Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 16, Pages 6499-6503Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b02436
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Funding
- JSPS KAKENHI (S) [17H06173]
- Foundation NAGASE Science Technology Development
- Sumitomo Foundation
- JSPS KAKENHI (B) [17H03017]
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We have developed a versatile, high-yield synthesis of diarylchloroniums/lambda(3)-chloranes through the reaction of various chloroarenes with readily prepared mesityldiazonium tetrakis(pentafluorophenyl)borate under mild conditions. The scope of the reaction is broad, including ArCl, ArBr, and ArI. The diarylchloroniums/lambda(3)-chloranes prepared here show unique reactivity in various respects, enabling intermolecular electrophilic arylation reaction of weak nucleophiles, and chlorane-halogane exchange reaction.
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