Article
Polymer Science
Micah Belle Marie Yap Ang, Yun-Ting Lu, Shu-Hsien Huang, Jeremiah C. Millare, Hui-An Tsai, Kueir-Rarn Lee
Summary: Surfactants can modify the property and performance of polyamide layer during interfacial polymerization of amines and trimesoyl chloride. Different types of surfactants have different effects on the membrane, such as changing the surface charge and hydrophilicity, and affecting the water and salt transport. It is important to choose a suitable surfactant to regulate the membrane performance.
JOURNAL OF POLYMER RESEARCH
(2022)
Article
Engineering, Chemical
Nawshad Akther, Yuki Kawabata, Sungil Lim, Tomohisa Yoshioka, Sherub Phuntsho, Hideto Matsuyama, Ho Kyong Shon
Summary: Loading ultra-low concentrations of graphene oxide quantum dots (GQDs) into the polyamide (PA) layer of an outer-selective hollow fiber (OSHF) thin-film composite (TFC) membrane can enhance water permeability but may also impact membrane selectivity. Molecular dynamics simulation revealed that GQDs decrease reaction rates during interfacial polymerization (IP), reducing water permeability and acting as barriers to water molecules near the PA layer surface. At high loading, GQDs can aggregate and reduce membrane selectivity by forming non-selective voids at the interface between the PA layer and GQDs.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Mohammad Askari, Can Zeng Liang, Looh Tchuin (Simon) Choong, Tai-Shung Chung
Summary: The study developed high mechanical strength TFC-PES hollow fiber membranes for both RO and OARO processes, showing high water permeability and NaCl rejection rates. The membranes exhibit different permeability changes when exposed to different concentrations of NaCl during OARO.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Siqi Wu, Fei Wang, Shenghua Zhou, Li Long, Zhe Yang, Chuyang Y. Tang
Summary: This study systematically investigated three classical approaches for m-phenylenediamine loading during interfacial polymerization reaction and found that the vacuum-assisted method can greatly improve monomer availability and enhance the membrane structure and performance.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Xinghua Lv, Enlin Wang, Shaoxiao Liu, Liyang Liu, Yating Yin, Shuxuan Li, Baowei Su, Lihui Han
Summary: This study developed a TA-reinforced TFC HF RO membrane by using tannic acid as a reinforced additive. The membrane exhibited super hydrophilicity, thin and smooth separation layer, as well as excellent water permeance and salt rejection. It also demonstrated outstanding fouling resistance, chlorine resistance, and long-term stability, making it a promising material for brackish water desalination and tap water treatment.
Article
Engineering, Chemical
Paula Jungwon Choi, Sungil Lim, Hokyong Shon, Alicia Kyoungjin An
Summary: The outer selective hollow fiber forward osmosis (OSHF FO) membranes incorporated with negatively charged silver nanoparticles (NPs) showed better stability and fouling resistance, leading to a longer lifespan and higher flux recovery after salt cleaning.
Article
Engineering, Environmental
Z. Alihemati, S. A. Hashemifard, T. Matsuura, A. F. Ismail
Summary: TFC hollow fibers were fabricated for desalination by forward osmosis, with longer air gap distance leading to better FO performance. The effect of hollow fiber length on FO performance remains controversial.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Chemical
Tianshi Yang, Chun Feng Wan, Junyou Zhang, Chakravarthy Gudipati, Tai-Shung Chung
Summary: A novel interfacial polymerization method was proposed to fabricate TFC hollow fiber membrane modules for RO applications, successfully addressing the challenge of synthesizing defect-free polyamide selective layer. By circulating MPD and TMC solutions on different pressures to form a strong, uniform, and defect-free polyamide selective layer on the inner surface. Experimental results showed that the TFC hollow fiber membrane module prepared by this method exhibited good RO performance.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Shuwei Zhao, Pengjia Dou, Nan Sun, Ho Kyong Shon, Tao He
Summary: This study introduces a new vacuum-assisted interfacial polymerization process for optimal distribution of the aqueous phase and controlled interfacial polymerization of dialyzer membranes. The prepared forward osmosis (FO) module shows good performance and is beneficial for direct preparation of dialysate from tap water, highlighting its potential applications in home hemodialysis.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Ook Choi, Dong-Hyun Peck, Chul Ho Park
Summary: The outer-selective thin film composite (TFC) hollow fiber membranes designed in this work using novel strategies of continuous interfacial polymerization have been optimized for performance and can be used in various applications thanks to their high water flux and salt rejection capabilities.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Engineering, Chemical
Ruth Habte Hailemariam, June-Seck Choi, Mekdimu Mezemir Damtie, Hojung Rho, Kwang-Duck Park, Jonghun Lee, Yun Chul Woo
Summary: This study focused on improving the performance of polyamide thin film composite membranes through co-solvent-assisted interfacial polymerization. The results showed that adding co-solvent can enhance water flux performance of the membrane without sacrificing salt rejection. The study demonstrates the potential of CAIP membranes for brackish water desalination and water treatment.
Article
Engineering, Chemical
Yitian Qin, Zhihao Zhu, Guodong Kang, Haijun Yu, Yiming Cao
Summary: The study demonstrates the feasibility of using plasticizer-assisted interfacial polymerization to fabricate aromatic polyamide layers with improved desalination performance. By adjusting the concentration of plasticizer, water flux can be significantly enhanced while salt rejection may slightly decrease. The introduction of DEP disrupts the hydrogen bonding between polyamide chains, enhancing the softness of the polyamide layer and promoting water diffusion efficiency.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Biochemistry & Molecular Biology
Marwin R. Gallardo, Micah Belle Marie Yap Ang, Jeremiah C. Millare, Shu-Hsien Huang, Hui-An Tsai, Kueir-Rarn Lee
Summary: In this study, thin-film composite polyamide membranes were fabricated using the vacuum-assisted interfacial polymerization method and compared with membranes prepared using the traditional interfacial polymerization technique. The results showed that the membranes fabricated using the vacuum-assisted interfacial polymerization method had higher crosslinking degree, surface roughness, and structure density, resulting in higher separation performance.
Article
Polymer Science
Manuel Reyes De Guzman, Micah Belle Marie Yap Ang, Shu-Hsien Huang, Qing-Yi Huang, Yu-Hsuan Chiao, Kueir-Rarn Lee
Summary: Thin-film composite polyamide membranes produced through interfacial polymerization can function more efficiently by adjusting the chemical structure of participating monomers. Among the three diamine monomers considered, CHDA was found to be the most effective in producing TFC NF-like FO membranes with optimal performance.
Article
Engineering, Chemical
Ali Behboudi, Sanaz Ghiasi, Toraj Mohammadi, Mathias Ulbricht
Summary: By altering spinning conditions and using PVP as a blending additive, a PVC hollow fiber membrane for water desalination applications was successfully fabricated, showing high flux and salt rejection rates, especially suitable for nanofiltration and forward osmosis tests.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Paula Jungwon Choi, Sungil Lim, Hokyong Shon, Alicia Kyoungjin An
Summary: The outer selective hollow fiber forward osmosis (OSHF FO) membranes incorporated with negatively charged silver nanoparticles (NPs) showed better stability and fouling resistance, leading to a longer lifespan and higher flux recovery after salt cleaning.
Article
Engineering, Environmental
Dai Quyet Truong, Youngwoo Choo, Nawshad Akther, Sharaniya Roobavannan, Ahmad Norouzi, Vipul Gupta, Michael Blumenstein, Tien Vinh Nguyen, Gayathri Naidu
Summary: In this study, KCoFC@ZIF was successfully synthesized by grafting zeolitic imidazole frameworks (ZIF) onto potassium cobalt hexacyanoferrate (KCoFC) ion exchange nanomaterial. KCoFC@ZIF showed increased surface area and reduced pore diameter, resulting in high selective recovery of rubidium (Rb) in seawater with high potassium concentration. KCoFC@ZIF demonstrated high Rb uptake capacity and regenerative efficiency.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Sayed Mukit Hossain, Hanwei Yu, Youngwoo Choo, Gayathri Naidu, Dong Suk Han, Ho Kyong Shon
Summary: This study improves the selectivity of lithium ions by modifying the electrode surfaces using the metal-organic framework ZiF-8. The in-situ growth of ZiF-8 on the surface of activated carbon electrodes increases the selectivity of lithium ions compared to bare electrodes.
Review
Environmental Sciences
Anwar Ul Haq Khan, Ravi Naidu, Raja Dharmarajan, Cheng Fang, Hokyong Shon, Zhaomin Dong, Yanju Liu
Summary: This review focuses on the occurrence and interactions of engineered nanoparticles (ENPs) and brominated flame retardants (BFRs) in water systems, as well as the formation of complex compounds in the environment. It summarizes the release of ENPs and BFRs, their key interaction mechanisms, and their influence on the behavior and toxic effects of PBDEs. The study highlights the distinct behavior of mixed compounds (ENPs-BFRs) and emphasizes the importance of understanding the interactions in comprehensive risk assessments.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Article
Engineering, Environmental
Sungil Lim, Yu Chang Kim
Summary: This study aims to optimize a calcite bed reactor system to efficiently dissolve calcite granules to supply calcium ions for desalinated water re-mineralization. By manipulating operational parameters, the most efficient calcite dissolution was achieved with dissolved calcium ions conforming to drinking water standards. The study also found that higher feed flow rates and shorter EBCT resulted in increased calcite dissolution and production quantity.
ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY
(2023)
Article
Engineering, Chemical
Mohammad Mahbub Kabir, Mst. Mahmoda Akter, Zhenguo Huang, Leonard Tijing, Ho Kyong Shon
Summary: This study comprehensively evaluates the role of water industries in hydrogen production from a circular economy perspective, providing significant insights for future hydrogen energy development.
Article
Chemistry, Multidisciplinary
Tasneem Elmakki, Sifani Zavahir, Umme Hafsa, Leena Al-Sulaiti, Zubair Ahmad, Yuan Chen, Hyunwoong Park, Ho Kyong Shon, Yeek-Chia Ho, Dong Suk Han
Summary: In this study, alpha-LiAlO2 was used as a Li-capturing positive electrode material to recover Li from aqueous Li resources. The material synthesis was cost-effective and low-energy. It showed selective capture of Li+ ions in the concentration range of 100 mM to 25 mM. The system demonstrated the ability to handle complex solutions such as seawater reverse osmosis brine.
Review
Biochemistry & Molecular Biology
Hyeon Tae Kim, Morteza Afsari, Noel Peter B. Tan, Ho Kyong Shon, Leonard D. Tijing
Summary: Thermally localized solar-driven water evaporation (SWE) has been increasingly developed in recent years for cost-efficient freshwater production. Multistage SWE systems, with their simple structure and high solar-to-thermal conversion rates, have attracted much attention. In this study, currently designed multistage SWE devices were reviewed and examined based on their characteristics and performances. The key factors to consider include heat and mass transport, conversion efficiency, water production rate, and kWh/number of stages. These reviewed designs have the potential to be adopted for small-scale solar desalination, providing sufficient freshwater in regions with limited access.
Article
Engineering, Environmental
Sharaniya Roobavannan, Youngwoo Choo, Dai Quyet Truong, Dong Suk Han, Ho Kyong Shon, Gayathri Naidu
Summary: Lithium (Li) is increasing in value due to its use in energy storage devices for electric vehicles. Seawater mining of Li is a sustainable alternative to conventional land mining. In this study, a hybrid nanomaterial, HMO@ZIF, was developed to selectively adsorb Li from seawater. The encapsulation of zeolitic imidazolate frameworks (ZIF) onto hydrogen manganese oxide (HMO) particles led to improved Li uptake through increased surface area, additional functional groups, and zinc ion intercalation.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Jiaxi Jiang, Pema Dorji, Umakant Badeti, Weonjung Sohn, Stefano Freguia, Sherub Phuntsho, Ibrahim El Saliby, Ho Kyong Shon
Summary: Human urine is a valuable source of fertilisers, and this study investigated the use of a hybrid MBR and MCDI system for nutrient removal and recovery. The results showed that MCDI effectively removed nitrate, phosphate, and ammonium from the treated urine, and achieved high recovery rates in the concentrated brine. The study further demonstrated the feasibility of using MCDI for nutrient recovery without the need for chemical additives.
Article
Engineering, Chemical
Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han
Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.
Article
Engineering, Environmental
Junghyun Kim, Leonard Tijing, Ho Kyong Shon, Seungkwan Hong
Summary: Membrane distillation (MD) has potential for high salinity treatment and zero liquid discharge (ZLD), but faces challenges in fouling and scaling under high recovery conditions. This study proposes alternating current (AC) operation for electrically conductive membrane distillation (ECMD) to control both cations and anions, increasing water recovery by 27%.
Article
Engineering, Chemical
Mohammad Mahbub Kabir, Golam Md. Sabur, Mst. Mahmoda Akter, Sang Yong Nam, Kwang Seop Im, Leonard Tijing, Ho Kyong Shon
Summary: This paper explores the integration of electrodialysis (ED) technology in the water industries (WIN) for sustainable desalination, resource, and energy recovery. The authors provide a comprehensive analysis of recent advancements and conduct a techno-economic and environmental sustainability analysis. They also discuss the use of ED for energy recovery and assess scaling-up issues based on recent scientific findings. The study offers novel insights for the development of a sustainable closed-loop economy in the water industries.
Article
Engineering, Chemical
Weonjung Sohn, Jiaxi Jiang, Sherub Phuntsho, Ho Kyong Shon
Summary: This study demonstrates that incorporating biofilm carriers and powdered activated carbon in a membrane bioreactor enhances nitrification rates and reduces hydraulic retention time, resulting in higher energy efficiency and decreased footprint.
Article
Engineering, Chemical
M. S. Sajna, Tasneem Elmakki, Kira Schipper, Seungwon Ihm, Youngwook Yoo, Byungsung Park, Hyunwoong Park, Ho Kyong Shon, Dong Suk Han
Summary: This review paper explores the potential of seawater desalination plants to address the increasing demand for water, energy, mineral resources, and foods, particularly in resource-scarce regions. By utilizing seawater and integrating renewable energy sources, these plants can contribute significantly to sustainable development and promote a circular economy.
Article
Engineering, Chemical
Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu
Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Retraction
Engineering, Chemical
Chang Liu, Jinghong Liu, Liang Zhu, Shanfu Tang, Huixin Xiong
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma
Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman
Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer
Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho
Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang
Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar
Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev
Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun
Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li
Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis
Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang
Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes
Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang
Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.
JOURNAL OF MEMBRANE SCIENCE
(2024)