Journal
ORGANIC LETTERS
Volume 21, Issue 11, Pages 3986-3989Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01144
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Funding
- National Natural Science Foundation of China [NSFC-21502171]
- Natural Science Foundation of Zhejiang Province, China [LY17B060001]
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Two benzyne-enabled desulfurization reactions have been demonstrated which convert diaryl sulfoxides and heteroaryl sulfoxides to biaryls and desulfurized heteroarenes, respectively. The reaction accessing biaryls tolerates a variety of functional groups, such as halides, pseudohalides, and carbonyls. Mechanistic studies reveal that both reactions proceed via a common assembly process but divergent disassemblies of the generated tetraaryl(heteroaryl) sulfuranes.
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