4.7 Article

Amperometric sensing of hydrazine by using single gold nanopore electrodes filled with Prussian Blue and coated with polypyrrole and carbon dots

Journal

MICROCHIMICA ACTA
Volume 186, Issue 6, Pages -

Publisher

SPRINGER WIEN
DOI: 10.1007/s00604-019-3486-6

Keywords

Single gold nanoelectrodes; Nanoprobe; Hydrazine; Carbon dots; Electrocatalytic oxidation

Funding

  1. National Natural Science Foundation of China [21775003, 21375002]
  2. National key Research and Development project of China [2017YFD0701403]
  3. Foundation for Innovation Team of Bioanalytical Chemistry of Anhui Province

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A nanoprobe for hydrazine sensing is described that is making use of a single gold nanopore electrode (SAuNPEs) that was modified by electro-deposition of Prussian Blue (PB) and then coated with a thin membrane of polypyrrole and carbon dots in order to enhance stability and catalytic activity. Best operated at a low potential of 0.3V vs. Ag/AgCl, the nanosensor display good electrocatalytic activity towards the oxidation of hydrazine, with a linear response in the 0.5-80M hydrazine concentration range and a 0.18M detection limit (at S/N=3). The method was applied to the determination of hydrazine in human urine.

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