Journal
EUROPEAN POLYMER JOURNAL
Volume 113, Issue -, Pages 236-243Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2019.01.067
Keywords
Conjugated polymers; Supramolecular encapsulation; CycIodextrins; Fluorescence; Surface morphology; Semiconductors
Categories
Funding
- DFG [HE 5967/4-1, NA 686/11-1]
- Chinese Scholarship Council
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In this study, we investigate the influence of gamma-cyclodextrin (gamma CD) or octakis-(2,3,6-tri-O-methyl)-gamma-cyclodextrin (TMe-gamma CD) encapsulation on the solubility, thermal, optical, electrochemical, morphological, and electrical properties of an aromatic polyazomethine (PA). PA was prepared by oxidative C-C coupling of pyrenyl groups from the monomer MA using FeCl3 as catalyst in DMF. After threading of gamma CD or TMe-gamma CD macrocycles onto the PA chains, the H-1 NMR spectra were in line with the formation of the respective inclusion complexes, PA.gamma CD and PA.TMe-gamma CD, which showed distinct improvements of their solubility in common organic solvents, higher thermal stability, as well as better film-forming ability. Fluorescence spectroscopy revealed that the emission maximum shifted from 388 nm for PA to 425 nm and 428 nm for PA.gamma CD and PATMe-gamma CD, which is in good agreement with encapsulation of PA backbones into the hydrophobic cavities. Fluorescence lifetime measurements indicated multiexponential decays for all compounds, which is in accordance with different conformers in the excited state. Atomic force microscopy indicated that the surfaces of PA.gamma CD and PATMe-gamma CD in the solid state showed needle-shaped morphologies with widths of 105 +/- 25 nm and 46 +/- 13 nm, respectively, whereas the surface of the naked PA polymer displayed an irregular morphology with embedded particles and width of 158 +/- 29 nm. The electrochemical band gaps (Delta E-g) of PA.gamma CD and PATMe-gamma CD were lower than that of nonencapsulated PA. The electrical conductivities of the investigated compounds were about 10(-11) S cm(-1), which is in the range of insulating materials.
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