Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 42, Pages 9870-9874Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201902358
Keywords
coordination polymers; polyphenols; surface chemistry; tannic acid; silicate complexation; thin films
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Funding
- Faculty of Dentistry, UiO
- Carl Trygger Foundation [CTS 17:130]
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Surface modification with polyphenolic molecules has been pursued in biomedical materials owing to their antioxidant, anti-inflammatory, and antimicrobial characteristics. Recently, the use of silicic acid (Si-aq) as a mediator for efficient surface deposition of tannic acid (TA) was reported, but the postulated Si-TA polymeric networks were not characterized. Herein, we present unambiguous evidence for silicate-TA networks that involve Si-O-C motifs by using solid-state NMR spectroscopy, further supported by XPS and ToF-SIMS. By using QCM-D we demonstrate the advantages of Si-aq, compared to using transition-metal ions, to improve the coating efficiency under mildly acidic conditions. The presented homogenous coating buildup and validated applicability in inorganic buffers broadens the use of TA for surface modifications in technological and biomedical applications.
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