Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 15, Pages 6180-6184Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b02510
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Funding
- NSERC of Canada
- Canada Research Chair
- Einstein Visiting Professorship at TU Berlin
- Alexander Graham Bell Canada Graduate Scholarship
- German Science Foundation (DFG)
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Reaction of dihydrogen and the borinium cation salt [Mes(2)B][B(C6F5)(4)] gave an arene-stabilized mesityl-borenium cation, which isotopically scrambles HD. Similarly, reaction with triethylsilane gave the diboranium cation [MesB(mu-H)(2)(mu-Mes)BMes](+) featuring three bridge-bonds between two boron centers. Reaction of same (Mes(2)BH)(2) with Bronsted acid also afforded the same diboranium whereas the corresponding reaction with (MesBH(2))(2) yielded the triboron cation [H2B(mu-H)(mu-Mes)B(mu-Mes)(mu-H)BH2](+).
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