Journal
ORGANIC LETTERS
Volume 21, Issue 11, Pages 4340-4344Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01520
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Funding
- National Natural Science Foundation of China [21772029, 21472028]
- National Key Technologies RD Program [2014BA-D23B01]
- Ministry of Education of Singapore [MOE2013-T2-2-003, MOE2016-T2-1-032, RG108/16]
- Singapore National Research Foundation [NRF-NRFI2016-06]
- A*STAR Individual Research Grant [A1783c0008]
- Nanyang Research Award Grant
- Nanyang Technological University
- Thousand Talent Plan
- The 10 Talent Plan (Shicengci) of Guizhou Province
- Guizhou Province Returned Oversea Student Science and Technology Activity Program, Guizhou University (China)
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An NHC-catalyzed alpha-carbon amination of chloroaldehydes was developed. Cyclohexadiene-1,2-diimines are used as amination reagents and four-atom synthons. Our reaction affords optically enriched dihydroquinoxalines that are core structures in natural products and synthetic bioactive molecules.
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