4.7 Article

Corrosion resistance and interfacial morphologies of a high Nb-containing TiAl alloy with and without thermal barrier coatings in molten salts

Journal

CORROSION SCIENCE
Volume 156, Issue -, Pages 139-146

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2019.05.011

Keywords

High Nb-containing TiAl alloy; Corrosion behavior; Thermal barrier coatings; Air plasma spraying

Funding

  1. National Natural Science Foundation of China [51371144]

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In this work, corrosion behaviors of the high Nb-containing TiAl alloy with and without thermal barrier coatings are compared to illustrate the factors and corresponding mechanism determining stability of TiAl alloy in molten salts. The high Nb-containing TiAl alloy with coatings suffers a mass change of -7.50 mg/cm(2) in the mixture salts of 75 wt.%Na2SO4+25 wt.%NaCl at 800 degrees C for 50 h. The mass change of TiAl alloy with coatings is only 0.20 mg/cm(2) and the thickness of corrosion region is 10 +/- 1 mu m. Dense ceramic coating retards molten salts diffusing to TiAl substrate and corrosion products suppress self-sustaining reaction of TiAl alloy.

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