amino acids were synthesized for the selective sensing of perrhenate ion (ReO4-) in water with high luminescent properties. These neutral sensors demonstrated excellent selectivity, stability, and recyclability, providing a new approach for environmental monitoring.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Inorganic & Nuclear
Ya Chen, Xiaoping Yang, Yuebo Cheng, Lijie Zhang, Zhi Yang, Desmond Schipper
Summary: A tubelike Zn(II)-Yb(III) cluster was synthesized and showed a regulatable near-IR-luminescent response to nitrofuran antibiotics and fluoroquinolones with high sensitivity.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Jia-Ning Cui, Hui Zhu, Guang-Hua Cui
Summary: The water-stable luminescent coordination polymer synthesized in this study possesses a stable 3D framework and can be used as a luminescent probe for detecting acetylacetone and Fe3+ ions.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Ya Liu, Lianshe Fu, Gui-Ying Dong
Summary: This study presents the synthesis of two new water-stable ternary coordination polymers through a hydrothermal process. These polymers exhibit high sensitivity and selectivity for sensing antibiotics and heavy metal ions and demonstrate excellent thermal and chemical stability in a wide pH range.
INORGANICA CHIMICA ACTA
(2022)
Article
Chemistry, Physical
Xiang-Wen Wang, Yu-Qiao Su, Vladislav A. Blatov, Guang-Hua Cui
Summary: Three new ternary Zn(.)-based coordination polymers were synthesized and characterized. One of them exhibits a 1D trapezoidal chain structure, which is further expanded into a 2D supramolecular layer through π-π stacking interaction. Another one shows an unusual 3, 5, 6-coordinated simplified underlying network, while the third one reveals a 2D hcb sheet structure and extends into a 3D supramolecular framework via classic hydrogen bond interactions. These three polymers and their paper-based sensors are highly sensitive and selective for the detection of levofloxacin and benzaldehyde.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Sibo Wang, Bo Sun, Zhongmin Su, Guohui Hong, Xiao Li, Yanling Liu, Qingqing Pan, Jing Sun
Summary: In this study, five isostructural lanthanide metal-organic frameworks were synthesized and shown to have excellent processability and multifunctional luminescent characteristics. One of the compounds also demonstrated excellent temperature sensing performance. Additionally, two of the compounds were found to be fluorescent sensors for detecting multiple substances.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Masoume Malmir, Majid M. Heravi, Zahra Yekke-Ghasemi, Masoud Mirzaei
Summary: In this study, a tri-component composite consisting of Fe3O4 nanoparticles, Keggin-type polyoxometalate, and graphene oxide was prepared and investigated as a catalyst for the oxidation of sulfides to sulfoxides. The catalyst showed excellent stability, high yields, and recyclability, making it a promising choice for organic-inorganic hybrid catalytic reactions conducted under mild conditions.
Article
Chemistry, Inorganic & Nuclear
Samuel D. Juarez-Escamilla, Sriloy Dey, Bruno Donnadieu, T. Keith Hollis
Summary: In this study, a bidentate Mo complex was synthesized using metalation and transmetalation methodology. The synthesis was optimized to achieve a high yield. The crystal structure of the bidentate complex was determined. Additionally, alternative forms of ligands were discovered in the reaction.
Article
Chemistry, Inorganic & Nuclear
Mohamed H. Abdel-Rhman, Ghada Samir, Mostafa A. Hussien, Nasser M. Hosny
Summary: This study investigated the dissolution performance of hydrazine carbonate solution on zirconium dibutyl phosphate (Zr-DBP), and found that hydrazine carbonate solution could promote the dissolution of Zr-DBP. The effects of dissolution temperature and hydrogen peroxide concentration on the dissolution efficiency were also explored, and the corrosion effect on stainless steel by hydrazine carbonate solution was studied.
Article
Chemistry, Inorganic & Nuclear
Qiaofang Fu, Fangyu Tan, Wu Ying
Summary: This study successfully prepared vermiculite/g-C3N4/TiO2 composites and found that under specific conditions, the composites exhibited excellent degradation effects, with a high degradation rate for methylene blue. Additionally, the composites were able to enhance surface area, reduce carrier loading rate, improve light energy utilization, and enhance durability.
Article
Chemistry, Inorganic & Nuclear
Annabelle G. W. Hodson, Robert T. Mason
Summary: Functionalised polystyrene resins have been found to be efficient catalysts in the synthesis of specific complexes, with the conversion rate controlled by the polymer structure. The addition of amines or amino acids can further yield substituted 13-butadienyl complexes, which have been analyzed by NMR.
Article
Chemistry, Inorganic & Nuclear
C. Kavitha, S. Anbarasan, P. Subramaniam
Summary: The sulfoxidation of PMAAs by the oxo(salen)chromium(V) complex in aqueous acetonitrile medium was studied. The rate of the reaction is influenced by the polarity of the medium and the substituents on PMAA, with electron donating substituents accelerating the reaction and electron withdrawing substituents retarding the reaction.
Article
Chemistry, Inorganic & Nuclear
Qiang-Qiang Liu, Mithun Kumar Ghosh, Shu-Lan Cai, Xiao-Hong Liu, Lu Lu, Mohd. Muddassir, Tanmay Kumar Ghorai, Jun Wang
Summary: Three newly developed coordination polymers (CPs) with semiconducting properties were synthesized using hydrothermal methods. These CPs exhibit superior photocatalytic activity and can degrade organic pollutants effectively.
Article
Chemistry, Inorganic & Nuclear
Mehrnaz Aliahmadi, Ali Nemati Kharat, Jan Janczak
Summary: This study proposes a method for synthesizing allyl alcohol using cost-effective and renewable bio-resource glycerol. By utilizing catalysts, alcohol as a solvent, and a reducing agent, allyl alcohol with an efficiency of 100% was obtained. The structures of the newly synthesized complexes were determined using X-ray single crystallography.
Article
Chemistry, Inorganic & Nuclear
Ji-Yan Gao, Nan Zhang, Dong-Sheng Huang, Xiang-Rong Liu, Zai-Wen Yang, Shun-Sheng Zhao
Summary: Two new transition metal complexes I and II were synthesized and characterized. The complexes exhibited strong thermal stabilities and showed effective binding to CT-DNA and BSA. Complex II exhibited stronger inhibition activity against P. aeruginosa than gentamicin sulfate. These complexes have potential applications in drug research.
Article
Chemistry, Inorganic & Nuclear
Rishabh Ujjval, Hilal Ahmad Khan, Chinnappan Sivasankar, Natesan Thirupathi
Summary: In this study, a rigid 2-aminobenzimidazole type guanidine and its platinum complexes were synthesized through a series of reactions and characterized by various physical and chemical methods. The reaction mechanism was also explained through DFT calculations.
Article
Chemistry, Inorganic & Nuclear
Marcelo Carpes Nunes, Thais Zaboenco, Vinicius Kemper Melara, Gabriel Barros Baptistella, Andre Luiz Barboza Formiga, Andersson Barison, Fabio Souza Nunes
Summary: A new luminescent molecular thermometer has been developed, which uses the spin-crossover equilibrium of a nickelcyclen derivative to measure temperature. The sensor shows high sensitivity and accuracy.
Article
Chemistry, Inorganic & Nuclear
Yuyu Shan, Zhenqin Zhao, Xia Zhang, Zhan Wu, Xiu-Ling Li
Summary: In this study, a new bridging ligand was synthesized through refluxing, and two mononuclear Cu(I) complexes and two trinuclear Cu(I)-Eu(III) complexes were obtained through self-assembly. The Cu(I) antenna chromophores successfully transferred energy to the Eu(III) centers, achieving sensitized Eu(III) luminescence.
Article
Chemistry, Inorganic & Nuclear
Gabriela Sanchez-Lecuona, Mayra C. Vazquez-Nunez, Bruno Donnadieu, Miguel A. Munoz-Hernandez, Virginia Montiel-Palma
Summary: The reaction of RuHCl(PPh3)3 with GaMe3 has been studied and the obtained complexes were analyzed in detail. The results indicate the formation of a Ru-Ga bond, suggesting the generation of an in situ formed ambiphilic phosphinogallyl ligand. This is of significance for understanding the interaction between metal-halogen bonds and metal-small molecule bonds.
Article
Chemistry, Inorganic & Nuclear
Sevil Sener, Nursel Acar, Fatih Dumludag
Summary: The synthesis, characterization, spectroscopic and bonding features of a new Co (II) phthalocyanine compound containing two thiocarbohydrazone groups were explained. The compound showed semiconductor properties and potential as a temperature sensor.
Article
Chemistry, Inorganic & Nuclear
Ledja B. O. Davi, Aryanna S. P. N. Costa, Mariana S. Silva, Adriana S. Ribeiro, Cintya D. A. E. S. Barbosa, Julio C. S. Da Silva, Dimas J. P. Lima, Daniela S. Anunciacao
Summary: In this study, a dansyl derivative sensor called o-PDDS was prepared and used for the detection of Al3+ ions in water. The o-PDDS sensor exhibited high sensitivity and linear response towards Al3+ ions. Experimental and computational studies confirmed a 1:1 stoichiometry ratio between o-PDDS and Al3+ ions. Real sample analysis demonstrated the selectivity and detection performance of the sensor, indicating its potential for field use.