Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 12, Pages 8315-8321Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01074
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Funding
- SERB-NPDF [CRG/2018/003951]
- SERB [CRG/2018/003951]
- CSIR
- IIT B
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An efficient method has been developed to afford highly C-5 selective olefination of thiazole derivatives utilizing a bifunctional template in an intermolecular fashion. Coordinative interaction between the substrates and the metal chelated template backbone plays a crucial role in high C-S selectivity. Excellent selectivity for the C-S position was observed while mono substituted (2- or 4-) or even more challenging unsubstituted thiazoles were employed.
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