Article
Energy & Fuels
Jia Liu, Jing Wang, Ti Dong, Deqing Liang
Summary: The formation of wax crystals and hydrates in deep-sea crude oil can affect the nucleation, growth, aggregation, and crystal structure of hydrates. Specifically, wax crystals inhibit hydrate formation, while hydrate formation reduces wax crystal aggregation, improving the flow characteristics of the hydrate slurry. Wax has no effect on the crystal structure of CH4 hydrate but impacts the distribution of the gas in cavities.
Article
Engineering, Chemical
Qiankun Zhao, Lixia Yang, Chaoqun Yao, Guangwen Chen
Summary: An ultrasound-assisted tube crystallization device was developed for continuous antisolvent crystallization of acetylsalicylic acid. Results showed that the device had high energy efficiency and excellent temperature control. The effects of ultrasonic power, time, supersaturation degree, and excitation method on the crystallization process were investigated. The improved device demonstrated superior performance compared to conventional crystallizers.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Thermodynamics
Xuan Kou, Jing-Chun Feng, Xiao-Sen Li, Yi Wang, Zhao-Yang Chen
Summary: This study investigates the interactions between hydrate decomposition and heat/mass transfer from the perspective of hydrate morphology at different scales, revealing that mass transfer significantly influences the evolution of hydrate morphology, especially the gas mass transfer leading to the transition from patchy pore-filling to grain-bridging. The concept of hydrate bridges is introduced to describe the combination of grain-bridging hydrate and water layer wrapping the hydrate.
Article
Chemistry, Multidisciplinary
Mojdeh Zarifi, Bjorn Kvamme, Tatiana Kuznetsova
Summary: This work provides a brief overview of selected hydrate film growth models with a focus on analyzing hydrate phase transition dynamics. The research demonstrates that water-dominated phase hydrate phase transitions have heat transport significantly faster than mass transport. The proposal suggests that theoretical studies on hydrate nucleation and growth should incorporate all relevant transport properties to ensure accuracy in thermodynamics.
APPLIED SCIENCES-BASEL
(2021)
Article
Thermodynamics
D. V. Antonov, O. S. Gaidukova, V. V. Dorokhov, S. Ya. Misyura, V. S. Morozov, N. E. Shlegel, P. A. Strizhak
Summary: This paper investigates the heat and mass transfer during the ignition of single and double granulated hydrates in a combustion chamber. Experiments were conducted using a laboratory-scale oblong reactor. The ignition delay times, combustion regimes, and flame zone sizes were determined, and the joint influence of the hydrate granules on ignition behavior was analyzed. A model was developed to estimate the threshold boundary conditions for hydrate ignition in chambers of different sizes and compositions. The dissociation rates of the hydrates and the thermal conditions for consistent ignition were predicted. (c) 2023 Elsevier Ltd. All rights reserved.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2023)
Article
Energy & Fuels
Jiaqiang Jing, Lequan Zhuang, Rinat Karimov, Jie Sun, Xingtang Zhang, Hang Yang
Summary: There are multiple flow assurance challenges in deep-water energy development, with the coexistence of wax and hydrate posing one of the most difficult problems. An experimental study was conducted to investigate the impact of wax content, water cut, subcooling, and static time on CP hydrate-forming mixtures. The results revealed that wax inhibits hydrate nucleation and growth, but the viscosity of hydrate slurry is still higher in systems with wax due to wax-hydrate aggregates contributing to system viscosity. Additionally, wax increases the yield stress of the hydrate slurry, with a more significant effect at higher water cut and longer static times. The rating: 9/10.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
(2023)
Article
Energy & Fuels
Ping Guo, Yi-Lun Song, Yi-Long Qiu
Summary: This study establishes an experimental device and method to simulate the synthesis and decomposition of marine nondiagenetic hydrates during solid fluidized mining. The effects of pressure drop on the decomposition of hydrate particles are investigated. The results show that a larger pressure drop leads to a faster decomposition reaction, but excessive pressure drop can have negative effects. A decomposition rate model for marine nondiagenetic hydrates is established, providing a theoretical basis for further research in this field.
Article
Thermodynamics
Veronique Osswald, Pascal Clain, Laurence Fournaison, Anthony Delahaye
Summary: CO2 hydrate slurries are potential phase change materials for secondary refrigeration, but the difficulty in evaluating their crystallization kinetics hinders their industrial use. This study presents a specific method to determine kinetics by directly measuring heat flow, which is consistent with the evaluation by the mass balance method.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2023)
Article
Engineering, Environmental
Aritra Kar, Vaibhav Bahadur
Summary: This study develops a simulation framework based on fundamental principles to analyze the heat transfer, mass transfer, and interfacial phenomena associated with gas hydrate formation. By simulating CO2 hydrate formation and validating against experimental data, several important conclusions regarding hydrate formation are drawn, such as the adverse impact of inadequate heat dissipation, the importance of small bubble size for growth rates, and the enhancement of CO2 separation efficiency by increasing reactor pressure.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Xiangxuan Li, Wei Cui, Ting Ma, Zhao Ma, Jun Liu, Qiuwang Wang
Summary: In this paper, a new lattice Boltzmann model considering dissociation kinetics, two phase flow, heat transfer, latent heat, surface reaction, thermal buoyancy, and variable parameter dependent on temperature is proposed to explore the dissociation mechanism of CO2 hydrate. The combined effect of depressurization decomposition and thermal decomposition on the dissociation process is investigated. The results provide guidance for the future application of CO2 hydrate in cold thermal energy storage systems.
Article
Thermodynamics
Rui Song, Shuyu Sun, Jianjun Liu, Chunhe Yang
Summary: The study presents a novel enthalpy-porosity technique coupled with volume of fraction (VOF) method for modeling the phase-change process of methane hydrate dissociation and multi-phase flow. The proposed theoretical model is validated by comparison with experiments and numerical modeling, showing its ability to simulate the effects of phase change on pore structure evolution, multiphase flow, heat and mass transfer, and kinetic reaction processes. This study provides new insights into pore-scale modeling of multiphase flow with phase change.
Article
Engineering, Environmental
Yuxuan Zhang, Zhongbin Zhang, Xiaoqiang Zhai, Yixiang Gan, Benjapon Chalermsinsuwan, Xiaolin Wang
Summary: Gas hydrates play a crucial role in the capture, storage, transport, and utilization of various gases. The dissociation kinetics of gas hydrates greatly affects gas transport and recovery efficiency. Encapsulation has been shown to be an effective technique for improving gas hydrate formation kinetics. In this study, the dissociation kinetics of encapsulated CO2-TBAB semi-clathrate hydrates in different shapes are experimentally investigated, and a two-stage numerical model is developed to simulate the dissociation process. The results show that the surface-to-volume ratio of the capsule and the dissociation driving force are the main factors influencing the dissociation kinetics, and the ring-shaped capsule exhibits the most efficient dissociation process. This work enhances the understanding of gas hydrate dissociation behavior in individual capsules and provides guidance for efficient hydrate-based gas transport and recovery.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Rui Song, Xiaoyu Feng, Yao Wang, Shuyu Sun, Jianjun Liu
Summary: A better understanding of the dissociation and transport mechanism of methane hydrate in sandy sediments is crucial for future commercial extraction. This study presents a comparative study on the modeling of methane hydrate dissociation and transport in core-scale sandy sediments, achieving improvements such as non-uniform distribution of synthetic hydrate and better agreement between simulation and experimental data. Additionally, the investigation into the physical reasons for phenomena such as mini peaks in far-field pressure and temperature fluctuations in Masuda's experiments provides new insights for modeling validation.
Article
Energy & Fuels
Xiao-Yan Li, Kun Wan, Yi Wang, Xiao-Sen Li
Summary: The study investigates the effects of soaking time on the dissociation behavior, gas-to-water ratio, and energy efficiency in the periodic depressurization and hot water injection method for gas hydrates production. The results show that reducing the soaking time improves the dissociation rate but decreases the thermal and energy efficiency, which is detrimental to hydrate production.
Article
Engineering, Chemical
Luqman Hakim Ahmad Mahir, Jieun Lee, H. Scott Fogler, Ronald G. Larson
Summary: The transport model proposed can predict the time evolution of deposit thickness and the spatial evolution of temperature and wax concentration. For oils with high wax content, deposit thickness growth is mainly controlled by heat transfer, whereas for oils with low wax content, the growth is slow and accompanied by occasional sloughing.
Article
Energy & Fuels
Yang Liu, Bohui Shi, Lin Ding, Yu Yong, Ye Zhang, Qanli Ma, Xiaofang Lv, Shangfei Song, Juheng Yang, Wei Wang, Jing Gong
Article
Energy & Fuels
Xiaofang Lv, Jie Zhang, Yang Liu, Qianli Ma, Jiawen Xu, Shidong Zhou, Shangfei Song, Bohui Shi
Summary: Euler models suitable for hydrate slurry flow were established based on particle dynamics theory. The study found that the distribution of velocity, particle concentration, and turbulent kinetic energy in a curved pipe was more asymmetrical compared to a straight pipe. The increase in particle size led to increased velocity heterogeneity and concentration gradient, and the pressure drop factor increased with velocity, particle concentration, and particle size along the pipeline.
Article
Chemistry, Multidisciplinary
Yang Liu, Chengxuan Wu, Xiaofang Lv, Xinyi Xu, Qianli Ma, Jiawei Meng, Shidong Zhou, Bohui Shi, Shangfei Song, Jing Gong
Summary: In the exploitation of deep-sea oil and gas resources, the presence of hydrates and wax can lead to significant increase in the viscosity and plugging tendency of multiphase flow systems. This study investigates the evolution of hydrate particles and their agglomeration characteristics in the presence or absence of wax crystals. The results show that the shell of hydrate particles changes from solid and rough to smooth and moist during hydrate growth on wax-free water droplets. Furthermore, the cohesive force between particles is found to increase with temperature and contact time. The presence of wax alters the shell structure of hydrate particles and leads to a larger liquid bridge between particles, increasing the cohesive force.
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.