4.6 Review

Nanozeolites: synthesized, properties, applications

Journal

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume 91, Issue 2, Pages 415-429

Publisher

SPRINGER
DOI: 10.1007/s10971-019-05012-4

Keywords

Zeolite; Nanocrystals; Synthesis; Applications

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This review focuses on the synthesis, crystallization mechanism, and application of colloidal zeolites. The synthesis formulations and features of different zeolite-type structures prepared in nanosized form are summarized. Special attention is paid to zeolites prepared as stable colloidal suspensions. Nanocrystalline zeolites comprise acceptable nanomaterials by glass areas of smaller than 100nm that own a different surface, including inner cover reactivity. Nanocrystalline zeolites, so while silica lite, ZSM-5, including A, Y, did integrate also largely identified by film X-ray diffraction, including particle microscopy. The nanocrystalline zeolites did more employed as making pieces to make bigger, low zeolite compositions by encapsulated metal or natural classes. The cover features of nanocrystalline zeolites and low-zeolite compositions received tailoring for functionalization of outside sialon organizations. Other uses of nanozeolites for the preparation of functionalized materials, for the synthesis of mesoporous silicas of improved hydrothermal stability, and as seeds for zeolite syntheses are illustrated. The emerging applications of nanozeolites in sensing, optoelectronics, and medicine constitute another topic in this review. [GRAPHICS] . HighlightsNanosized silicalite crystals can be obtained with very few framework defects.The density of connectivity defects can be adjusted in nanocrystals.The zeolite coatings exhibited good antifogging properties and could be maintained over 6 months under ambient environment.Nanozeolite Y colloids were used to prepare transparent coatings on glass substrates under mild temperature conditions.

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